NEXBTL

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NEXBTL is a renewable diesel fuel production process commercialized by the Finnish oil and refining company Neste Oil. Whether as an admixture or in its pure form, NEXBTL is able to supplement or partially replace diesel fuel without problems. Unblended NEXBTL meets the requirements set by the European pre-standard CEN TS 15940. Fuel blends meet the European diesel fuel standard EN 590.

Despite the name BTL, the feedstock is vegetable oil and waste animal fats, not whole plants. However, fuel quality is equal to the synthetic Fischer-Tropsch BTL and GTL diesel fuels.

Process[edit]

NEXBTL diesel is produced in a patented vegetable oil refining process. Chemically, it entails direct catalytic hydrotreating of plant oils, which are triglycerides, into the corresponding alkanes. The glycerol chain of the triglyceride is hydrogenated to the corresponding C3 alkane, propane — there is no glycerol sidestream. This process removes oxygen from the oil; the diesel is not an oxygenate like traditional transesterified FAME biodiesel. Catalytic isomerization into branched alkanes is then done to adjust the cloud point in order to meet winter operability requirements. As it is chemically identical to ideal conventional diesel, it requires no modification or special precautions for the engine.[1][2]

Production[edit]

Two refineries in Porvoo, Finland were brought on stream in 2007 and 2009, each with a capacity of 0.2 million tons per year.[3][4][5] Two larger refineries, with annual production of 0.8 million tons both, were brought on stream in Singapore and Rotterdam in 2010 and 2011, respectively.[6][7][8][9]

Emissions[edit]

Neste has calculated that the use of NEXBTL cuts carbon dioxide emissions by 40 to 60 percent, taking into account the entire production and transport chain.[10]

Due to the chemistry of the process, the renewable diesel is pure alkane and contains no aromatics, oxygen (although oxygen would have promoted cleaner combustion[11]) or sulfur.[2]

Cloud point[edit]

The cloud point (or gel point) can be adjusted down to −40 °C (−40 °F)[12] during the manufacturing process, compared to petrodiesel's cloud point of −30 °C (−22 °F),[13] which could improve the cloud point of diesel when blended. The cloud point is the temperature when the wax precipitates out of the fuel in the form of small wax crystals, making the fuel cloudy and more difficult to move within the fuel lines and systems of vehicles. The lower the cloud point of a particular fuel is, the more suitable it is in colder environments.

Feedstocks[edit]

A mix of palm oil, rapeseed oil, and waste fat from the food industry can be used. Initially, palm oil was the principal (90%) feedstock, although its share has been reduced to 53% by 2013.[14]

However, palm oil may endanger the carbon neutrality of the fuel if forest is cleared to make way for palm plantations. In response to this concern, Neste has joined the Round Table on Sustainable Palm Oil (RSPO) to certify that the palm oil is produced in a carbon-neutral, environmentally responsible manner. Neste purchases most of its palm oil from IOI,[15] but requires a separate production chain for the RSPO-certified palm oil, in order not to create demand for rainforest destruction.

Deforestation would release carbon to the atmosphere, and reduce the overall carbon binding capacity of the land, thus it would be counterproductive with respect to the carbon balance. In 2007, Greenpeace protested the use of palm oil, concluding the potential for deforestation remains. According to Greenpeace, increasing the production of palm oil reduces the available land area, so indirectly generates demand for rainforest destruction, even if the palm oil itself is rainforest-certified. Greenpeace noted RSPO is voluntary organization and claimed government regulation in palm oil producing countries, such as Indonesia, cannot be relied on because of political corruption. Greenpeace also claimed palm oil diesel can actually produce three to 10 times more carbon dioxide emissions than petrodiesel because of the indirect effects of clearing of swamps, forest fires and indirect generation of demand for land area.[16] Greenpeace demands that Neste should use domestic feedstocks such as rapeseed oil or biogas, instead. However, rapeseed is a slower-growing, cold-climate source with lesser carbon-binding potential than the oil palm, making emissions from cultivation and transport proportionally more severe.

In 2013, the share of palm oil in the feedstock has been reduced to 53%, being replaced by reclaimed waste oils such as used frying oil, animal and fish fat, and camelina, jatropha, soy and rapeseed oil. Use of reclaimed waste oil reduces the greenhouse gas impact by 88–91%.[14] Neste Oil is continuing to look into new feedstock, including algae, jatropha[17] and microbial oil.[18][19]

Use[edit]

This diesel is blended with petrodiesel. A market is created because the European Union required 5.75% of transport fuels should be biofuels by 2010. The EU further decided on 18 December 2008, that by 2020, the share of energy from renewable sources in all forms of transportation be at least 10% of the final consumption of energy.[20] Systems and regions without an electrical grid will be the long-term market for hydrotreated vegetable oils, as the EU prefers electrical use by factor 2.5. In the Helsinki area, the Helsinki Metropolitan Area Council and the Helsinki City Transport conducted a three-year experiment by running buses with 25% NEXBTL diesel at first, and then switching to 100% in 2008.[21] The trial, which was the largest field test of a biofuel produced from renewable raw materials worldwide, was a success: local emissions were decreased significantly, with particle emissions decreased by 30% and nitrogen oxide emissions by 10%, with excellent winter performance and no problems with catalytic converters.[22] Since then, Helsinki buses have run on NEXBTL.

As a result of its hydrocarbon nature, NEXBTL operates without problems in current diesel vehicles in all climatic conditions. It does not have any of the drawbacks of the traditional ester type FAME biodiesel, such as cold operability, 'best before' date, engine and fuel system deposit formation, risk for microbial growth and water pick up, engine oil dilution and deterioration.

NEXBTL can be blended into diesel fuel in any ratio, whereas the use of the traditional FAME biodiesel is limited to maximum 7 % by the EN 590 standard in order to avoid technical problems in engines and vehicles.

The European Union requires the use of renewable fuel, therefore it is expected to be a major market for NEXBTL.[citation needed]

Following a proposal by VDA, Daimler Trucks and Daimler Buses recommend the biofuel NEXBTL as an admixture to petrodiesel.[23]

See also[edit]

References[edit]

  1. ^ http://www.climatechange.ca.gov/events/2006-06-27+28_symposium/presentations/CalHodge_handout_NESTE_OIL.PDF
  2. ^ a b "Hydrotreated Vegetable Oil (HVO) as a Renewable Diesel Fuel". SAE International. Retrieved 2010-05-10. 
  3. ^ Biodieselhankkeet käynnistävät Suomessa valtavan risusavotan - HS.fi - Autot
  4. ^ http://www.nesteoil.com/default.asp?path=1;41;540;1259;1260;11736;12851
  5. ^ http://www.nesteoil.com/default.asp?path=1,41,537,2397,2235
  6. ^ Neste Oil to build a NExBTL Renewable Diesel plant in Singapore - Neste Oil Com
  7. ^ http://www.nesteoil.com/default.asp?path=1;41;540;1259;1261;13291;16384
  8. ^ http://www.nesteoil.com/default.asp?path=1;41;540;1259;1261;16768;18120
  9. ^ Thalén, Soile. "NExBTL diesel outdoes its rivals". Tekes. Retrieved 2010-05-10. 
  10. ^ Institut für Energie und Umwelt (ifeu): An Assessment of Energy and Greenhouse Gases of NEXBTL (Final Report, June 2006, on behalf of Neste Oil Corporation) http://www.nesteoil.com/binary.asp?GUID=52C6D33B-F406-4681-BFC2-37C70914E9DD
  11. ^ http://www.tandfonline.com/doi/abs/10.1080/00102200290021353#.Ugwa_6zpx1E
  12. ^ http://www.vtt.fi/inf/pdf/tiedotteet/2011/T2604.pdf VTT: Optimized usage of NExBTL renewable diesel fuel
  13. ^ Frequently Asked Questions Heavy Duty - Diesel Fuel Filtration
  14. ^ a b http://www.nesteoil.com/default.asp?path=1,41,11991,12243,15658
  15. ^ "Neste Oil S'pore plant to buy palm oil from IOI Corp". Reuters UK. 2008-01-15. Retrieved 2008-02-07. 
  16. ^ Greenpeace. "Kysymyksiä ja vastauksia palmuöljystä". 
  17. ^ "New raw materials are researched". Nesteoil.com. Retrieved 2010-05-10. 
  18. ^ http://www.nesteoil.com/default.asp?path=1;41;540;1259;1260;13292;15693 (English) http://www.nesteoil.fi/default.asp?path=35,52,12005,12007,12133,15698 (Finnish)
  19. ^ http://www.biodieselmagazine.com/articles/4456/neste-banks-on-waste-based-microbial-oil
  20. ^ http://ec.europa.eu/energy/strategies/2008/doc/2008_01_climate_action/2008_0609_en.pdf
  21. ^ YTV. YTV and HKL lead the way Biofuel reduces bus transportation emissions. http://www.ytv.fi/ENG/transport/travelling_news/lo_2007_10_03_biofuel.htm
  22. ^ http://www.hsl.fi/en/abouthsl/news/2011/Pages/Page_20110210013111.aspx
  23. ^ http://www.daimler.com/dccom/0-5-1096051-1-1099732-1-0-0-1096078-0-0-135-876574-0-0-0-0-0-0-0.html[dead link]