|Molar mass||464.13 g/mol|
|Detonation velocity||10,100 m/s|
Except where noted otherwise, data is given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
|what is: / ?)(|
Octanitrocubane (molecular formula: C8(NO2)8) is a high explosive that, like TNT, is shock-insensitive (not readily detonated by shock), not detonating even when struck by a hammer. The octanitrocubane molecule has the same chemical structure as cubane (C8H8) except that each of the eight hydrogen atoms is replaced by a nitro group (NO2).
It is however not as powerful as once thought, as the high density theoretical crystal structure has not been achieved. For this reason heptanitrocubane, the slightly less nitrated form, is believed to have marginally better performance despite having a worse oxygen balance.
Octanitrocubane is thought to have 20–25% greater performance than HMX (octogen). This increase in power is due to its highly expansive breakdown into CO2 and N2, as well as to the presence of strained chemical bonds in the molecule which have stored potential energy. In addition, octanitrocubane produces no water vapor making it less visible, and both the chemical itself and its decomposition products (nitrogen and carbon dioxide) are considered to be non-toxic.
Octanitrocubane has a detonation velocity of 10,100 m/s, making it the fastest known explosive.
Small amounts have been synthesized in the laboratory, but not enough for performance testing as an explosive.
Octanitrocubane was first synthesized by Philip Eaton (who was also the first to synthesize cubane in 1964) and Mao-Xi Zhang at the University of Chicago in 1999, with the structure proven by crystallographer Richard Gilardi of the United States Naval Research Laboratory.
The R.E. factor of octanitrocubane is 2.38, making it the most effective chemical explosive known.
Although octanitrocubane is predicted to be one of the most effective explosives, the difficulty of its synthesis inhibits practical use. Philip Eaton’s synthesis was difficult and lengthy, and required cubane (rare enough to begin with) as a starting point. As a result, octanitrocubane is more valuable, gram for gram, than gold. A proposed path to synthesis is the cyclotetramerization of the as yet undiscovered and presumably unstable dinitroacetylene.
- Astakhov AM, Stepanov RS, Babushkin AY (1998). "On the detonation parameters of octanitrocubane". Combustion Explosion and Shock Waves 34 (1): 85–87. doi:10.1007/BF02671823.
- Mao-Xi Zhang, Philip E. Eaton, Richard Gilardi (2000). "Hepta- and Octanitrocubanes". Angewandte Chemie International Edition 39 (2): 401–404. doi:10.1002/(SICI)1521-3773(20000117)39:2<401::AID-ANIE401>3.0.CO;2-P. PMID 10649425.
- Philip E. Eaton, Mao-Xi Zhang, Richard Gilardi, Nat Gelber, Sury Iyer, Rao Surapaneni (2001). "Octanitrocubane: A New Nitrocarbon". Propellants, Explosives, Pyrotechnics 27 (1): 1–6. doi:10.1002/1521-4087(200203)27:1<1::AID-PREP1>3.0.CO;2-6.