Phycourobilin

From Wikipedia, the free encyclopedia
Jump to: navigation, search
Phycourobilin
Phycourobilin.png
Identifiers
CAS number 61932-71-6 YesY
PubChem 5289229
Jmol-3D images Image 1
Properties
Molecular formula C33H42N4O6
Molar mass 590.71
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
 YesY (verify) (what is: YesY/N?)
Infobox references

Phycourobilin is a tetrapyrrole orange molecule involved in photosynthesis in cyanobacteria and red algae. This chromophore is bound to the phycobiliprotein phycoerythrin, the distal component of the light-harvesting system of cyanobacteria and red algae (phycobilisome).

When bound to phycoerythrin, phycourobilin shows an absorption maximum around 495 nm. This chromophore is always a donor chromophore of phycoerythrins, since their acceptor chromophore is always phycoerythrobilin. It can also be linked to the linker polypeptides of the phycobilisome, in which its precise role remains unclear.

Phycourobilin is found in marine phycobilisome containing organisms, allowing them to efficiently absorb blue-green light. In the ubiquitous marine cyanobacteria Synechococcus, the amount of phycourobilin in the phycobilisomes is correlated to the ecological niche the cells inhabit: offshore Synechococcus are quite phycourobililin-rich, while coastal Synechococcus contain very little or no phycourobilin. This represents a remarkable adaptation of the cyanobacterial light-harvesting system, as oceanic waters are relatively richer in blue light than onshore waters.

References[edit]