Isotopes of tin
Tin (Sn) is the element with the greatest number of stable isotopes (ten), which is probably related to the fact that 50 is a "magic number" of protons. 29 additional unstable isotopes are known, including the "doubly magic" tin-100 (100Sn) (discovered in 1994)[1] and tin-132 (132Sn). The longest-lived radioisotope is 126Sn with a half-life of 230,000 years. All other radioisotopes have half-lives less than a year.
Contents |
[edit] Tin-121m
| Prop: Unit: |
t½ a |
Yield % |
Q * keV |
βγ * |
|---|---|---|---|---|
| 155Eu | 4.76 | .0803 | 252 | βγ |
| 85Kr | 10.76 | .2180 | 687 | βγ |
| 113mCd | 14.1 | .0008 | 316 | β |
| 90Sr | 28.9 | 4.505 | 2826 | β |
| 137Cs | 30.23 | 6.337 | 1176 | βγ |
| 121mSn | 43.9 | .00005 | 390 | βγ |
| 151Sm | 90 | .5314 | 77 | β |
Tin-121m is a radioisotope and nuclear isomer of tin with a halflife of 43.9 years. In a normal thermal reactor, it has a very low fission product yield; thus, this isotope is not a significant contributor to nuclear waste.
Fast fission or fission of some heavier actinides will produce 121mSn at higher yields.
[edit] Tin-126
| Prop: Unit: |
t½ Ma |
Yield % |
Q * KeV |
βγ * |
|---|---|---|---|---|
| 99Tc | 0.211 | 6.1385 | 294 | β |
| 126Sn | 0.230 | 0.1084 | 4050 | βγ |
| 79Se | 0.327 | 0.0447 | 151 | β |
| 93Zr | 1.53 | 5.4575 | 91 | βγ |
| 135Cs | 2.3 | 6.9110 | 269 | β |
| 107Pd | 6.5 | 1.2499 | 33 | β |
| 129I | 15.7 | 0.8410 | 194 | βγ |
| Thermal | Fast | 14 MeV | |
|---|---|---|---|
| 232Th | not fissile | .0593±.0087 | 1.08 ± .17 |
| 233U | .233 ± .032 | .325 ± .075 | 1.79 ± .24 |
| 235U | .0594±.0052 | .098 ± .020 | 1.62 ± .49 |
| 238U | not fissile | .093 ± .020 | 1.38 ± .25 |
| 239Pu | .314 ± .049 | .209 ± .044 | ? |
| 241Pu | .362 ± .089 | .157 ± .031 | ? |
Tin-126 is a radioisotope of tin and one of only 7 long-lived fission products. While tin-126's halflife of 230,000 years translates to a low specific activity that limits its radioactive hazard, its short-lived decay product, antimony-126, emits high-energy gamma radiation, making external exposure to tin-126 a potential concern.
126Sn is in the middle of the mass range for fission products. Thermal reactors, which make up almost all current nuclear power plants, produce it at a very low yield (such as 0.0236% or 0.06%), since slow neutrons almost always fission 235U or 239Pu into unequal halves. Fast fission in a fast reactor or nuclear weapon, or fission of some heavy minor actinides like californium, will produce it at higher yields.
| Actinides | Half-life | Fission products | ||||||
|---|---|---|---|---|---|---|---|---|
| 244Cm | 241Pu f | 250Cf | 243Cmf | 10–30 y | 137Cs | 90Sr | 85Kr | |
| 232U f | 238Pu | f is for fissile |
69–90 y | 151Sm nc➔ | ||||
| 4n | 249Cf f | 242Amf | 141–351 | No fission product has half-life 102 to 2×105 years |
||||
| 241Am | 251Cf f | 431–898 | ||||||
| 240Pu | 229Th | 246Cm | 243Am | 5–7 ky | ||||
| 4n | 245Cmf | 250Cm | 239Pu f | 8–24 ky | ||||
| 233U f | 230Th | 231Pa | 32–160 | |||||
| 4n+1 | 234U | 4n+3 | 211–290 | 99Tc | 126Sn | 79Se | ||
| 248Cm | 242Pu | 340–373 | Long-lived fission products | |||||
| 237Np | 4n+2 | 1–2 My | 93Zr | 135Cs nc➔ | ||||
| 236U | 4n+1 | 247Cmf | 6–23 My | 107Pd | 129I | |||
| 244Pu | 80 My | >7% | >5% | >1% | >.1% | |||
| 232Th | 238U | 235U f | 0.7–12 Gy | fission product yield | ||||
[edit] Table
| nuclide symbol |
Z(p) | N(n) | isotopic mass (u) |
half-life | decay mode(s)[3][n 1] |
daughter isotope(s)[n 2] |
nuclear spin |
representative isotopic composition (mole fraction) |
range of natural variation (mole fraction) |
|---|---|---|---|---|---|---|---|---|---|
| excitation energy | |||||||||
| 99Sn[n 3] | 50 | 49 | 98.94933(64)# | 5# ms | 9/2+# | ||||
| 100Sn[n 4] | 50 | 50 | 99.93904(76) | 1.1(4) s [0.94(+54-27) s] |
β+ (83%) | 100In | 0+ | ||
| β+, p (17%) | 99Cd | ||||||||
| 101Sn | 50 | 51 | 100.93606(32)# | 3(1) s | β+ | 101In | 5/2+# | ||
| β+, p (rare) | 100Cd | ||||||||
| 102Sn | 50 | 52 | 101.93030(14) | 4.5(7) s | β+ | 102In | 0+ | ||
| β+, p (rare) | 101Cd | ||||||||
| 102mSn | 2017(2) keV | 720(220) ns | (6+) | ||||||
| 103Sn | 50 | 53 | 102.92810(32)# | 7.0(6) s | β+ | 103In | 5/2+# | ||
| β+, p (rare) | 102Cd | ||||||||
| 104Sn | 50 | 54 | 103.92314(11) | 20.8(5) s | β+ | 104In | 0+ | ||
| 105Sn | 50 | 55 | 104.92135(9) | 34(1) s | β+ | 105In | (5/2+) | ||
| β+, p (rare) | 105Cd | ||||||||
| 106Sn | 50 | 56 | 105.91688(5) | 115(5) s | β+ | 106In | 0+ | ||
| 107Sn | 50 | 57 | 106.91564(9) | 2.90(5) min | β+ | 107In | (5/2+) | ||
| 108Sn | 50 | 58 | 107.911925(21) | 10.30(8) min | β+ | 108In | 0+ | ||
| 109Sn | 50 | 59 | 108.911283(11) | 18.0(2) min | β+ | 109In | 5/2(+) | ||
| 110Sn | 50 | 60 | 109.907843(15) | 4.11(10) h | EC | 110In | 0+ | ||
| 111Sn | 50 | 61 | 110.907734(7) | 35.3(6) min | β+ | 111In | 7/2+ | ||
| 111mSn | 254.72(8) keV | 12.5(10) µs | 1/2+ | ||||||
| 112Sn | 50 | 62 | 111.904818(5) | Observationally Stable[n 5] | 0+ | 0.0097(1) | |||
| 113Sn | 50 | 63 | 112.905171(4) | 115.09(3) d | β+ | 113In | 1/2+ | ||
| 113mSn | 77.386(19) keV | 21.4(4) min | IT (91.1%) | 113Sn | 7/2+ | ||||
| β+ (8.9%) | 113In | ||||||||
| 114Sn | 50 | 64 | 113.902779(3) | Observationally Stable[n 6] | 0+ | 0.0066(1) | |||
| 114mSn | 3087.37(7) keV | 733(14) ns | 7- | ||||||
| 115Sn | 50 | 65 | 114.903342(3) | Observationally Stable[n 6] | 1/2+ | 0.0034(1) | |||
| 115m1Sn | 612.81(4) keV | 3.26(8) µs | 7/2+ | ||||||
| 115m2Sn | 713.64(12) keV | 159(1) µs | 11/2- | ||||||
| 116Sn | 50 | 66 | 115.901741(3) | Observationally Stable[n 6] | 0+ | 0.1454(9) | |||
| 117Sn | 50 | 67 | 116.902952(3) | Observationally Stable[n 6] | 1/2+ | 0.0768(7) | |||
| 117m1Sn | 314.58(4) keV | 13.76(4) d | IT | 117Sn | 11/2- | ||||
| 117m2Sn | 2406.4(4) keV | 1.75(7) µs | (19/2+) | ||||||
| 118Sn | 50 | 68 | 117.901603(3) | Observationally Stable[n 6] | 0+ | 0.2422(9) | |||
| 119Sn | 50 | 69 | 118.903308(3) | Observationally Stable[n 6] | 1/2+ | 0.0859(4) | |||
| 119m1Sn | 89.531(13) keV | 293.1(7) d | IT | 119Sn | 11/2- | ||||
| 119m2Sn | 2127.0(10) keV | 9.6(12) µs | (19/2+) | ||||||
| 120Sn | 50 | 70 | 119.9021947(27) | Observationally Stable[n 6] | 0+ | 0.3258(9) | |||
| 120m1Sn | 2481.63(6) keV | 11.8(5) µs | (7-) | ||||||
| 120m2Sn | 2902.22(22) keV | 6.26(11) µs | (10+)# | ||||||
| 121Sn[n 7] | 50 | 71 | 120.9042355(27) | 27.03(4) h | β- | 121Sb | 3/2+ | ||
| 121m1Sn | 6.30(6) keV | 43.9(5) a | IT (77.6%) | 121Sn | 11/2- | ||||
| β- (22.4%) | 121Sb | ||||||||
| 121m2Sn | 1998.8(9) keV | 5.3(5) µs | (19/2+)# | ||||||
| 121m3Sn | 2834.6(18) keV | 0.167(25) µs | (27/2-) | ||||||
| 122Sn[n 7] | 50 | 72 | 121.9034390(29) | Observationally Stable[n 8] | 0+ | 0.0463(3) | |||
| 123Sn[n 7] | 50 | 73 | 122.9057208(29) | 129.2(4) d | β- | 123Sb | 11/2- | ||
| 123m1Sn | 24.6(4) keV | 40.06(1) min | β- | 123Sb | 3/2+ | ||||
| 123m2Sn | 1945.0(10) keV | 7.4(26) µs | (19/2+) | ||||||
| 123m3Sn | 2153.0(12) keV | 6 µs | (23/2+) | ||||||
| 123m4Sn | 2713.0(14) keV | 34 µs | (27/2-) | ||||||
| 124Sn[n 7] | 50 | 74 | 123.9052739(15) | Observationally Stable[n 9] | 0+ | 0.0579(5) | |||
| 124m1Sn | 2204.622(23) keV | 0.27(6) µs | 5- | ||||||
| 124m2Sn | 2325.01(4) keV | 3.1(5) µs | 7- | ||||||
| 124m3Sn | 2656.6(5) keV | 45(5) µs | (10+)# | ||||||
| 125Sn[n 7] | 50 | 75 | 124.9077841(16) | 9.64(3) d | β- | 125Sb | 11/2- | ||
| 125mSn | 27.50(14) keV | 9.52(5) min | 3/2+ | ||||||
| 126Sn[n 10] | 50 | 76 | 125.907653(11) | 2.30(14)×105 a | β- (66.5%) | 126m2Sb | 0+ | ||
| β- (33.5%) | 126m1Sb | ||||||||
| 126m1Sn | 2218.99(8) keV | 6.6(14) µs | 7- | ||||||
| 126m2Sn | 2564.5(5) keV | 7.7(5) µs | (10+)# | ||||||
| 127Sn | 50 | 77 | 126.910360(26) | 2.10(4) h | β- | 127Sb | (11/2-) | ||
| 127mSn | 4.7(3) keV | 4.13(3) min | β- | 127Sb | (3/2+) | ||||
| 128Sn | 50 | 78 | 127.910537(29) | 59.07(14) min | β- | 128Sb | 0+ | ||
| 128mSn | 2091.50(11) keV | 6.5(5) s | IT | 128Sn | (7-) | ||||
| 129Sn | 50 | 79 | 128.91348(3) | 2.23(4) min | β- | 129Sb | (3/2+)# | ||
| 129mSn | 35.2(3) keV | 6.9(1) min | β- (99.99%) | 129Sb | (11/2-)# | ||||
| IT (.002%) | 129Sn | ||||||||
| 130Sn | 50 | 80 | 129.913967(11) | 3.72(7) min | β- | 130Sb | 0+ | ||
| 130m1Sn | 1946.88(10) keV | 1.7(1) min | β- | 130Sb | (7-)# | ||||
| 130m2Sn | 2434.79(12) keV | 1.61(15) µs | (10+) | ||||||
| 131Sn | 50 | 81 | 130.917000(23) | 56.0(5) s | β- | 131Sb | (3/2+) | ||
| 131m1Sn | 80(30)# keV | 58.4(5) s | β- (99.99%) | 131Sb | (11/2-) | ||||
| IT (.0004%) | 131Sn | ||||||||
| 131m2Sn | 4846.7(9) keV | 300(20) ns | (19/2- to 23/2-) | ||||||
| 132Sn | 50 | 82 | 131.917816(15) | 39.7(8) s | β- | 132Sb | 0+ | ||
| 133Sn | 50 | 83 | 132.92383(4) | 1.45(3) s | β- (99.97%) | 133Sb | (7/2-)# | ||
| β-, n (.0294%) | 132Sb | ||||||||
| 134Sn | 50 | 84 | 133.92829(11) | 1.050(11) s | β- (83%) | 134Sb | 0+ | ||
| β-, n (17%) | 133Sb | ||||||||
| 135Sn | 50 | 85 | 134.93473(43)# | 530(20) ms | β- | 135Sb | (7/2-) | ||
| β-, n | 134Sb | ||||||||
| 136Sn | 50 | 86 | 135.93934(54)# | 0.25(3) s | β- | 136Sb | 0+ | ||
| β-, n | 135Sb | ||||||||
| 137Sn | 50 | 87 | 136.94599(64)# | 190(60) ms | β- | 137Sb | 5/2-# | ||
- ^ Abbreviations:
EC: Electron capture
IT: Isomeric transition - ^ Bold for stable isotopes
- ^ Heaviest known nuclide with more protons than neutrons
- ^ Heaviest known nuclide with equal numbers of protons and neutrons
- ^ Believed to decay by β+β+ to 112Cd
- ^ a b c d e f g Theoretically capable of spontaneous fission
- ^ a b c d e Fission product
- ^ Believed to undergo β-β- decay to 122Te
- ^ Believed to undergo β-β- decay to 124Te with a half-life over 100×1015 years
- ^ Long-lived fission product
[edit] Notes
- Geologically exceptional samples are known in which the isotopic composition lies outside the reported range. The uncertainty in the atomic mass may exceed the stated value for such specimens.
- Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
- Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC which use expanded uncertainties.
[edit] References
- ^ Identification and decay spectroscopy of 100Sn at the GSI projectile fragment separator FRS, K. Sümmerer et al., Nucl. Phys. A616, 341 (1997).
- ^ http://www-nds.iaea.org/sgnucdat/c1.htm Chain Fission Yields, IAEA
- ^ http://www.nucleonica.net/unc.aspx
- Isotope masses from:
- G. Audi, A. H. Wapstra, C. Thibault, J. Blachot and O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties". Nuclear Physics A 729: 3–128. Bibcode 2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. http://www.nndc.bnl.gov/amdc/nubase/Nubase2003.pdf.
- Isotopic compositions and standard atomic masses from:
- J. R. de Laeter, J. K. Böhlke, P. De Bièvre, H. Hidaka, H. S. Peiser, K. J. R. Rosman and P. D. P. Taylor (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry 75 (6): 683–800. doi:10.1351/pac200375060683. http://www.iupac.org/publications/pac/75/6/0683/pdf/.
- M. E. Wieser (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry 78 (11): 2051–2066. doi:10.1351/pac200678112051. http://iupac.org/publications/pac/78/11/2051/pdf/. Lay summary.
- Half-life, spin, and isomer data selected from the following sources. See editing notes on this article's talk page.
- G. Audi, A. H. Wapstra, C. Thibault, J. Blachot and O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties". Nuclear Physics A 729: 3–128. Bibcode 2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. http://www.nndc.bnl.gov/amdc/nubase/Nubase2003.pdf.
- National Nuclear Data Center. "NuDat 2.1 database". Brookhaven National Laboratory. http://www.nndc.bnl.gov/nudat2/. Retrieved September 2005.
- N. E. Holden (2004). "Table of the Isotopes". In D. R. Lide. CRC Handbook of Chemistry and Physics (85th ed.). CRC Press. Section 11. ISBN 978-0849304859.
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