Livermorium

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Livermorium
116Lv
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Livermorium (unknown chemical properties)
Ununseptium (unknown chemical properties)
Ununoctium (unknown chemical properties)
Po

Lv

(Usn)
ununpentiumlivermoriumununseptium
Livermorium in the periodic table
Appearance
unknown
General properties
Name, symbol, number livermorium, Lv, 116
Pronunciation /ˌlɪvərˈmɔəriəm/
LIV-ər-MOHR-ee-əm
Element category unknown
but probably a poor metal
Group, period, block 16 (chalcogens), 7, p
Standard atomic weight [293]
Electron configuration [Rn] 5f14 6d10 7s2 7p4
(predicted)[1]
2, 8, 18, 32, 32, 18, 6
(predicted)
Physical properties
Phase solid (predicted)[1][2]
Density (near r.t.) 12.9 (predicted)[1] g·cm−3
Melting point 637–780 K, 364–507 °C, 687–944 (extrapolated)[2] °F
Boiling point 1035–1135 K, 762–862 °C, 1403–1583 (extrapolated)[2] °F
Heat of fusion 7.61 (extrapolated)[2] kJ·mol−1
Heat of vaporization 42 (predicted)[3] kJ·mol−1
Atomic properties
Oxidation states −2,[4] +2, +4 (predicted)[1][3]
Ionization energies
(more)
1st: 723.6 (predicted)[1] kJ·mol−1
2nd: 1331.5 (predicted)[3] kJ·mol−1
3rd: 2846.3 (predicted)[3] kJ·mol−1
Atomic radius 183 (predicted)[3] pm
Covalent radius 162–166 (extrapolated)[2] pm
Miscellanea
CAS registry number 54100-71-9
History
Naming after Lawrence Livermore National Laboratory,[5] itself named partly after Livermore, California
Discovery Joint Institute for Nuclear Research and Lawrence Livermore National Laboratory (2000)
Most stable isotopes
Main article: Isotopes of livermorium
iso NA half-life DM DE (MeV) DP
293Lv syn 61 ms α 10.54 289Fl
292Lv syn 18 ms α 10.66 288Fl
291Lv syn 18 ms α 10.74 287Fl
290Lv syn 7.1 ms α 10.84 286Fl
· references

Livermorium is the synthetic superheavy element with the symbol Lv and atomic number 116. The name was adopted by IUPAC on May 30, 2012.[5]

It is placed as the heaviest member of group 16 (VIA), although a sufficiently stable isotope is not known at this time to allow chemical experiments to confirm its position as a heavier homologue to polonium.

It was first detected in 2000. Since then, about 35 atoms of livermorium have been produced, either directly or as a decay product of ununoctium, belonging to the four neighbouring isotopes with masses 290–293. The most stable isotope known is livermorium-293 with a half-life of ~60 ms.

History[edit]

Unsuccessful synthesis attempts[edit]

In late 1998, Polish physicist Robert Smolańczuk published calculations on the fusion of atomic nuclei towards the synthesis of superheavy atoms, including ununoctium.[6] His calculations suggested that it might be possible to make ununoctium and livermorium by fusing lead with krypton under carefully controlled conditions.[6]

In 1999, researchers at Lawrence Berkeley National Laboratory made use of these predictions and announced the discovery of livermorium and ununoctium, in a paper published in Physical Review Letters,[7] and very soon after the results were reported in Science.[8] The researchers reported to have performed the reaction

86
36
Kr
+ 208
82
Pb
293
118
Uuo
+ n.

The following year, they published a retraction after researchers at other laboratories were unable to duplicate the results and the Berkeley lab itself was unable to duplicate them as well.[9] In June 2002, the director of the lab announced that the original claim of the discovery of these two elements had been based on data fabricated by principal author Victor Ninov.[10][11]

Discovery[edit]

On July 19, 2000, scientists at Dubna (JINR) detected a single decay from an atom of livermorium following the irradiation of a Cm-248 target with Ca-48 ions. The results were published in December 2000.[12] This 10.54 MeV alpha-emitting activity was originally assigned to 292Lv due to the correlation of the daughter to previously assigned 288Fl. That assignment was later altered to 289Fl, and hence this activity was correspondingly changed to 293Lv. Two further atoms were reported by the institute during their second experiment between April–May 2001.[13]

\,^{48}_{20}\mathrm{Ca} + \,^{248}_{96}\mathrm{Cm} \to \,^{296}_{116}\mathrm{Lv} ^{*} \to \,^{293}_{116}\mathrm{Lv} + 3\,^{1}_{0}\mathrm{n}

In the same experiment they also detected a decay chain which corresponded to the first observed decay of flerovium and assigned to 289Fl.[13] This activity has not been observed again in a repeat of the same reaction. However, its detection in this series of experiments indicates the possibility of the decay of an isomer of livermorium, namely 293bLv, or a rare decay branch of the already discovered isomer,293aLv, in which the first alpha particle was missed. Further research is required to positively assign this activity.

The team repeated the experiment in April–May 2005 and detected 8 atoms of livermorium. The measured decay data confirmed the assignment of the discovery isotope as 293Lv. In this run, the team also observed 292Lv in the 4n channel for the first time.[14]

In May 2009, the Joint Working Party reported on the discovery of copernicium and acknowledged the discovery of the isotope 283Cn.[15] This implied the de facto discovery of livermorium, as 291Lv (see below), from the acknowledgment of the data relating to the granddaughter 283Cn, although the actual discovery experiment may be determined as that above.

In 2011, the IUPAC evaluated the Dubna team results and accepted them as a reliable identification of element 116.[16]

Naming[edit]

Livermorium is historically known as eka-polonium.[17] Ununhexium (Uuh) was the temporary IUPAC systematic element name. Scientists usually refer to the element simply as element 116 (or E116). According to IUPAC recommendations, the discoverer or discoverers of a new element have the right to suggest a name.[18]

The discovery of livermorium was recognized by the Joint Working Group (JWG) of IUPAC on 1 June 2011, along with that of flerovium.[16] According to the vice-director of JINR, the Dubna team wanted to name element 116 moscovium, after the Moscow Oblast in which Dubna is located.[19] However, the name livermorium and the symbol Lv were adopted on May 31, 2012[5] after an approval process by the IUPAC.[20] The name recognises the Lawrence Livermore National Laboratory, within the city of Livermore, California, USA, which collaborated with JINR on the discovery. The city in turn is named after the American rancher Robert Livermore, a naturalized Mexican citizen of English birth.

Current and future experiments[edit]

The team at Dubna have indicated plans to synthesize livermorium using the reaction between plutonium-244 and titanium-50. This experiment will allow them to assess the feasibility of using projectiles with Z > 20 required in the synthesis of superheavy elements in the eighth period (Z > 118). Although initially scheduled for 2008, the reaction looking at the synthesis of evaporation residues has not been conducted to date.[21]

There are also plans to repeat the Cm-248 reaction at different projectile energies in order to probe the 2n channel, leading to the new isotope 294Lv. In addition, they have future plans to complete the excitation function of the 4n channel product, 292Lv, which will allow them to assess the stabilizing effect of the N=184 shell on the yield of evaporation residues.

Nucleosynthesis[edit]

Target-projectile combinations leading to Z=116 compound nuclei

The below table contains various combinations of targets and projectiles which could be used to form compound nuclei with atomic number 116. The table below provides cross-sections and excitation energies for hot fusion reactions producing livermorium isotopes directly. Data in bold represent maxima derived from excitation function measurements. The below table contains various targets-projectile combinations for which calculations have provided estimates for cross section yields from various neutron evaporation channels.

Target Projectile CN Attempt result
208Pb 82Se 290Lv[22] Failure to date
232Th 58Fe 290Lv Reaction yet to be attempted
238U 54Cr 292Lv[23] Failure to date
244Pu 50Ti 294Lv Reaction yet to be attempted
248Cm 48Ca 296Lv[14][23] Successful reaction
246Cm 48Ca 294Lv[14][23] Reaction yet to be attempted
245Cm 48Ca 293Lv[24][23] Successful reaction
249Cf 40Ar 289Lv Reaction yet to be attempted

Cold fusion[edit]

208Pb(82Se,xn)290−xLv

In 1998, the team at GSI attempted the synthesis of 290Lv as a radiative capture (x=0) product. No atoms were detected providing a cross section limit of 4.8 pb.

Hot fusion[edit]

This section deals with the synthesis of nuclei of livermorium by so-called "hot" fusion reactions. These are processes which create compound nuclei at high excitation energy (~40–50 MeV, hence "hot"), leading to a reduced probability of survival from fission. The excited nucleus then decays to the ground state via the emission of 3–5 neutrons. Fusion reactions utilizing 48Ca nuclei usually produce compound nuclei with intermediate excitation energies (~30–35 MeV) and are sometimes referred to as "warm" fusion reactions. This leads, in part, to relatively high yields from these reactions.

238U(54Cr,xn)292−xLv

There are sketchy indications that this reaction was attempted by the team at GSI in 2006. There are no published results on the outcome, presumably indicating that no atoms were detected. This is expected from a study of the systematics of cross sections for 238U targets.[25]

248Cm(48Ca,xn)296−xLv (x=3,4)

The first attempt to synthesise livermorium was performed in 1977 by Ken Hulet and his team at the Lawrence Livermore National Laboratory (LLNL). They were unable to detect any atoms of livermorium.[26] Yuri Oganessian and his team at the Flerov Laboratory of Nuclear Reactions (FLNR) subsequently attempted the reaction in 1978 and were met by failure. In 1985, a joint experiment between Berkeley and Peter Armbruster's team at GSI, the result was again negative with a calculated cross-section limit of 10–100 pb.[27]

In 2000, Russian scientists at Dubna finally succeeded in detecting a single atom of livermorium, assigned to the isotope 292Lv.[12] In 2001, they repeated the reaction and formed a further 2 atoms in a confirmation of their discovery experiment. A third atom was tentatively assigned to 293Lv on the basis of a missed parental alpha decay.[13] In April 2004, the team ran the experiment again at higher energy and were able to detect a new decay chain, assigned to 292Lv. On this basis, the original data were reassigned to 293Lv. The tentative chain is therefore possibly associated with a rare decay branch of this isotope. In this reaction, 2 further atoms of 293Lv were detected.[14]

In an experiment run at the GSI between June-July 2010, scientists detected six atoms of livermorium; two atoms of 293116 and four atoms of 292116. They were able to confirm both the decay data and cross sections for the fusion reaction.

245Cm(48Ca,xn)293−x116 (x=2,3)

In order to assist in the assignment of isotope mass numbers for livermorium, in March–May 2003 the Dubna team bombarded a 245Cm target with 48Ca ions. They were able to observe two new isotopes, assigned to 291Lv and 290Lv.[24] This experiment was successfully repeated in Feb–March 2005 where 10 atoms were created with identical decay data to those reported in the 2003 experiment.[28]

As decay product[edit]

Livermorium has also been observed in the decay of ununoctium. In October 2006 it was announced that 3 atoms of ununoctium had been detected by the bombardment of californium-249 with calcium-48 ions, which then rapidly decayed into livermorium.[28]

The observation of 290Lv allowed the assignment of the product to 294Uuo and proved the synthesis of ununoctium.

Fission of compound nuclei with Z=116[edit]

Several experiments have been performed between 2000–2006 at the Flerov laboratory of Nuclear Reactions in Dubna studying the fission characteristics of the compound nuclei 296,294,290Lv. Four nuclear reactions have been used, namely 248Cm+48Ca, 246Cm+48Ca, 244Pu+50Ti and 232Th+58Fe. The results have revealed how nuclei such as this fission predominantly by expelling closed shell nuclei such as 132Sn (Z=50, N=82). It was also found that the yield for the fusion-fission pathway was similar between 48Ca and 58Fe projectiles, indicating a possible future use of 58Fe projectiles in superheavy element formation. In addition, in comparative experiments synthesizing 294Lv using 48Ca and 50Ti projectiles, the yield from fusion-fission was ~3x less for 50Ti, also suggesting a future use in SHE production.[29]

Isotopes and nuclear properties[edit]

Chronology of isotope discovery
Isotope Year discovered Discovery reaction
290Lv 2002 249Cf(48Ca,3n)[30]
291Lv 2003 245Cm(48Ca,2n)[24]
292Lv 2004 248Cm(48Ca,4n)[14]
293Lv 2000 248Cm(48Ca,3n)[12]

Theoretical calculation in a quantum tunneling model supports the experimental data relating to the synthesis of 293,292Lv.[31][32]

Retracted isotope
289Lv

In 1999, researchers at Lawrence Berkeley National Laboratory announced the synthesis of 293Uuo (see ununoctium), in a paper published in Physical Review Letters.[7] The claimed isotope 289Lv decayed by 11.63 MeV alpha emission with a half-life of 0.64 ms. The following year, they published a retraction after other researchers were unable to duplicate the results.[33] In June 2002, the director of the lab announced that the original claim of the discovery of these two elements had been based on data fabricated by the principal author Victor Ninov. As such, this isotope of livermorium is currently unknown.

Chemical properties[edit]

Extrapolated chemical properties[edit]

Oxidation states[edit]

Livermorium is projected to be the fourth member of the 7p series of non-metals and the heaviest member of group 16 (VIA) in the Periodic Table, below polonium. The group oxidation state of +6 is known for all the members apart from oxygen which lacks available d-orbitals for expansion and is limited to a maximum +2 state, exhibited in the fluoride OF2. The +4 is known for sulfur, selenium, tellurium, and polonium, undergoing a shift in stability from reducing for S(IV) and Se(IV) to oxidizing in Po(IV). Tellurium(IV) is the most stable for this element. This suggests a decreasing stability for the higher oxidation states as the group is descended and livermorium should portray an oxidizing +4 state and a more stable +2 state. The lighter members are also known to form a −2 state as oxide, sulfide, selenide, telluride, and polonide.

Chemistry[edit]

The possible chemistry of livermorium can be extrapolated from that of polonium. It should therefore undergo oxidation to a dioxide, LvO2, although a trioxide, LvO3 is plausible, but unlikely. The stability of a +2 state should manifest itself in the formation of a simple monoxide, LvO. Fluorination will likely result in a tetrafluoride, LvF4 and/or a difluoride, LvF2; a hexafluoride, LvF6, is possible but unlikely. Chlorination and bromination may well stop at the corresponding dihalides, LvCl2 and LvBr2. Oxidation by iodine should certainly stop at LvI2 and may even be inert to this element.[citation needed] The heavier livermorium dihalides are predicted to be linear, but the lighter ones are predicted to be bent.[34]

See also[edit]

References[edit]

  1. ^ a b c d e Haire, Richard G. (2006). "Transactinides and the future elements". In Morss; Edelstein, Norman M.; Fuger, Jean. The Chemistry of the Actinide and Transactinide Elements (3rd ed.). Dordrecht, The Netherlands: Springer Science+Business Media. ISBN 1-4020-3555-1. 
  2. ^ a b c d e Bonchev, Danail; Kamenska, Verginia (1981). "Predicting the Properties of the 113–120 Transactinide Elements". J. Phys. Chem. 85: 1177–1186. 
  3. ^ a b c d e Fricke, Burkhard (1975). "Superheavy elements: a prediction of their chemical and physical properties". Recent Impact of Physics on Inorganic Chemistry 21: 89–144. doi:10.1007/BFb0116498. Retrieved 4 October 2013. 
  4. ^ Thayer, John S. (2010). Chemistry of heavier main group elements. p. 83. doi:10.1007/9781402099755_2. 
  5. ^ a b c "Element 114 is Named Flerovium and Element 116 is Named Livermorium". IUPAC. 30 May 2012. 
  6. ^ a b Smolanczuk, R. (1999). "Production mechanism of superheavy nuclei in cold fusion reactions". Physical Review C 59 (5): 2634–2639. Bibcode:1999PhRvC..59.2634S. doi:10.1103/PhysRevC.59.2634. 
  7. ^ a b Ninov, Viktor; Gregorich, K.; Loveland, W.; Ghiorso, A.; Hoffman, D.; Lee, D.; Nitsche, H.; Swiatecki, W.; Kirbach, U.; Laue, C. et al. (1999). "Observation of Superheavy Nuclei Produced in the Reaction of 86Kr with 208Pb". Physical Review Letters 83 (6): 1104–1107. Bibcode:1999PhRvL..83.1104N. doi:10.1103/PhysRevLett.83.1104. 
  8. ^ Service, R. F. (1999). "Berkeley Crew Bags Element 118". Science 284 (5421): 1751. doi:10.1126/science.284.5421.1751. 
  9. ^ Public Affairs Department (2001-07-21). "Results of element 118 experiment retracted". Berkeley Lab. Retrieved 2008-01-18. 
  10. ^ Dalton, R (2002). "Misconduct: The stars who fell to Earth". Nature 420 (6917): 728–729. Bibcode:2002Natur.420..728D. doi:10.1038/420728a. PMID 12490902. 
  11. ^ Element 118 disappears two years after it was discovered. Physicsworld.com. Retrieved on 2012-04-02.
  12. ^ a b c Oganessian, Yu. Ts. (2000). "Observation of the decay of ^{292}116". Physical Review C 63: 011301. Bibcode:2001PhRvC..63a1301O. doi:10.1103/PhysRevC.63.011301. 
  13. ^ a b c "Confirmed results of the 248Cm(48Ca,4n)292116 experiment", Patin et al., LLNL report (2003). Retrieved 2008-03-03
  14. ^ a b c d e Oganessian, Yu. Ts.; Utyonkov, V.; Lobanov, Yu.; Abdullin, F.; Polyakov, A.; Shirokovsky, I.; Tsyganov, Yu.; Gulbekian, G.; Bogomolov, S.; Gikal, B. N. et al. (2004). "Measurements of cross sections and decay properties of the isotopes of elements 112, 114, and 116 produced in the fusion reactions 233,238U, 242Pu, and 248Cm+48Ca". Physical Review C 70 (6): 064609. Bibcode:2004PhRvC..70f4609O. doi:10.1103/PhysRevC.70.064609.  edit
  15. ^ R.C.Barber; H.W.Gaeggeler;P.J.Karol;H. Nakahara; E.Verdaci; E. Vogt (2009). "Discovery of the element with atomic number 112" (IUPAC Technical Report). Pure Appl. Chem. 81 (7): 1331. doi:10.1351/PAC-REP-08-03-05. 
  16. ^ a b Barber, Robert C.; Karol, Paul J.; Nakahara, Hiromichi; Vardaci, Emanuele; Vogt, Erich W. (2011). "Discovery of the elements with atomic numbers greater than or equal to 113 (IUPAC Technical Report)". Pure and Applied Chemistry 83 (7): 1. doi:10.1351/PAC-REP-10-05-01. 
  17. ^ The Search for New Elements: the Projects of Today in a Larger Perspective
  18. ^ Koppenol, W. H. (2002). "Naming of new elements(IUPAC Recommendations 2002)". Pure and Applied Chemistry 74 (5): 787. doi:10.1351/pac200274050787. 
  19. ^ "Russian Physicists Will Suggest to Name Element 116 Moscovium". rian.ru. 2011. Retrieved 2011-05-08. : Mikhail Itkis, the vice-director of JINR stated: "We would like to name element 114 after Georgy Flerov – flerovium, and another one [element 116] – moscovium, not after Moscow, but after Moscow Oblast".
  20. ^ "News: Start of the Name Approval Process for the Elements of Atomic Number 114 and 116". International Union of Pure and Applied Chemistry. Retrieved 22 February 2012. 
  21. ^ Flerov Lab.
  22. ^ Feng, Zhao-Qing; Jin, Gen-Ming; Li, Jun-Qing; Scheid, Werner (2007). "Formation of superheavy nuclei in cold fusion reactions". Physical Review C 76 (4): 044606. arXiv:0707.2588. Bibcode:2007PhRvC..76d4606F. doi:10.1103/PhysRevC.76.044606. 
  23. ^ a b c d Feng, Z; Jin, G; Li, J; Scheid, W (2009). "Production of heavy and superheavy nuclei in massive fusion reactions". Nuclear Physics A 816: 33. arXiv:0803.1117. Bibcode:2009NuPhA.816...33F. doi:10.1016/j.nuclphysa.2008.11.003. 
  24. ^ a b c Oganessian, Y. T.; Utyonkov, V.; Lobanov, Y.; Abdullin, F.; Polyakov, A.; Shirokovsky, I.; Tsyganov, Y.; Gulbekian, G.; Bogomolov, S.; Gikal, B. et al. (2004). "Measurements of cross sections for the fusion-evaporation reactions 244Pu(48Ca,xn)292−x114 and 245Cm(48Ca,xn)293−x116". Physical Review C 69 (5): 054607. Bibcode:2004PhRvC..69e4607O. doi:10.1103/PhysRevC.69.054607.  edit
  25. ^ "List of experiments 2000–2006"
  26. ^ Hulet, E. K.; Lougheed, R.; Wild, J.; Landrum, J.; Stevenson, P.; Ghiorso, A.; Nitschke, J.; Otto, R.; Morrissey, D.; Baisden, P.; Gavin, B.; Lee, D.; Silva, R.; Fowler, M.; Seaborg, G. (1977). "Search for Superheavy Elements in the Bombardment of 248Cm with 48Ca". Physical Review Letters 39 (7): 385. Bibcode:1977PhRvL..39..385H. doi:10.1103/PhysRevLett.39.385. 
  27. ^ Armbruster, P.; Agarwal, YK; Brüchle, W; Brügger, M; Dufour, JP; Gaggeler, H; Hessberger, FP; Hofmann, S; Lemmertz, P; Münzenberg, G et al. (1985). "Attempts to Produce Superheavy Elements by Fusion of 48Ca with 248Cm in the Bombarding Energy Range of 4.5–5.2 MeV/u". Physical Review Letters 54 (5): 406–409. Bibcode:1985PhRvL..54..406A. doi:10.1103/PhysRevLett.54.406. PMID 10031507. 
  28. ^ a b <Please add first missing authors to populate metadata.>. Synthesis of the isotopes of elements 118 and 116 in the 249Cf and 245Cm+48Ca fusion reactions. 
  29. ^ see Flerov lab annual reports 2000–2006
  30. ^ see ununoctium
  31. ^ P. Roy Chowdhury, C. Samanta, and D. N. Basu (2006). "α decay half-lives of new superheavy elements". Phys. Rev. C 73: 014612. arXiv:nucl-th/0507054. Bibcode:2006PhRvC..73a4612C. doi:10.1103/PhysRevC.73.014612. 
  32. ^ C. Samanta, P. Roy Chowdhury and D.N. Basu (2007). "Predictions of alpha decay half lives of heavy and superheavy elements". Nucl. Phys. A 789: 142–154. arXiv:nucl-th/0703086. Bibcode:2007NuPhA.789..142S. doi:10.1016/j.nuclphysa.2007.04.001. 
  33. ^ Ninov, V.; Gregorich, K.; Loveland, W.; Ghiorso, A.; Hoffman, D.; Lee, D.; Nitsche, H.; Swiatecki, W.; Kirbach, U.; Laue, C. et al. (2002). "Editorial Note: Observation of Superheavy Nuclei Produced in the Reaction of 86Kr with 208Pb [Phys. Rev. Lett. 83, 1104 (1999)]". Physical Review Letters 89 (3): 039901. Bibcode:2002PhRvL..89c9901N. doi:10.1103/PhysRevLett.89.039901. 
  34. ^ Van WüLlen, C.; Langermann, N. (2007). "Gradients for two-component quasirelativistic methods. Application to dihalogenides of element 116". The Journal of Chemical Physics 126 (11): 114106. Bibcode:2007JChPh.126k4106V. doi:10.1063/1.2711197. PMID 17381195.  edit

External links[edit]