Neutron activation is the process in which neutron radiation induces radioactivity in materials, and occurs when atomic nuclei capture free neutrons, becoming heavier and entering excited states. The excited nucleus often decays immediately by emitting gamma rays, or particles such as electrons (beta rays), alpha particles, or fission products and neutrons (in nuclear fission). Thus, the process of neutron capture, even after any intermediate decay, often results in the formation of an unstable activation product. Such radioactive nuclei can exhibit half-lives ranging from small fractions of a second to many years.
Neutron activation is the only common way that a stable material can be induced into becoming intrinsically radioactive. All naturally-occurring materials, including air, water, and soil, can be induced (activated) by neutron capture into some amount of radioactivity in varying degrees, as a result of production of neutron-rich radioisotopes. Some atoms require more than one neutron to become unstable, which makes them harder to activate because the probability of a double or triple capture by a nucleus is below that of single capture. Water, for example, is made up of hydrogen and oxygen. Hydrogen requires a double capture to attain instability as hydrogen-3, tritium, while oxygen requires three captures to become unstable oxygen-19. Thus water is relatively difficult to activate, as compared to sea salt (NaCl), in which both the sodium and chlorine atoms become unstable with a single capture each. These facts were realized first-hand at the Operation Crossroads atomic test series in 1946.
27Co + n → 60
The cobalt-60 then decays by the emission of a beta particle plus gamma rays into nickel-60. This reaction has a half-life of about 5.27 years; and due to the availability of cobalt-59 (100% of its natural abundance) this neutron bombarded isotope of cobalt is a valuable source of nuclear radiation (namely gamma radiation) for radiotherapy.
In other cases, and depending on the kinetic energy of the neutron, the capture of a neutron can cause nuclear fission—the splitting of the atomic nucleus into two smaller nuclei. If the fission requires an input of energy, that comes from the kinetic energy of the neutron. An example of this kind of fission in a light element can occur when the stable isotope of lithium, lithium-7, is bombarded with fast neutrons and undergoes the following nuclear reaction:
In other words, the capture of a neutron by lithium-7 causes it to split into an energetic helium nuclei (alpha particle), a hydrogen-3 (tritium) nucleus and a free neutron. The Castle Bravo accident, in which the thermonuclear bomb test at Enewetak Atoll in 1954 exploded with 2.5 times the expected yield, was caused by the unexpectedly high probability of this reaction.
Neutron activation is the only common way that a stable material can be induced into becoming intrinsically radioactive. Neutrons are only free in quantity in the microseconds of a nuclear weapon's explosion and in an active nuclear reactor.
In an atomic weapon, neutrons are only generated for from 1 to 50 microseconds, but in huge numbers. Most are absorbed by the metallic bomb casing, which has not yet or only just started to be affected by the explosion within it. The neutron activation of the soon-to-be vaporized metal is responsible for a significant portion of the nuclear fallout in nuclear bursts high in the atmosphere. In other types of activation neutrons may irradiate soil that is disbursed in a mushroom cloud at or near the Earth's surface, resulting in fallout from activation of soil chemical elements.
Effects on materials over time
In any location with high neutron fluxes, such as within the cores of nuclear reactors, neutron activation contributes to material erosion; periodically the lining materials themselves must be disposed of, as low-level radioactive waste. Some materials are more subject to neutron activation than others, so a suitably chosen low-activation material can significantly reduce this problem (see International Fusion Materials Irradiation Facility). For example Chromium-51 will form by neutron activation in Chrome steel (which contains Cr-50) that is exposed to a typical reactor neutron flux.
Carbon-14, most frequently but not solely, generated by the neutron activation of atmospheric nitrogen-14 with thermal neutron, is (together with its dominant natural production pathway from cosmic ray-air interactions and historical production from atmospheric nuclear testing) also generation in comparatively minute amounts inside many designs of nuclear reactors which contain nitrogen gas impurities in their fuel cladding, coolant water and by neutron activating the oxygen contained in the water itself. Fast breeder reactors(FBR) produce about an order of magnitude less C-14 than the most common reactor type, the Pressurized water reactor, as FBRs do not use water as a primary coolant.
For physicians and radiation safety officers, activation of sodium in the human body to sodium-24, and phosphorus to phosphorus-31, can give a good immediate estimate of acute accidental neutron exposure.
In the ICF fusion approach, the fusion yield of the experiment (directly proportional to neutron production) is usually determined by measuring the gamma-ray emissions of aluminum or copper neutron activation targets. Aluminum can capture a neutron and generate radioactive Sodium-24 which has a half life of 15 hours, and a beta decay energy of 5.514 MeV.
Neutron activation analysis is one of the most sensitive and accurate methods of trace element analysis. It requires no sample preparation or solubilization and can therefore be applied to objects that need to be kept intact such as a valuable piece of art. Although the activation induces radioactivity in the object, its level is typically low and its lifetime may be short, so that its effects soon disappear. In this sense, neutron activation is a non-destructive analysis method.
Neutron activation analysis can be done in situ. For example, aluminum (Al-27) can be activated by capturing relatively low-energy neutrons to produce the isotope Al-28, which decays with a half-life of 2.3 minutes with a decay energy of 4.642 MeV. This activated isotope is used in oil drilling to determine the clay content(clay is generally an alumino-silicate) of the underground area under exploration.
For historians, accidental neutron activation can be used to authenticate atomic artifacts and materials subjected to neutron fluxes from fission incidents. For example, one of the fairly unique isotopes found in trinitite, and therefore with its absence likely signifying a fake sample of the mineral, is a barium neutron activation product, the barium in the trinity device coming from the slow explosive lens employed in the device, known as Baratol.
- Neutron activation analysis
- Phosphorus-32 produced when sulfur captures a neutron.
- Table of nuclides
- Salted bomb
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- US Army (1952). Operation Ivy Final Report Joint Task Force 132.
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- Neutron Activation Analysis web
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- neutron capture as it relates to nucleosynthesis
- neutron capture and the Chart of the nuclides
- the chart of the Nuclides
- Discovery of the Chromium isotopes, Chromium-55 by Cr-54 neutron capture
- US Army (1952). Operation Ivy Final Report Joint Task Force 132.