Lead zirconate titanate

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Lead zirconate titanate
Identifiers
CAS number 12626-81-2 YesY
PubChem 159452
EC-number 235-727-4
Jmol-3D images Image 1
Properties
Molecular formula (Pb[ZrxTi1-x]O3 0≤x≤1)
Molar mass 303.065 to 346.4222 g/mol
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
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Infobox references

Lead zirconium titanate is an intermetallic inorganic compound with the chemical formula Pb[ZrxTi1-x]O3 0≤x≤1). Also called PZT, it is a ceramic perovskite material that shows a marked piezoelectric effect, which finds practical applications in the area of electroceramics. It is a white solid that is insoluble in all solvents.

Electroceramic properties[edit]

Being piezoelectric, it develops a voltage (or potential difference) across two of its faces when compressed (useful for sensor applications), or physically changes shape when an external electric field is applied (useful for actuator applications). The dielectric constant of PZT can range from 300 to 3850 depending upon orientation and doping.[1]

Being pyroelectric, this material develops a voltage difference across two of its faces when it experiences a temperature change. As a result, it can be used as a heat sensor.

It is also ferroelectric, which means it has a spontaneous electric polarization (electric dipole) which can be reversed in the presence of an electric field.

The material features an extremely large dielectric constant at the morphotropic phase boundary (MPB) near x = 0.52.[2]

Uses[edit]

PZT-based materials are components of ultrasound transducers and ceramic capacitors, STM/AFM actuators (tubes).

PZT is used to make ultrasound transducers and other sensors and actuators, as well as high-value ceramic capacitors and FRAM chips. PZT is also used in the manufacture of ceramic resonators for reference timing in electronic circuitry. In 1975 Sandia National Laboratories was working on anti-flash goggles to protect aircrew from burns and blindness in case of a nuclear explosion.[3] The PLZT lenses could turn opaque in less than 150 microseconds.

Commercially, it is usually not used in its pure form, rather it is doped with either acceptors, which create oxygen (anion) vacancies, or donors, which create metal (cation) vacancies and facilitate domain wall motion in the material. In general, acceptor doping creates hard PZT while donor doping creates soft PZT. Hard and soft PZT's generally differ in their piezoelectric constants. Piezoelectric constants are proportional to the polarization or to the electrical field generated per unit of mechanical stress, or alternatively is the mechanical strain produced by per unit of electric field applied. In general, soft PZT has a higher piezoelectric constant, but larger losses in the material due to internal friction. In hard PZT, domain wall motion is pinned by the impurities thereby lowering the losses in the material, but at the expense of a reduced piezoelectric constant.

Varieties of PZTs[edit]

One of the commonly studied chemical composition is PbZr0.52Ti0.48O3. The increased piezoelectric response and poling efficiency near to x = 0.52 is due to the increased number of allowable domain states at the MPB. At this boundary, the 6 possible domain states from the tetragonal phase <100> and the 8 possible domain states from the rhombohedral phase <111> are equally favorable energetically, thereby allowing a maximum 14 possible domain states.

Like structurally similar lead scandium tantalate and barium strontium titanate, PZT can be used for manufacture of uncooled staring array infrared imaging sensors for thermographic cameras. Both thin film (usually obtained by chemical vapor deposition) and bulk structures are used. The formula of the material used usually approaches Pb1.1(Zr0.3Ti0.7)O3 (called PZT 30/70). Its properties may be modified by doping it with lanthanum, resulting in lanthanum-doped lead zirconium titanate (PLZT, also called lead lanthanum zirconium titanate), with formula Pb0.83La0.17(Zr0.3Ti0.7)0.9575O3 (PLZT 17/30/70).[4]

See also[edit]

References[edit]

  1. ^ Piezo Technologies' Materials Specifications
  2. ^ Rouquette, J; Haines, J; Bornand, V; Pintard, M; Papet, Ph; Bousquet, C; Konczewicz, L; Gorelli, FA; Hull, S (2004). "Pressure tuning of the morphotropic phase boundary in piezoelectric lead zirconate titanate". Physical Review B 70 (1): 014108. doi:10.1103/PhysRevB.70.014108. 
  3. ^ J. Thomas Cutchen, James O. Harris, Jr., and George R. Laguna (1975). "PLZT electrooptic shutters: applications". Applied Optics 14. pp. 1866–1873. doi:10.1364/AO.14.001866. 
  4. ^ Liu, W; Jiang, B; Zhu, W (2000). "Self-biased dielectric bolometer from epitaxially grown Pb(Zr,Ti)O3 and lanthanum-doped Pb(Zr,Ti)O3 multilayered thin films". Applied Physics Letters 77 (7): 1047–1049. doi:10.1063/1.1289064. 

External links[edit]