Phthalocyanine Blue BN

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Copper Phtalocyanine Blue.JPG
Phthalocyanine blue pigment powder
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Hex triplet #000f89
sRGBB  (rgb) (0, 15, 137)
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Phthalocyanine Blue BN, also called Monastral blue, phthalo blue (and others) (CAS 147-14-8, EINECS 205-685-1), is a bright, crystalline, synthetic blue pigment from the group of phthalocyanine dyes.

It was first developed as a pigment in the mid-1930s. Its brilliant blue is frequently used in paints and dyes. It is highly valued for its superior properties such as light fastness, tinting strength, covering power and resistance to the effects of alkalies and acids. It has the appearance of a blue powder, insoluble in water and most solvents. The anecdotal history of the compound is that a chemist at the ICI phthalimide plant was troubled by blue contamination of the product. This was traced to a by-product formed when the phthalimide reacted with trace amounts of iron from the metal reactor. The chemist took samples of this blue and using sulfuric acid as a solvent, managed to produce a workable pigment. This was converted into the copper centered blue and sold under the trade name Monastral. Difficulty was experienced in forming stable dispersions with the first alpha forms, especially in mixtures with rutile Titanium, where the blue pigment tended to flocculate. The beta form was more stable, as was the improved stabilized alpha form. Today, there are even more isomeric forms available.

Synonyms and trade names[edit]

The substance, chemical name (29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32)copper (or copper phthalocyanine),[1] is also known as monastral blue, phthalo blue, helio blue, thalo blue, Winsor blue, phthalocyanine blue, C.I. Pigment Blue 15:2, Copper phthalocyanine blue, Copper tetrabenzoporphyrazine, Cu-Phthaloblue, PB-15, PB-36, and C.I. 74160. Numerous other trade names and synonyms exist.[2] The abbreviation "CuPc" is also used.[3]

Applications[edit]

Ink[edit]

Due to its stability, phthalo blue is also used in inks, coatings, and many plastics. The pigment is insoluble and has no tendency to migrate in the material. It is a standard pigment used in printing ink and the packaging industry.

A common component on the artist's palette, phthalo blue is a cool blue with a bias towards green. It has intense tinting strength and easily overpowers the mix when combined with other colors. It is a transparent staining color and can be applied using glazing techniques.

Industrial production was of the order of 10,000 tonnes pa in the 1980–90s in Japan alone.[2] The pigment is the highest volume pigment produced.[4]

Phthalocyanine Blue BN is also used as a source material for manufacture of Phthalocyanine Green G.

Photovoltaics[edit]

Copper phthalocyanine, often referred to as CuPc, is also a leading material used in organic solar cell research.

Quantum computing[edit]

The compound may also have uses in the development of quantum computing due to the length of time its electrons can exist in a state of quantum superposition.[5] CuPc can be easily processed into a thin film for use in device fabrication, which makes it an attractive qubit candidate.[6]

Structure, reactivity and properties[edit]

Phthalocyanine Blue BN

Phthalocyanine blue (C32H16N8Cu) a complex of copper with phthalocyanine. Molecular mass is 576.08,[1] melting point 600 °C (with decomposition), the substance is practically insoluble in water (< 0.1 g/100 ml at 20 °C),[1] but soluble in concentrated sulfuric acid.[2] Density of the solid is ~1.6 g/cm3.[2] The color is due to a π-π* electronic transition, with λmax ~ 610 nm.[7]

Toxicity and hazards[edit]

The compound is non-biodegradeable, but not toxic to fish or plants.[2] No specific dangers have been associated with this compound.[8] Oral LD50 in mammals is estimated to be greater than 5 g per kg, with no ill effects found at that level of ingestion,[2] for chronic ingestion levels of concern were found to occur at 0.2 g/kg or greater.[2] There is no evidence for carcinogenic effects yet known.[2] There is some evidence that exposure to phthalocyanines can cause serious birth defects in developing embryos.[9]

See also[edit]

References[edit]

  1. ^ a b c Copper phthalocyanine chemblink.com
  2. ^ a b c d e f g h COPPER PHTHALOCYANINE, CAS No.: 147-14-8 inchem.org
  3. ^ e.g. Structural and Transport Properties of Copper Phthalocyanine (CuPc) Thin Films www.egmrs.org
  4. ^ Industrial applications of phthalocyanines. Author : Peter Gregory, Journal of Porphyrins and Phthalocyanines (JPP) Vol 4 Issue 4 Year 2000 via worldscinet.com
  5. ^ Warner, Marc; et al. (October 26, 2013). "New Material for Quantum Computing Discovered Out of the Blue". Nature. Retrieved November 3, 2013. 
  6. ^ Quenqua, Douglas (November 4, 2013). "A Key to Quantum Computing, Close to Home". The New York Times. 
  7. ^ H. S. Rzepa, www.ch.imperial.ac.uk/rzepa/blog/?p=3641, Accessed: 2011-03-08. (Archived by WebCite® at http://www.webcitation.org/5x2Q0jeBj)
  8. ^ Safety data sheet cornelius.co.uk
  9. ^ "Sulphonated phthalocyanine induced caudal malformative syndrome in the chick embryo." (Abstract), Sandor S, Prelipceanu O, and Checiu I., U.S. National Library of Medicine National Institutes of Health

External links[edit]