Polonium hexafluoride

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Polonium hexafluoride
Identifiers
CAS number 35473-38-2
Properties
Molecular formula PoF6
Molar mass 322.97 g/mol
Appearance white solid
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
Infobox references

Polonium hexafluoride (PoF6) is a possible chemical compound of polonium and fluorine and one of the seventeen known binary hexafluorides.[1]

Synthesis[edit]

Unsuccessful[edit]

The synthesis of PoF6 via the reaction

Po + 3 F
2
PoF
6

was attempted in 1945, but the attempt was unsuccessful. The boiling point was predicted to be about −40 °C.[2]

Successful[edit]

PoF6 may have been successfully synthesised via the fluorination of polonium metal,[1]:594 where a volatile polonium fluoride was produced, but it was not fully characterized.[3]

References[edit]

  1. ^ a b Holleman, A. F.; Wiberg, E. (2001), Inorganic Chemistry, San Diego: Academic Press, p. 594, ISBN 0-12-352651-5 
  2. ^ Summary of work to date on volatile neutron source, Monsanto Chemical Company, Unit 3 abstracts of progress reports, August 16–31, 1945; Abstract; PDF.
  3. ^ Weinstock, B., Chernick, C.L.: The preparation of a volatile polonium fluoride. J. Am. Chem. Soc. 82, 4116–4117 (1960)

.