Marcasite

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Marcasite
MarcassiteII.jpg
Marcasite with tarnish (8x6 cm)
General
Category Sulfide mineral
Formula
(repeating unit)
FeS2
Strunz classification 02.EB.10a
Crystal symmetry Orthorhombic 2/m 2/m 2/m
Unit cell a = 4.436 Å, b = 5.414 Å, c = 3.381 Å; Z = 2
Identification
Formula mass 119.98
Color Tin-white on fresh surface, pale bronze-yellow, darkening on exposure, iridescent tarnish
Crystal habit

Crystals typically tabular on {010}, curved faces common; stalactitic,

reniform, massive; cockscomb and spearhead shapes due to twinning on {101}.
Crystal system Orthorhombic, Pnnm
Twinning Common and repeated on {101}; less common on {011}.
Cleavage Cleavage: {101}, rather distinct; {110} in traces
Fracture Irregular/Uneven
Tenacity Brittle
Mohs scale hardness 6-6.5
Luster Metallic
Streak Dark-grey to black.
Diaphaneity Opaque
Specific gravity 4.875 calculated, 4.887 measured
Pleochroism [100] creamy white; [010] light yellowish white; [001] white with rose-brown tint. Anisotropism: Very strong, yellow through pale green to dark green
References [1][2][3]

The mineral marcasite, sometimes called white iron pyrite, is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both structures do have in common that they contain the disulfide S22- ion having a short bonding distance between the sulfur atoms. The structures differ in how these dianions are arranged around the Fe2+ cations. Marcasite is lighter and more brittle than pyrite. Specimens of marcasite often crumble and break up due to the unstable crystal structure.

On fresh surfaces it is pale yellow to almost white and has a bright metallic luster. It tarnishes to a yellowish or brownish color and gives a black streak. It is a brittle material that cannot be scratched with a knife. The thin, flat, tabular crystals, when joined in groups, are called "cockscombs."

In marcasite jewellery, pyrite used as a gemstone is termed "marcasite". That is, marcasite jewellery is made from pyrite not from marcasite. In the late medieval and early modern eras the word "marcasite" meant both pyrite and marcasite (and iron sulfides in general).[4] The narrower, modern scientific definition for marcasite as orthorhombic iron sulfide dates from 1845.[2] The jewellery sense for the word pre-dates this 1845 scientific redefinition. Marcasite in the scientific sense is not used as a gem due to its brittleness.

Occurrence[edit]

Iridescent cluster of marcasite crystals (3.3 x 2.1 x 1.4 cm)
Two halves of a ball of radiating marcasite from France.

Marcasite can be formed as both a primary or a secondary mineral. It typically forms under low-temperature highly acidic conditions. It occurs in sedimentary rocks (shales, limestones and low grade coals) as well as in low temperature hydrothermal veins. Commonly associated minerals include pyrite, pyrrhotite, galena, sphalerite, fluorite, dolomite and calcite.[1]

As a primary mineral it forms nodules, concretions and crystals in a variety of sedimentary rock, such as at Dover, Kent, England, where it forms as sharp individual crystals and crystal groups, and nodules (similar to those shown here) in chalk.

As a secondary mineral it forms by chemical alteration of a primary mineral such as pyrrhotite or chalcopyrite.

Alteration[edit]

Marcasite reacts more readily than pyrite under conditions of high humidity. The product of this disintegration is iron(II) sulfate and sulfuric acid. The hydrous iron sulfate forms a white powder consisting of the mineral melanterite, FeSO4·7H2O.[5]

This disintegration of marcasite in mineral collections is known as "pyrite decay". When a specimen goes through pyrite decay, the marcasite reacts with moisture and oxygen in the air, the sulfur oxidizing and combining with water to produce sulfuric acid that attacks other sulfide minerals and mineral labels. Low humidity (less than 60%) storage conditions prevents or slows the reaction.[6]

References[edit]

  1. ^ a b Handbook of Mineralogy
  2. ^ a b Mindat.org
  3. ^ Webmineral data
  4. ^ CNRTL (in French)
  5. ^ Klein, Cornelis and Cornelius S. Hurlbut, Manual of Mineralogy, Wiley, 20th ed. 1985, p.286 ISBN 0-471-80580-7
  6. ^ http://www.nps.gov/history/museum/publications/conserveogram/11-02.pdf NPS Storage Concerns For Geological Collections, Conserv-O-Gram, April 1998

External links[edit]