Phosphoryl nitride in chemistry is a reactive intermediate with the structure OPN. It is a linear oxygen phosphorus nitrogen molecule with a formal double bond between P and O (phosphoryl) and a triple bond (nitride) between P and N. It can be obtained in argon matrix isolation at 16 K by laser photolysis of phosphoryl triazide, OP(N3)3. OPN and its isomer ONP can interconvert by photoisomerization.
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- Elusive O═P≡N, a Rare Example of Phosphorus σ2λ5-Coordination Xiaoqing Zeng, Helmut Beckers, and Helge Willner Journal of the American Chemical Society 2011 133 (51), 20696-20699 doi:10.1021/ja2091867