Mercuric amidochloride

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Mercuric amidochloride
Mercuric-amidochloride-from-xtal-2000-3D-CM-ellipsoids.png
Identifiers
CAS number 10124-48-8 YesY
PubChem 3032553
ChemSpider 21106343 YesY
UNII JD546Z56F0 N
ATC code D08AK01
Jmol-3D images Image 1
Properties
Molecular formula ClH2HgN
Molar mass 252.065 g/mol
Density 5.56 g/cm3
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
 N (verify) (what is: YesY/N?)
Infobox references

Mercuric amidochloride is an inorganic compound with the formula HgNH2Cl. It consists of a zig-zag 1-dimensional polymer (HgNH2)n with chloride counterions.[1][2] It arises from the reaction of ammonia and mercuric chloride. Addition of base converts it into "Millon's base," which has the formula [Hg2N]OH(H2O)x. A variety of related amido and nitrido materials with chloride, bromide, and hydroxide are known.[3]

Before the toxicity of mercury was appreciated, mercuric amidochloride, known as "ammoniated mercury", was used as a topical antiseptic and disinfectant.[4][5]

Eli Lilly & Company - Ointment No. 8 - Ammoniated Mercury 10%

See also[edit]

  • Merbromin, also known as "Mercurochrome", another antiseptic mercury compound
  • Thiomersal, another antiseptic mercury compound

References[edit]

  1. ^ Wells, A.F. (1984). Structural Inorganic Chemistry. Oxford: Clarendon Press. ISBN 0-19-855370-6. [page needed]
  2. ^ Lipscomb, W. N. (1951). "The structure of mercuric amidochloride, HgNH2Cl". Acta Crystallographica 4 (3): 266–8. doi:10.1107/S0365110X51000866. 
  3. ^ Holleman, A. F.; Wiberg, E. (2001). Inorganic Chemistry. San Diego: Academic Press. ISBN 0-12-352651-5. [page needed]
  4. ^ Aberer W, Gerstner G, Pehamberger H (September 1990). "Ammoniated mercury ointment: outdated but still in use". Contact Dermatitis 23 (3): 168–71. PMID 2149317. 
  5. ^ http://www.huidziekten.nl/allergie/stoffen/mercury-ammonium-chloride.htm[full citation needed]