Mechanochemistry

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Mechanochemistry or mechanical chemistry is the coupling of mechanical and chemical phenomena on a molecular scale and includes mechanical breakage, chemical behaviour of mechanically-stressed solids (e.g., stress-corrosion cracking), tribology, polymer degradation under shear, cavitation-related phenomena (e.g., sonochemistry and sonoluminescence), shock wave chemistry and physics, and even the burgeoning field of molecular machines. Mechanochemistry can be seen as an interface between chemistry and mechanical engineering. It is possible to synthesize chemical products by using only mechanical action. The mechanisms of mechanochemical transformations are often complex and different from usual thermal or photochemical mechanisms.[1][2] The method of ball milling is a widely used process in which mechanical force is used to achieve chemical processing and transformations.[3] The special issue of Chemical Society Review (vol. 42, 2013) is dedicated to the theme of mechanochemistry. Fundamentals and applications ranging from nano materials to technology have been reviewed [4]

The term mechanochemistry is sometimes confused with mechanosynthesis, which refers specifically to the machine-controlled construction of complex molecular products.[5][6]

Mechanochemical phenomena have been utilized since time immemorial, for example in making fire. The oldest method of making fire is to rub pieces of wood against each other, creating friction and hence heat, allowing the wood to undergo combustion at a high temperature. Another method involves the use of flint and steel, during which a spark (a small particle of pyrophoric metal) spontaneously combusts in air, starting fire instantaneously.

References[edit]

  1. ^ Hickenboth, Charles R.; Moore, Jeffrey S.; White, Scott R.; Sottos, Nancy R.; Baudry1, Jerome; Wilson, Scott R. (2007). "Biasing Reaction Pathways with Mechanical Force,". Nature 446 (7134): 423–427. doi:10.1038/nature05681. PMID 17377579. Retrieved 20 June 2013. (subscription required)
  2. ^ Carlier L. & al. , Greener pharmacy using solvent-free synthesis: investigation of the mechanism in the case of dibenzophenazine, Powder Technol. 2013, 240, 41-47.
  3. ^ Carlier L. & al. , Use of co-grinding as a solvent-free solid state method to synthesize dibenzophenazines, Tetrahedron Let. 2011, 52, 4686-4689.
  4. ^ Hallmarks of mechanochemistry: from nanoparticles to technology, Peter Baláž, Marcela Achimovičová,Matej Baláž, Peter Billik, Zara Cherkezova-Zheleva, José Manuel Criado, Francesco Delogu, Erika Dutková, Eric Gaffet, Francisco José Gotor, Rakesh Kumar, Ivan Mitov, Tadej Rojac, Mamoru Senna, Andrey Streletskiikl and Krystyna Wieczorek-Ciurowam, Chem. Soc. Rev., 2013,42, 7571-7637, DOI: 10.1039/C3CS35468G
  5. ^ Drexler, K. Eric. Nanosystems: Molecular Machinery, Manufacturing, and Computation. New York: John Wiley & Sons. ISBN 0-471-57547-X. 
  6. ^ Batelle Memorial Institute and Foresight Nanotech Institute. "Technology Roadmap for Productive Nanosystems". Retrieved 2008. 

Lenhardt, J. M.; Ong, M. T.; Choe, R.; Evenhuis, C. R.; Martinez, T. J.; Craig, S. L., Trapping a Diradical Transition State by Mechanochemical Polymer Extension. Science 2010, 329 (5995), 1057-1060

See also[edit]