The compilation debuted at No. 26 in the United Kingdom album chart on 2 September 2007. This represents Starr's highest UK album chart peak since 1974, when the Goodnight Vienna album debuted and peaked at No. 30. The album stayed in the UK Top 100 chart for three weeks. The album also had a 2-week chart run in the United States, where it debuted at No. 130 with 5,426 copies sold during the first week of release.
This album is notable for including all of the songs from the first Ringo Starr's greatest hits compilation Blast from Your Past.
The track listing and title for the iTunes release differs from the standard release. Unlike the standard CD release, the digital album contains "Oo-Wee" (from Goodnight Vienna), "Have You Seen My Baby" and an extended version of "Six O'Clock" (both from Ringo) in favor of "Hey! Baby", "A Dose of Rock 'n' Roll" and "King of Broken Hearts." A digital booklet was also included with the purchase of Photograph: The Digital Hits.