|Molar mass||147.846 g/mol|
|Density||4.65 g/cm3 |
|Melting point||1,257 °C (2,295 °F; 1,530 K)|
|Band gap||4 eV|
Refractive index (nD)
|no 2.30, ne 2.21|
|Point group||3m (C3v)|
|EU Index||Not listed|
LD50 (Lethal dose)
|8000 mg/kg (oral, rat)|
Except where noted otherwise, data is given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
|what is: / ?)(|
Lithium niobate (LiNbO3) is a compound of niobium, lithium, and oxygen. Its single crystals are an important material for optical waveguides, mobile phones, piezoelectric sensors, optical modulators and various other linear and non-linear optical applications.
Lithium niobate is a colorless solid insoluble in water. It has a trigonal crystal system, which lacks inversion symmetry and displays ferroelectricity, Pockels effect, piezoelectric effect, photoelasticity and nonlinear optical polarizability. Lithium niobate has negative uniaxial birefringence which depends slightly on the stoichiometry of the crystal and on temperature. It is transparent for wavelengths between 350 and 5200 nanometers.
Lithium niobate can be doped by magnesium oxide, which increases its resistance to optical damage (also known as photorefractive damage) when doped above the optical damage threshold. Other available dopants are Fe, Zn, Hf, Cu, Gd, Er, Y, Mn and B.
After a crystal is grown, it is sliced into wafers of different orientation. Common orientations are Z-cut, X-cut, Y-cut, and cuts with rotated angles of the previous axes.
Nanoparticles of lithium niobate and niobium pentoxide can be produced at low temperature. The complete protocol implies a LiH induced reduction of NbCl5 followed by in situ spontaneous oxidation into low-valence niobium nano-oxides. These niobium oxides are exposed to air atmosphere resulting in pure Nb2O5. Finally, the stable Nb2O5 is converted into lithium niobate LiNbO3 nanoparticles during the controlled hydrolysis of the LiH excess. Spherical nanoparticles of lithium niobate with a diameter of approximately 10 nm can be prepared by impregnating a mesoporous silica matrix with a mixture of an aqueous solution of LiNO3 and NH4NbO(C2O4)2 followed by 10 min heating in an IR furnace.
Lithium niobate is used extensively in the telecoms market, e.g. in mobile telephones and optical modulators. It is the material of choice for the manufacture of surface acoustic wave devices. For some uses it can be replaced by lithium tantalate, LiTaO3. Other uses are in laser frequency doubling, nonlinear optics, Pockels cells, optical parametric oscillators, Q-switching devices for lasers, other acousto-optic devices, optical switches for gigahertz frequencies, etc. It is an excellent material for manufacture of optical waveguides.
It's also used in the making of optical spatial low-pass (anti-aliasing) filters.
Periodically poled lithium niobate (PPLN)
Periodically poled lithium niobate (PPLN) is a domain-engineered lithium niobate crystal, used mainly for achieving quasi-phase-matching in nonlinear optics. The ferroelectric domains point alternatively to the +c and the -c direction, with a period of typically between 5 and 35 µm. The shorter periods of this range are used for second harmonic generation, while the longer ones for optical parametric oscillation. Periodic poling can be achieved by electrical poling with periodically structured electrode. Controlled heating of the crystal can be used to fine-tune phase matching in the medium due to a slight variation of the dispersion with temperature.
Periodic poling uses the largest value of lithium niobate's nonlinear tensor, d33= 27 pm/V. Quasi-phase matching gives maximum efficiencies that are 2/π (64%) of the full d33, about 17 pm/V
However, due to its low photorefractive damage threshold, PPLN only finds limited applications: at very low power levels. MgO doped lithium niobate is fabricated by periodically poled method. Periodically poled MgO doped lithium niobate (PPMgOLN) therefore expands the application to medium power level.
which is valid for T = 25 to 180 °C, for wavelengths λ between 2.8 and 4.8 micrometers.
In these equations f = (T-24.5)(T+570.82), λ is in micrometers, and T is in °C.
More generally for ordinary and extraordinary index for MgO doped LiNbO3:
|Parameters||5% MgO doped CLN||1% MgO doped SLN|
for congruent LiNbO3 (CLN) and stochiometric LiNbO3 (SLN).
- Spec sheet of Crystal Technology, Inc.
- "Luxpop". Retrieved June 18, 2010. (Value at nD=589.2 nm, 25 °C.)
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