|Jmol-3D images||Image 1|
|Molar mass||122.42 g/mol|
|Melting point||750 ºC decomp.|
|Solubility in water||insoluble|
|Solubility||insoluble in acid
slightly soluble in aqua regia
|EU Index||Not listed|
|Other anions||Palladium sulfide|
|Other cations||Nickel(II) oxide|
|Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)|
|(what is: / ?)|
Palladium(II) oxide is the inorganic compound of formula PdO. It is the only well characterised oxide of palladium. It is prepared by treating the metal with oxygen. Above about 900 °C, the oxide reverts to palladium metal and oxygen gas. It is not attacked by acids.
PdO is often obtained as a poorly defined material that is generated for applications as a catalyst (see Adams catalyst). Palladium oxide is prepared by heating palladium sponge in oxygen at 350 °C.
- 2 Pd + O2 → 2 PdO
- 2 PdCl2 + 4 KNO3 → 2 PdO + 4 KCl + 2 NO2 + O2 (possible reaction)
or the product of dissolving palladium in aqua regia, followed by the addition of sodium nitrate at 600 °C. A hydrated form of the oxide (which dissolves in acid) can be prepared by precipitation from solution, for example, by hydrolysis of palladium nitrate or reaction of a soluble palladium compound with a strong base. The brown hydrated oxide converts to black anhydrous oxide on heating. Its susceptibility to attack by acids decreases at lower water content.
- Greenwood, Norman N.; Earnshaw, Alan (1984). Chemistry of the Elements. Oxford: Pergamon Press. pp. 1336–37. ISBN 0-08-022057-6.
- Donald Starr and R. M. Hixon (1943), "Tetrahydrofuran", Org. Synth.; Coll. Vol. 2: 566
- Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1965, NY. Vol. 2. p. 1583.
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