Lithium imide

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Lithium imide
Lithium imide.png
Properties
Molecular formula Li2NH
Molar mass 28.897 g/mol
Density 1.48 g/cm3
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
Infobox references

Lithium imide is an inorganic compound with the chemical formula Li
2
NH
. It is a white solid that turns brick red in sunshine.

\rm \ 2Li_2NH \rightarrow LiNH_2 + Li_3N

After vacuo heating, the mixture returns to white.[1]

It can be synthesized by the decomposition of lithium amide:

\rm \ 2LiNH_2 \rightarrow Li_2NH + NH_3

Its crystal structure is similar to lithium oxide (a = 504pm) and its density is 1.48g/cm3. It is also a strong base that is able to react with many organic compounds.[1]

Leyden Energy is working on battery technology involving lithium imide. They state that they expect 10% more charge time and double the battery lifespan, but expect it not to be available in mass consumer products until 2014.[2]

References[edit]

  1. ^ a b (simplified Chinese)张青莲. 《无机化学丛书》第一卷:稀有气体、氢、碱金属. 北京: 科学出版社. p. 338. ISBN 7-03-002238-6. 
  2. ^ Dolcourt, Jessica (2012-09-03). "Smartphone battery life: 2 problems, 4 fixes (Smartphones Unlocked) | Dialed In - CNET Blogs". Cnet.com. Retrieved 2012-12-16.