Ionic compound

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The crystal structure of sodium chloride, NaCl, a typical ionic compound. The purple spheres represent sodium cations, Na+, and the green spheres represent chloride anions, Cl.

In chemistry, an ionic compound is a chemical compound in which ions are held together in a lattice structure by ionic bonds. The positively charged ions are called cations and the negatively charged ions are called anions. These can be simple ions where a single atom has a charge imbalance, or polyatomic ions made of multiple atoms. Ions in ionic compounds are held together by the electrostatic forces between oppositely charged bodies. Individual ions can have multiple nearest neighbours, so are not considered to be part of molecules, but instead part of a continuous network. Ionic compounds have high melting and boiling points, and they are hard and very brittle. As solids they are almost always electrically insulating, but when melted or dissolved they become highly conductive, because the ions are mobilized.

Nomenclature[edit]

According to the nomenclature defined by IUPAC, in the most simple case of a binary ionic compound with no possible ambiguity about the stoichiometry, the common name is written using two words.[1] The name of the cation comes first, followed by the name of the anion.[2] For example, MgCl2 is named magnesium chloride, and Na2SO4 is named sodium sulfate (SO42−, sulfate, is an example of a polyatomic ion). To obtain the empirical formula from these names, the stoichiometry can be deduced from the charges on the ions, and the requirement of overall charge neutrality.

If the oxidation state of the cation is ambiguous, Stock nomenclature requires the oxidation number to be written in Roman numerals in parentheses directly after the name of the cation (without a space separating them). For example, FeSO4 is named iron(II) sulfate (with the 2+ charge on the Fe2+ ions balancing the 2− charge on the sulfate ion), whereas Fe2(SO4)3 is named iron(III) sulfate (because the two iron ions in each formula unit have a charge of 3+, to balance the 2− on each of the three sulfate ions). If the Classical naming system is being used, some ionic compounds have special "old" names, such as ferrous and ferric, for iron(II) and iron(III) respectively, and cuprous and cupric, for copper(I) and copper(II) respectively, so under that system Fe2(SO4)3 is named ferric sulfate.

Characteristics[edit]

Ions can be single atoms, as the sodium and chlorine in common table salt sodium chloride, or more complex groups such as the carbonate in calcium carbonate. But to be considered an ion, they must carry a positive or negative charge. Thus, in an ionic bond, one 'bonder' must have a positive charge and the other a negative one. By sticking to each other, they resolve, or partially resolve, their separate charge imbalances. Positive to positive and negative to negative ionic bonds do not occur.

Chemical compounds are never strictly ionic. Even the most electronegative/electropositive pairs such as caesium fluoride exhibit a degree of covalency. Similarly, covalent compounds often exhibit charge separations. See also HSAB theory.

Ionic compounds have very strong electrostatic bonds between particles. As a result, they generally have very high melting and boiling points and a low vapour pressure.[3] They also have good electrical conductivity when molten or in an aqueous solution.[4] Ionic inorganic compounds typically have high melting points so are solids at room temperature and usually form crystals. Unlike organic compounds they do not char nor ignite. On the other hand organic compounds have low melting points, most of them are insoluble in water, and characteristically they ignite quite easily.[5]

The ions produced by electron transfer attract each other by electrostatic attraction and this creates an ionic bond.

Structure[edit]

Ions typically pack into extremely regular crystalline structures, in an arrangement that minimizes the Coulomb energy (maximizing attractions and minimizing repulsions). For spherical ions (including all simple ions), the arrangement of anions in these systems are often related to close-packed arrangements of spheres, with the cations occupying interstices. Depending on the stoichiometry of the ionic compound, and the coordination (principally determined by the size ratio) of cations and anions, a variety of structures are commonly observed.[6]

Common ionic compound structures with close-packed anions[6]
Stoichiometry Cation:anion coordination Interstitial sites occupied Cubic close packing Hexagonal close packing
MX 6:6 all octahedral sodium chloride nickel arsenide
4:4 alternate tetrahedral zinc blende wurtzite
MX2 8:4 all tetrahedral fluorite
6:3 half octahedral (alternate layers fully occupied) cadmium chloride cadmium iodide
MX3 6:2 one-third octahedral chromium(III) chloride[7] bismuth iodide
M2X3 6:4 two-thirds octahedral corundum
ABO3 two-thirds octahedral ilmenite
AB2O4 one-eighth tetrahedral and one-half octahedral spinel, inverse spinel olivine

In some cases the anions take on a simple cubic packing, and the resulting common structures observed are:

Common ionic compound structures with simple cubic packed anions[7]
Stoichiometry Cation:anion coordination Interstitial sites occupied Example structure
MX 8:8 all filled cesium chloride
MX2 8:4 half filled calcium fluoride
M2X 4:8 half filled lithium oxide

Solubility[edit]

Following the aphorism, "like dissolves like", ionic compounds dissolve most readily in polar solvents (such as water) or ionic liquids. Ionic compounds tend not to dissolve in nonpolar solvents (such as diethyl ether or petrol/gasoline).

When the oppositely charged ions in the solid ionic lattice are surrounded by the opposite pole of a polar molecule, the solid ions are pulled out of the lattice and into the liquid. When this force is more than the electrostatic attraction of the lattice, the ions become dissolved in the liquid.

Electrical conductivity[edit]

Although ionic compounds contain charged atoms or clusters, they do not typically conduct electricity when they are in the solid state. In order to conduct, the charged particles must be mobile rather than stationary in a crystal lattice. When the ionic compounds are dissolved in a liquid or are themselves melted into a liquid, they can conduct electricity because the ions become mobile.[8]

In some unusual materials, fast ion conductors, one or more of the ionic components in the solid phase has a significant mobility, allowing conductivity.

See also[edit]

References[edit]

  1. ^ IUPAC 2005, p. 70.
  2. ^ Kotz, John C.; Treichel, Paul M; Weaver, Gabriela C. (2006). Chemistry and Chemical Reactivity (Sixth ed.). Belmont, CA: Thomson Brooks/Cole. p. 111. ISBN 0-534-99766-X. 
  3. ^ McQuarrie & Rock 1991, p. 503.
  4. ^ Dutta, Priti. "What are the characteristics of Ionic Compunds". Retrieved 2 December 2012. 
  5. ^ "A comparison of organic and inorganic compounds". Retrieved 2 December 2012. 
  6. ^ a b Moore, Lesley E. Smart; Elaine A. (2005). Solid state chemistry : an introduction (3. ed.). Boca Raton, Fla. [u.a.]: Taylor & Francis, CRC. p. 44. ISBN 9780748775163. 
  7. ^ a b Ellis, Arthur B. [] et al. (1995). Teaching general chemistry : a materials science companion (3. print ed.). Washington: American Chemical Soceity. p. 121. ISBN 084122725X. 
  8. ^ "Electrical Conductivity of Ionic Compound". Retrieved 2 December 2012. 

Bibliography[edit]