From Wikipedia, the free encyclopedia
Jump to: navigation, search

A polyamide is a macromolecule with repeating units linked by amide bonds. [1] Polyamides occur both naturally and artificially. Examples of naturally occurring polyamides are proteins, such as wool and silk. Artificially made polyamides can be made through step-growth polymerization or solid-phase synthesis yielding materials such as nylons, aramids, and sodium poly(aspartate). Synthetic polyamides are commonly used in textiles, automotive applications, carpets and sportswear due to their high durability and strength. The transportation industry is the major consumer, accounting for 35% of polyamide (PA) consumption. [2]


According to the composition of their main chain, polyamides are classified as follows:

Polyamide family Main chain Examples of polyamides Examples of commercial products
Aliphatic polyamides Aliphatic PA 6 and PA 66 Nylon from DuPont, Technyl from Solvay, Rilsan and Rilsamid from Arkema
Polyphthalamides Semi-aromatic PA 6T = hexamethylenediamine + terephthalic acid Trogamid from Evonik Industries, Amodel from Solvay
Aramides = aromatic polyamides Aromatic Paraphenylenediamine + terephthalic acid Kevlar and Nomex from DuPont, Teijinconex, Twaron and Technora from Teijin, Kermel from Kermel, and Spectra[disambiguation needed] from Honeywell.

According to the number of types of repeating units, polyamides can be:

  • homopolymers :
    • PA 6 : [NH−(CH2)5−CO]n made from ε-Caprolactam ;
    • PA 66 : [NH−(CH2)6−NH−CO−(CH2)4−CO]n made from hexamethylenediamine and adipic acid;
  • copolymers :
    • PA 6/66 : [NH-(CH2)6−NH−CO−(CH2)4−CO]n−[NH−(CH2)5−CO]m made from caprolactam, hexamethylenediamine and adipic acid ;
    • PA 66/610 : [NH−(CH2)6−NH−CO−(CH2)4−CO]n−[NH−(CH2)6−NH−CO−(CH2)8−CO]m made from hexamethylenediamine, adipic acid and sebacic acid.

According to their crystallinity, polyamides can be:

According to this classification, PA66, for example, is an aliphatic semi-crystalline homopolyamide.

Production from monomers[edit]

The amide link is produced from the condensation reaction of an amino group and a carboxylic acid or acid chloride group. A small molecule, usually water, or hydrogen chloride, is eliminated.

The amino group and the carboxylic acid group can be on the same monomer, or the polymer can be constituted of two different bifunctional monomers, one with two amino groups, the other with two carboxylic acid or acid chloride groups.

Amino acids can be taken as examples of single monomer (if the difference between R groups is ignored) reacting with identical molecules to form a polyamide:

The reaction of two amino acids. Many of these reactions produce long chain proteins

Aramid (pictured below) is made from two different monomers which continuously alternate to form the polymer and is an aromatic polyamide:

The reaction of 1,4-phenyl-diamine (para-phenylenediamine) and terephthaloyl chloride to produce Aramid

Current market and forecast[edit]

As one of the largest engineering polymer families, the global demand of polyamide resins and compounds was valued at roughly US$20.5 billion in 2013. The market is expected to reach US$30 billion by 2020 by following an average annual growth of 5.5%.[3]

See also[edit]


  1. ^ Palmer, R. J. 2001. Polyamides, Plastics. Encyclopedia Of Polymer Science and Technology. doi:10.1002/0471440264.pst251
  2. ^ Market Study Engineering Plastics, Ceresana, Sep 2013 [1]
  3. ^ "Market Report: Global Polyamide Market". Acmite Market Intelligence.