Les Ayvelles is located just 5 km south-east of Charleville-Mézières. Access to the commune is by road D764 from Villers-Semeuse in the north which passes through the centre of the commune and the village and continues to Flize in the south. The commune has large reservoirs in the east and a forest in the west (the Bois des Ayvelles) with the rest of the commune farmland.
The Meuse river forms the eastern border of the commune as it flows north to Belgium. The Ruisseau du Pierge rises in the west of the commune and flows east to join the Meuse.
In 2010 the commune had 927 inhabitants. The evolution of the number of inhabitants is known from the population censuses conducted in the commune since 1793. From the 21st century, a census of communes with fewer than 10,000 inhabitants is held every five years, unlike larger communes that have a sample survey every year.[Note 1]
^At the beginning of the 21st century, the methods of identification have been modified by Law No. 2002-276 of 27 February 2002, the so-called "law of local democracy" and in particular Title V "census operations" allows, after a transitional period running from 2004 to 2008, the annual publication of the legal population of the different French administrative districts. For communes with a population greater than 10,000 inhabitants, a sample survey is conducted annually, the entire territory of these communes is taken into account at the end of the period of five years. The first "legal population" after 1999 under this new law came into force in 1 January 2009 and was based on the census of 2006.