Optical depth

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For other uses, see Optical depth (astrophysics).

In physics, optical depth or optical thickness or Napierian absorbance, is the natural logarithm of the ratio of incident to transmitted radiant power through a material, and spectral optical depth or spectral optical thickness or spectral Napierian absorbance is the natural logarithm of the ratio of incident to transmitted spectral radiant power through a material.[1] Optical depth is dimensionless, and in particular is not a length, though it is a monotonically increasing function of path length, and approaches zero as the path length approaches zero. The use of the term "optical density" for optical depth is discouraged.[1]

In chemistry, a closely related quantity called "absorbance" or "decadic absorbance" is used instead of optical depth: the common logarithm of the ratio of incident to transmitted radiant power through a material, that is the optical depth divided by ln 10.

Mathematical definitions[edit]

Optical depth[edit]

Optical depth of a material, denoted τ, is given by:[2]

\tau = \ln\!\left(\frac{\Phi_\mathrm{e}^\mathrm{i}}{\Phi_\mathrm{e}^\mathrm{t}}\right) = -\ln T,

where

  • Φet is the radiant flux transmitted by that material;
  • Φei is the radiant flux received by that material;
  • T is the transmittance of that material.

Absorbance is related to optical depth by:

\tau = A \ln 10,

where A is the absorbance.

Spectral optical depth[edit]

Spectral absorbance in frequency and spectral absorbance in wavelength of a material, denoted τν and τλ respectively, are given by:[1]

\tau_\nu = \ln\!\left(\frac{\Phi_{\mathrm{e},\nu}^\mathrm{i}}{\Phi_{\mathrm{e},\nu}^\mathrm{t}}\right) = -\ln T_\nu,
\tau_\lambda = \ln\!\left(\frac{\Phi_{\mathrm{e},\lambda}^\mathrm{i}}{\Phi_{\mathrm{e},\lambda}^\mathrm{t}}\right) = -\ln T_\lambda,

where

Spectral absorbance is related to spectral optical depth by:

\tau_\nu = A_\nu \ln 10,
\tau_\lambda =A_\lambda \ln 10,

where

  • Aν is the spectral abosrbance in frequency;
  • Aλ is the spectral absorbance in wavelength.

Relationship with attenuation[edit]

Attenuance[edit]

Optical depth measures the attenuation of the transmitted radiant power in a material. Attenuation can be caused by absorption, but also reflection, scattering, and other physical processes. Optical depth of a material is approximately equal to its attenuance when both the absorbance is much less than 1 and the emittance of that material (not to be confused with radiant exitance or emissivity) is much less than the optical depth:

\Phi_\mathrm{e}^\mathrm{t} + \Phi_\mathrm{e}^\mathrm{att} = \Phi_\mathrm{e}^\mathrm{i} + \Phi_\mathrm{e}^\mathrm{e},
T + ATT = 1 + E,

where

  • Φet is the radiant power transmitted by that material;
  • Φeatt is the radiant power attenuated by that material;
  • Φei is the radiant power received by that material;
  • Φee is the radiant power emitted by that material;
  • T = Φetei is the transmittance of that material;
  • ATT = Φeattei is the attenuance of that material;
  • E = Φeeei is the emittance of that material,

and according to Beer–Lambert law,

T = e^{-\tau},

so:

ATT = 1 - e^{-\tau} + E \approx \tau + E \approx \tau,\quad \text{if}\ \tau \ll 1\ \text{and}\ E \ll \tau.

Attenuation coefficient[edit]

Optical depth of a material is also related to its attenuation coefficient by:

\tau = \int_0^l \alpha(z)\, \mathrm{d}z,

where

  • l is the thickness of that material through which the light travels;
  • α(z) is the attenuation coefficient or Napierian attenuation coefficient of that material at z,

and if α(z) is uniform along the path, the attenuation is said to be a linear attenuation and the relation becomes:

\tau = \alpha l.

Sometimes the relation is given using the attenuation cross section of the material, that is its attenuation coefficient divided by its number density:

\tau = \int_0^l \sigma N(z)\, \mathrm{d}z,

where

  • σ is the attenuation cross section of that material;
  • N(z) is the number density of that material at z,

and if N(z) is uniform along the path, the relation becomes:

\tau = \sigma Nl.

Applications[edit]

Atomic physics[edit]

In atomic physics, the spectral optical depth of a cloud of atoms can be calculated from the quantum-mechanical properties of the atoms. It is given by

\tau_\nu = \frac{d^2 N\nu} {2\mathrm{c} \hbar \varepsilon_0 \sigma \gamma},

where

Atmospheric sciences[edit]

See also: Beer's law

In atmospheric sciences, one often refers to the optical depth of the atmosphere as corresponding to the vertical path from Earth's surface to outer space; at other times the optical path is from the observer's altitude to outer space. The optical depth for a slant path is τ = , where τ′ refers to a vertical path, m is called the relative airmass, and for a plane-parallel atmosphere[clarification needed] it is determined as m = sec θ where θ is the zenith angle corresponding to the given path. Therefore

T = e^{-\tau} = e^{-m\tau'}.

The optical depth of the atmosphere can be divided into several components, ascribed to Rayleigh scattering, aerosols, and gaseous absorption. The optical depth of the atmosphere can be measured with a sun photometer.

Astronomy[edit]

In astronomy, the photosphere of a star is defined as the surface where its optical depth is 2/3. This means that each photon emitted at the photosphere suffers an average of less than one scattering before it reaches the observer. At the temperature at optical depth 2/3, the energy emitted by the star (the original derivation is for the Sun) matches the observed total energy emitted.[citation needed][clarification needed]

Note that the optical depth of a given medium will be different for different colors (wavelengths) of light.

For planetary rings, the optical depth is the (negative logarithm of the) proportion of light blocked by the ring when it lies between the source and the observer. This is usually obtained by observation of stellar occultations.

SI radiometry units
Quantity Unit Dimension Notes
Name Symbol[nb 1] Name Symbol Symbol
Radiant energy Qe[nb 2] joule J ML2T−2 Energy of electromagnetic radiation.
Radiant energy density we joule per cubic metre J/m3 ML−1T−2 Radiant energy per unit volume.
Radiant flux Φe[nb 2] watt W or J/s ML2T−3 Radiant energy emitted, reflected, transmitted or received, per unit time. This is sometimes also called "radiant power".
Spectral flux Φe,ν[nb 3]
or
Φe,λ[nb 4]
watt per hertz
or
watt per metre
W/Hz
or
W/m
ML2T−2
or
MLT−3
Radiant flux per unit frequency or wavelength. The latter is commonly measured in W⋅sr−1⋅m−2⋅nm−1.
Radiant intensity Ie,Ω[nb 5] watt per steradian W/sr ML2T−3 Radiant flux emitted, reflected, transmitted or received, per unit solid angle. This is a directional quantity.
Spectral intensity Ie,Ω,ν[nb 3]
or
Ie,Ω,λ[nb 4]
watt per steradian per hertz
or
watt per steradian per metre
W⋅sr−1⋅Hz−1
or
W⋅sr−1⋅m−1
ML2T−2
or
MLT−3
Radiant intensity per unit frequency or wavelength. The latter is commonly measured in W⋅sr−1⋅m−2⋅nm−1. This is a directional quantity.
Radiance Le,Ω[nb 5] watt per steradian per square metre W⋅sr−1⋅m−2 MT−3 Radiant flux emitted, reflected, transmitted or received by a surface, per unit solid angle per unit projected area. This is a directional quantity. This is sometimes also confusingly called "intensity".
Spectral radiance Le,Ω,ν[nb 3]
or
Le,Ω,λ[nb 4]
watt per steradian per square metre per hertz
or
watt per steradian per square metre, per metre
W⋅sr−1⋅m−2⋅Hz−1
or
W⋅sr−1⋅m−3
MT−2
or
ML−1T−3
Radiance of a surface per unit frequency or wavelength. The latter is commonly measured in W⋅sr−1⋅m−2⋅nm−1. This is a directional quantity. This is sometimes also confusingly called "spectral intensity".
Irradiance Ee[nb 2] watt per square metre W/m2 MT−3 Radiant flux received by a surface per unit area. This is sometimes also confusingly called "intensity".
Spectral irradiance Ee,ν[nb 3]
or
Ee,λ[nb 4]
watt per square metre per hertz
or
watt per square metre, per metre
W⋅m−2⋅Hz−1
or
W/m3
MT−2
or
ML−1T−3
Irradiance of a surface per unit frequency or wavelength. The former is commonly measured in 10−22 W⋅m−2⋅Hz−1, known as solar flux unit, and the latter in W⋅m−2⋅nm−1.[nb 6] This is sometimes also confusingly called "spectral intensity".
Radiosity Je[nb 2] watt per square metre W/m2 MT−3 Radiant flux leaving (emitted, reflected and transmitted by) a surface per unit area. This is sometimes also confusingly called "intensity".
Spectral radiosity Je,ν[nb 3]
or
Je,λ[nb 4]
watt per square metre per hertz
or
watt per square metre, per metre
W⋅m−2⋅Hz−1
or
W/m3
MT−2
or
ML−1T−3
Radiosity of a surface per unit frequency or wavelength. The latter is commonly measured in W⋅m−2⋅nm−1. This is sometimes also confusingly called "spectral intensity".
Radiant exitance Me[nb 2] watt per square metre W/m2 MT−3 Radiant flux emitted by a surface per unit area. This is the emitted component of radiosity. "Radiant emittance" is an old term for this quantity. This is sometimes also confusingly called "intensity".
Spectral exitance Me,ν[nb 3]
or
Me,λ[nb 4]
watt per square metre per hertz
or
watt per square metre, per metre
W⋅m−2⋅Hz−1
or
W/m3
MT−2
or
ML−1T−3
Radiant exitance of a surface per unit frequency or wavelength. The latter is commonly measured in W⋅m−2⋅nm−1. "Spectral emittance" is an old term for this quantity. This is sometimes also confusingly called "spectral intensity".
Radiant exposure He joule per square metre J/m2 MT−2 Radiant energy received by a surface per unit area, or equivalently irradiance of a surface integrated over time of irradiation. This is sometimes also called "radiant fluence".
Spectral exposure He,ν[nb 3]
or
He,λ[nb 4]
joule per square metre per hertz
or
joule per square metre, per metre
J⋅m−2⋅Hz−1
or
J/m3
MT−1
or
ML−1T−2
Radiant exposure of a surface per unit frequency or wavelength. The latter is commonly measured in J⋅m−2⋅nm−1. This is sometimes also called "spectral fluence".
Hemispherical emissivity ε 1 Radiant exitance of a surface, divided by that of a black body at the same temperature as that surface.
Spectral hemispherical emissivity εν
or
ελ
1 Spectral exitance of a surface, divided by that of a black body at the same temperature as that surface.
Directional emissivity εΩ 1 Radiance emitted by a surface, divided by that emitted by a black body at the same temperature as that surface.
Spectral directional emissivity εΩ,ν
or
εΩ,λ
1 Spectral radiance emitted by a surface, divided by that of a black body at the same temperature as that surface.
Hemispherical absorptance A 1 Radiant flux absorbed by a surface, divided by that received by that surface. This should not be confused with "absorbance".
Spectral hemispherical absorptance Aν
or
Aλ
1 Spectral flux absorbed by a surface, divided by that received by that surface. This should not be confused with "spectral absorbance".
Directional absorptance AΩ 1 Radiance absorbed by a surface, divided by the radiance incident onto that surface. This should not be confused with "absorbance".
Spectral directional absorptance AΩ,ν
or
AΩ,λ
1 Spectral radiance absorbed by a surface, divided by the spectral radiance incident onto that surface. This should not be confused with "spectral absorbance".
Hemispherical reflectance R 1 Radiant flux reflected by a surface, divided by that received by that surface.
Spectral hemispherical reflectance Rν
or
Rλ
1 Spectral flux reflected by a surface, divided by that received by that surface.
Directional reflectance RΩ 1 Radiance reflected by a surface, divided by that received by that surface.
Spectral directional reflectance RΩ,ν
or
RΩ,λ
1 Spectral radiance reflected by a surface, divided by that received by that surface.
Hemispherical transmittance T 1 Radiant flux transmitted by a surface, divided by that received by that surface.
Spectral hemispherical transmittance Tν
or
Tλ
1 Spectral flux transmitted by a surface, divided by that received by that surface.
Directional transmittance TΩ 1 Radiance transmitted by a surface, divided by that received by that surface.
Spectral directional transmittance TΩ,ν
or
TΩ,λ
1 Spectral radiance transmitted by a surface, divided by that received by that surface.
Attenuation coefficient αΩ 1 Radiance absorbed and scattered by a volume per unit length, divided by that received by that volume.
Spectral attenuation coefficient αΩ,ν
or
αΩ,λ
1 Spectral radiance absorbed and scattered by a volume per unit length, divided by that received by that volume.
See also: SI · Radiometry · Photometry
  1. ^ Standards organizations recommend that radiometric quantities should be denoted with suffix "e" (for "energetic") to avoid confusion with photometric or photon quantities.
  2. ^ a b c d e Alternative symbols sometimes seen: W or E for radiant energy, P or F for radiant flux, I for irradiance, W for radiant exitance.
  3. ^ a b c d e f g Spectral quantities given per unit frequency are denoted with suffix "ν" (Greek)—not to be confused with suffix "v" (for "visual") indicating a photometric quantity.
  4. ^ a b c d e f g Spectral quantities given per unit wavelength are denoted with suffix "λ" (Greek).
  5. ^ a b Directional quantities are denoted with suffix "Ω" (Greek).
  6. ^ NOAA / Space Weather Prediction Center includes a definition of the solar flux unit (SFU).


See also[edit]

References[edit]

  1. ^ a b c IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version:  (2006–) "Absorbance".
  2. ^ Christopher Robert Kitchin (1987). Stars, Nebulae and the Interstellar Medium: Observational Physics and Astrophysics. CRC Press. 

External links[edit]