Rechargeable battery

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A battery bank used for an uninterruptible power supply in a data center
A rechargeable lithium polymer mobile phone battery
A common consumer battery charger for rechargeable AA and AAA batteries

A rechargeable battery, storage battery, or accumulator is a type of electrical battery. It comprises one or more electrochemical cells, and is a type of energy accumulator used for electrochemical energy storage. It is technically known as a secondary cell because its electrochemical reactions are electrically reversible. Rechargeable batteries come in many different shapes and sizes, ranging from button cells to megawatt systems connected to stabilize an electrical distribution network. Several different combinations of chemicals are commonly used, including: lead–acid, nickel cadmium (NiCd), nickel metal hydride (NiMH), lithium ion (Li-ion), and lithium ion polymer (Li-ion polymer).

Rechargeable batteries have a lower total cost of use and environmental impact than disposable batteries. Some rechargeable battery types are available in the same sizes as common consumer disposable types. Rechargeable batteries have a higher initial cost but can be recharged inexpensively and reused many times.

Usage and applications[edit]

Rechargeable batteries are used for automobile starters, portable consumer devices, light vehicles (such as motorized wheelchairs, golf carts, electric bicycles, and electric forklifts), tools, and uninterruptible power supplies. Emerging applications in hybrid electric vehicles and electric vehicles are driving the technology to reduce cost and weight and increase lifetime.[1]

Traditional rechargeable batteries have to be charged before their first use; newer low self-discharge NiMH batteries hold their charge for many months, and are typically charged at the factory to about 70% of their rated capacity before shipping.

Grid energy storage applications use rechargeable batteries for load leveling, where they store electric energy for use during peak load periods, and for renewable energy uses, such as storing power generated from photovoltaic arrays during the day to be used at night. By charging batteries during periods of low demand and returning energy to the grid during periods of high electrical demand, load-leveling helps eliminate the need for expensive peaking power plants and helps amortize the cost of generators over more hours of operation.

The US National Electrical Manufacturers Association has estimated that US demand for rechargeable batteries is growing twice as fast as demand for nonrechargeables.[2]

Rechargeable batteries are used for mobile phones, laptops, mobile power tools like cordless screwdrivers. They are used as electric vehicle battery for example in electric cars, electric motorcycles and scooters, electric buses, electric trucks. In most submarines they are used to drive under water. In diesel-electric transmission they are used in ships, in locomotives and huge trucks. They are also used in distributed electricity generation and stand-alone power systems.

Charging and discharging[edit]

A solar-powered charger for rechargeable AA batteries
Further information: Battery charger

During charging, the positive active material is oxidized, producing electrons, and the negative material is reduced, consuming electrons. These electrons constitute the current flow in the external circuit. The electrolyte may serve as a simple buffer for internal ion flow between the electrodes, as in lithium-ion and nickel-cadmium cells, or it may be an active participant in the electrochemical reaction, as in lead–acid cells.

The energy used to charge rechargeable batteries usually comes from a battery charger using AC mains electricity, although some are equipped to use a vehicle's 12-volt DC power outlet. Regardless, to store energy in a secondary cell, it has to be connected to a DC voltage source. The negative terminal of the cell has to be connected to the negative terminal of the voltage source and the positive terminal of the voltage source with the positive terminal of the battery. Further, the voltage output of the source must be higher than that of the battery, but not much higher: the greater the difference between the power source and the battery's voltage capacity, the faster the charging process, but also the greater the risk of overcharging and damaging the battery.

Chargers take from a few minutes to several hours to charge a battery. Slow "dumb" chargers without voltage or temperature-sensing capabilities will charge at a low rate, typically taking 14 hours or more to reach a full charge. Rapid chargers can typically charge cells in two to five hours, depending on the model, with the fastest taking as little as fifteen minutes. Fast chargers must have multiple ways of detecting when a cell reaches full charge (change in terminal voltage, temperature, etc.) to stop charging before harmful overcharging or overheating occurs. The fastest chargers often incorporate cooling fans to keep the cells from overheating.

Diagram of the charging of a secondary cell battery.

Battery charging and discharging rates are often discussed by referencing a "C" rate of current. The C rate is that which would theoretically fully charge or discharge the battery in one hour. For example, trickle charging might be performed at C/20 (or a "20 hour" rate), while typical charging and discharging may occur at C/2 (two hours for full capacity). The available capacity of electrochemical cells varies depending on the discharge rate. Some energy is lost in the internal resistance of cell components (plates, electrolyte, interconnections), and the rate of discharge is limited by the speed at which chemicals in the cell can move about. For lead-acid cells, the relationship between time and discharge rate is described by Peukert's law; a lead-acid cell that can no longer sustain a usable terminal voltage at a high current may still have usable capacity, if discharged at a much lower rate. Data sheets for rechargeable cells often list the discharge capacity on 8-hour or 20-hour or other stated time; cells for uninterruptible power supply systems may be rated at 15 minute discharge.

Battery manufacturers' technical notes often refer to VPC; this is volts per cell, and refers to the individual secondary cells that make up the battery. (This is typically in reference to 12-volt lead-acid batteries.) For example, to charge a 12 V battery (containing 6 cells of 2 V each) at 2.3 VPC requires a voltage of 13.8 V across the battery's terminals.

Non-rechargeable alkaline and zinc–carbon cells output 1.5V when new, but this voltage drops with use. Most NiMH AA and AAA cells are rated at 1.2 V, but have a flatter discharge curve than alkalines and can usually be used in equipment designed to use alkaline batteries.

Damage from cell reversal[edit]

Subjecting a discharged cell to a current in the direction which tends to discharge it further, rather than charge it, is called reverse charging. Generally, pushing current through a discharged cell in this way causes undesirable and irreversible chemical reactions to occur, resulting in permanent damage to the cell. Reverse charging can occur under a number of circumstances, the two most common being:

  • When a battery or cell is connected to a charging circuit the wrong way around.
  • When a battery made of several cells connected in series is deeply discharged.

In the latter case, the problem occurs due to the different cells in a battery having slightly different capacities. When one cell reaches discharge level ahead of the rest, the remaining cells will force the current through the discharged cell. This is known as "cell reversal". Many battery-operated devices have a low-voltage cutoff that prevents deep discharges from occurring that might cause cell reversal.

Cell reversal can occur to a weakly charged cell even before it is fully discharged. If the battery drain current is high enough, the cell's internal resistance can create a resistive voltage drop that is greater than the cell's forward emf. This results in the reversal of the cell's polarity while the current is flowing.[3][4] The higher the required discharge rate of a battery, the better matched the cells should be, both in the type of cell and state of charge, in order to reduce the chances of cell reversal.

In some situations, such as when correcting Ni-Cad batteries that have been previously overcharged,[5] it may be desirable to fully discharge a battery. To avoid damage from the cell reversal effect, it is necessary to access each cell separately: each cell is individually discharged by connecting a load clip across the terminals of each cell, thereby avoiding cell reversal.

Damage during storage in fully discharged state[edit]

If a multi-cell battery is fully discharged, it will often be damaged due to the cell reversal effect mentioned above. It is possible however to fully discharge a battery without causing cell reversal—either by discharging each cell separately, or by allowing each cell's internal leakage to dissipate its charge over time.

Even if a cell is brought to a fully discharged state without reversal, however, damage may occur over time simply due to remaining in the discharged state. An example of this is the sulfation that occurs in lead-acid batteries that are left sitting on a shelf for long periods. For this reason it is often recommended to charge a battery that is intended to remain in storage, and to maintain its charge level by periodically recharging it. Since damage may also occur if the battery is overcharged, the optimal level of charge during storage is typically around 30% to 70%.

Depth of discharge[edit]

Main article: Depth of discharge

Depth of discharge (DOD) is normally stated as a percentage of the nominal ampere-hour capacity; 0% DOD means no discharge. Seeing as the usable capacity of a battery system depends on the rate of discharge and the allowable voltage at the end of discharge, the depth of discharge must be qualified to show the way it is to be measured. Due to variations during manufacture and aging, the DOD for complete discharge can change over time or number of charge cycles. Generally a rechargeable battery system will tolerate more charge/discharge cycles if the DOD is lower on each cycle.[6]

Active components[edit]

The active components in a secondary cell are the chemicals that make up the positive and negative active materials, and the electrolyte. The positive and negative are made up of different materials, with the positive exhibiting a reduction potential and the negative having an oxidation potential. The sum of these potentials is the standard cell potential or voltage.

In primary cells the positive and negative electrodes are known as the cathode and anode, respectively. Although this convention is sometimes carried through to rechargeable systems — especially with lithium-ion cells, because of their origins in primary lithium cells — this practice can lead to confusion. In rechargeable cells the positive electrode is the cathode on discharge and the anode on charge, and vice versa for the negative electrode.

Types[edit]

Type Voltagea Energy densityb Powerc E/$e Disch.f Cyclesg Lifeh
(V) (MJ/kg) (Wh/kg) (Wh/L) (W/kg) (Wh/$) (%/month) (#) (years)
Lead–acid 2.1 0.11-0.14 30-40 60-75 180 5-8 3-4% 500-800 5-8 (automotive battery), 20 (stationary)
Alkaline 1.5 0.31 85 250 50 7.7 <0.3 100-1000 <5
Nickel–iron 1.2 0.18 50 100 5-7.3[7] 20-40% 50+
Nickel–cadmium 1.2 0.14-0.22 40-60 50-150 150 1.25-2.5[7] 20% 1500
Nickel–hydrogen 1.5 0.27 75 60 220 20,000+ 15+ (satellite application with frequent charge-discharge cycles)
Nickel–metal hydride 1.2 0.11-0.29 30-80 140-300 250-1000 2.75 30% 500-1000
Nickel–zinc 1.7 0.22 60 170 900 2-3.3 100-500
Lithium-air (organic)[8] 2.7 7.2 2000 2000 400 ~100
Lithium Cobalt Oxide 3.6 0.58 150-250 250-360 1800 2.8-5[9] 5-10% 400–1200[10] 2-6
Lithium-ion polymer 3.7 0.47-0.72 130-200 300 3000+ 2.8-5.0 5% 500~1000 2-3
Lithium iron phosphate 3.25 0.32-0.4 80-120 170[citation needed] 1400 0.7-3.0[11] >10.000 90% DOD[12] >10
Lithium sulfur[13] 2.0 0.94-1.44[14] 400[15] 350 ~1400[16]
Lithium–titanate 2.3 0.32 90 4000+ 0.5-1.0[citation needed] 9000+ 20+
Sodium-ion[17] 1.7 30 3.3 5000+ Testing
Thin film lithium  ? 300[18] 959[18] 6000[18]  ?p[18] 40000[18]
Zinc-bromide 0.27-0.31 75-85
Zinc-cerium 2.5[19] Under testing
Vanadium redox 1.15-1.55 0.09-0.13 25-35[20] 20%[21] 14,000[22] 10 (stationary)[21]
Sodium-sulfur 0.54 150
Molten salt 2.58 0.25-1.04 70-290[23] 160[7] 150-220 4.54[24] 3000+ <=20
Silver-oxide 1.86 0.47 130 240
Quantum Battery (oxide semiconductor)[25][26] 1.5-3 500 8000(W/L) 100,000
Notes
Graph of mass and volume energy densities of several secondary cells
  • b Energy density = energy/weight or energy/size, given in three different units
  • c Specific power = power/weight in W/kg
  • e Energy/consumer price in W·h/US$ (approximately)
  • f Self-discharge rate in %/month
  • g Cycle durability in number of cycles
  • h Time durability in years
  • i VRLA or recombinant includes gel batteries and absorbed glass mats
  • p Pilot production
  • r Depending upon charge rate

Common[edit]

The nickel–cadmium battery (NiCd) was created by Waldemar Jungner of Sweden in 1899. It uses nickel oxide hydroxide and metallic cadmium as electrodes. Cadmium is a toxic element, and was banned for most uses by the European Union in 2004. Nickel–cadmium batteries have been almost completely superseded by nickel–metal hydride (NiMH) batteries.

The nickel–metal hydride battery (NiMH) became available in 1989.[27] These are now a common consumer and industrial type. The battery has a hydrogen-absorbing alloy for the negative electrode instead of cadmium.

The lithium-ion battery is the choice in most consumer electronics and have the best energy density and a very slow loss of charge when not in use.

The Lithium-ion polymer battery is light in weight and can be made in any shape desired.

Experimental types[edit]

The lithium sulfur battery was developed by Sion Power in 1994.[28] The company claims superior energy density to other lithium technologies.[29]

The thin film battery (TFB) is a refinement of lithium ion technology by Excellatron.[30] The developers claim a large increase in recharge cycles to around 40,000 and higher charge and discharge rates, at least 5 C charge rate. Sustained 60 C discharge and 1000C peak discharge rate and a significant increase in specific energy, and energy density.[31] Infinite Power Solutions makes TFB for microelectronic applications.[32]

A smart battery has voltage monitoring circuit built inside. Carbon foam-based lead acid battery: Firefly Energy developed a carbon foam-based lead acid battery with a reported energy density of 30-40% more than their original 38 Wh/kg,[33] with long life and very high power density.

The potassium-ion battery delivers around a million cycles, due to the extraordinary electrochemical stability of potassium insertion/extraction materials such as Prussian blue.

The sodium-ion battery is meant for stationary storage and competes with lead–acid batteries. It aims at a low total cost of ownership per kWh of storage. This is achieved by a long and stable lifetime. The effective number of cycles is above 5000 and the battery is not damaged by deep discharge. The energy density is rather low, somewhat lower than lead–acid.[citation needed]

The quantum Battery (oxide semiconductor) was developed by MJC. It is a small, lightweight cell with a multi-layer film structure and high energy and high power density. It is incombustible, has no electrolyte and generates a low amount of heat during charge. Its unique feature is its ability to capture electrons physically rather than chemically.[34]

In 2007, Yi Cui and colleagues at Stanford University's Department of Materials Science and Engineering discovered that using silicon nanowires as the anode of a lithium-ion battery increases the anode's volumetric charge density by up to a factor of 10, leading to the development of the nanowire battery.[35]

Another development is the paper-thin flexible self-rechargeable battery combining a thin-film organic solar cell with an extremely thin and highly flexible lithium-polymer battery, which recharges itself when exposed to light.[36]

Ceramatec, a research and development unit of CoorsTek, as of 2009 was testing a battery comprising a chunk of solid sodium metal mated to a sulfur compound by a paper-thin ceramic membrane which conducts ions back and forth to generate a current. The company claimed that it could fit about 40 kilowatt hours of energy into a package about the size of a refrigerator, and operate below 90 °C; and that their battery would allow about 3,650 discharge/recharge cycles (or roughly 1 per day for one decade).[37]

Battery electrodes can be microscopically viewed while bathed in wet electrolytes, resembling conditions inside operating batteries.[38]

In 2014, an Israeli company, StoreDot, claimed to be able to charge batteries in 30 seconds.[39][40][41]

Alternatives[edit]

A rechargeable battery is only one of several types of rechargeable energy storage systems.[42] Several alternatives to rechargeable batteries exist or are under development. For uses such as portable radios, rechargeable batteries may be replaced by clockwork mechanisms which are wound up by hand, driving dynamos, although this system may be used to charge a battery rather than to operate the radio directly. Flashlights may be driven by a dynamo directly. For transportation, uninterruptible power supply systems and laboratories, flywheel energy storage systems store energy in a spinning rotor for conversion to electric power when needed; such systems may be used to provide large pulses of power that would otherwise be objectionable on a common electrical grid.

Ultracapacitors—capacitors of extremely high value— are also used; an electric screwdriver which charges in 90 seconds and will drive about half as many screws as a device using a rechargeable battery was introduced in 2007,[43] and similar flashlights have been produced. In keeping with the concept of ultracapacitors, betavoltaic batteries may be utilized as a method of providing a trickle-charge to a secondary battery, greatly extending the life and energy capacity of the battery system being employed; this type of arrangement is often referred to as a "hybrid betavoltaic power source" by those in the industry.[44]

Ultracapacitors are being developed for transportation, using a large capacitor to store energy instead of the rechargeable battery banks used in hybrid vehicles. One drawback to capacitors compared with batteries is that the terminal voltage drops rapidly; a capacitor that has 25% of its initial energy left in it will have one-half of its initial voltage. By contrast, battery systems tend to have a terminal voltage that does not decline rapidly until nearly exhausted. The undesirable characteristic complicates the design of power electronics for use with ultracapacitors. However, there are potential benefits in cycle efficiency, lifetime, and weight compared with rechargeable systems. China started using ultracapacitors on two commercial bus routes in 2006; one of them is route 11 in Shanghai.[45]

Flow batteries, used for specialized applications, are recharged by replacing the electrolyte liquid. A flow battery can be considered to be a type of rechargeable fuel cell.

[See the separate article Battery for comparisons between battery types.]

See also[edit]

References[edit]

  1. ^ David Linden, Thomas B. Reddy (ed). Handbook Of Batteries 3rd Edition. McGraw-Hill, New York, 2002 ISBN 0-07-135978-8 chapter 22
  2. ^ "Batteries Product Stewardship | Wastes | EPA". Epa.gov. 2006-06-28. Retrieved 2012-08-14. 
  3. ^ Sequeira, C.A.C. Solid state batteries, North Atlantic Treaty Organization, Scientific Affairs Division, pp. 242-247, 254-259
  4. ^ AEROSPACE CORP EL SEGUNDO CA CHEMISTRY AND PHYSICS LAB. Nickel-Cadmium Battery Cell Reversal from Resistive Network Effects: Computer simulations of short-down on a variety of battery configurations, DTIC Online website.
  5. ^ Zaun, James A. NiCd Batteries do NOT have "memory", RepairFAQ.org website, September 24, 1996.
  6. ^ Reddy, Handbook of Batteries page 22-20
  7. ^ a b c "mpoweruk.com: Accumulator and battery comparisons (pdf)" (PDF). Retrieved 2012-08-14. 
  8. ^ [1][dead link]
  9. ^ http://www.werbos.com/E/WhoKilledElecPJW.htm (which links to http://www.thunder-sky.com/home_en.asp)
  10. ^ Battery Types and Characteristics for HEV ThermoAnalytics, Inc., 2007. Retrieved 11 June 2010.
  11. ^ alibaba.com
  12. ^ GWL-Power: Winston 90Ah over 10.000 /13.000 cycles, PDF, 21. February 2012.
  13. ^ Lithium_Sulfur[dead link]
  14. ^ "Solar plane makes record flight". BBC News. 24 August 2008. Retrieved 10 April 2010. 
  15. ^ Patent 6358643, PolyPlus.com website.[dead link]
  16. ^ Research News: A longer life for lithium-sulfur batteries, Fraunhofer.de website, April 2013.
  17. ^ Bullis, Kevin (2014-02-18). "How to Make a Cheap Battery for Storing Solar Power | MIT Technology Review". Technologyreview.com. Retrieved 2014-04-27. 
  18. ^ a b c d e "the Company". Excellatron. Retrieved 2012-08-14. 
  19. ^ Xie, Z.; Liu, Q.; Chang, Z.; Zhang, X. (2013). "The developments and challenges of cerium half-cell in zinc–cerium redox flow battery for energy storage". Electrochimica Acta 90: 695–704. doi:10.1016/j.electacta.2012.12.066. 
  20. ^ "Vanadium Redox Battery". Vrb.unsw.edu.au. Retrieved 2012-08-14. 
  21. ^ a b broken link[dead link]
  22. ^ The Vanadium Advantage: Flow Batteries Put Wind Energy in the Bank[dead link]
  23. ^ "Sumitomo considering marketing new lower-temperature molten-salt electrolyte battery to automakers for EVs and hybrids". Green Car Congress. 2011-11-11. Retrieved 2012-04-24. 
  24. ^ "EVWORLD FEATURE: Fuel Cell Disruptor - Part 2:BROOKS FUEL CELL | CARB | ARB | HYDROGEN | ZEBRA | EV | ELECTRIC". Evworld.com. Retrieved 2012-08-14. 
  25. ^ "Study of secondary battery semiconductor". Hiroshima University. 2011-11-25. Retrieved 2014-01-18. 
  26. ^ "Notice of the development of mass production technology of Secondary battery "battenice" based on quantum technology". MICRONICS JAPAN. 2013-11-19. Retrieved 2014-01-18. 
  27. ^ Katerina E. Aifantis et al, High Energy Density Lithium Batteries: Materials, Engineering, Applications Wiley-VCH, 2010 ISBN 3-527-32407-0 page 66
  28. ^ "Sion Power Corporation - Advanced Energy Storage : Welcome". Sionpower.com. Retrieved 2012-08-14. 
  29. ^ "Sion Power Corporation - Advanced Energy Storage : Technology Overview". Sionpower.com. Retrieved 2012-08-14. 
  30. ^ "Excellatron". Excellatron. 2010-06-02. Retrieved 2012-08-14. 
  31. ^ "the Company". Excellatron. Retrieved 2012-08-14. 
  32. ^ "The global leader in thin-film micro-energy storage devices". Infinite Power Solutions. Retrieved 2012-04-24. 
  33. ^ "Firefly Energy Eyeing the Hybrid Market; Lead-Acid Foam Batteries for Mild-Hybrid Applications Heading to DOE for Testing and Validation". Green Car Congress. 2008-01-12. Retrieved 2012-08-14. 
  34. ^ "World Smart Energy Week 2014 e-Guidebook". Reed Exhibitions Japan Ltd. Retrieved 2014-01-18. 
  35. ^ Serpo, Alex (15 January 2008). "A tenfold improvement in battery life?". News.com. CNET. Retrieved 2008-04-12. 
    "High-performance lithium battery anodes using silicon nanowires". Nanotechnology 3, 31 - 35 (2008). Nature. 16 December 2007. doi:10.1038/nnano.2007.411. Retrieved 2008-04-12. 
  36. ^ "Technology Review, Flexible Batteries That Never Need to Be Recharged, 2007". Technologyreview.com. 2007-04-04. Retrieved 2012-08-14. 
  37. ^ "New battery could change the world, one house at a time". Heraldextra.com. 2009-04-04. Retrieved 2012-08-14. 
  38. ^ Moving Forward With Rechargeable Battery Research, EET India, 30 December 2013
  39. ^ Lilien, Niv (2014-04-09). "StoreDot: Inside the nanotech that can charge your phone in 30 seconds". ZDNet. Retrieved 2014-04-24. 
  40. ^ "Samsung spots startup's quantum-dot potential". Power-eetimes.com. 2013-11-14. Retrieved 2014-04-24. 
  41. ^ Jared Newman (2014-04-07). "StoreDot Phone Charging Works in 30 Seconds, but There’s a Catch". TIME. Retrieved 2014-04-24. 
  42. ^ Miller, Charles. Illustrated Guide to the National Electrical Code, p. 445 (Cengage Learning 2011).
  43. ^ "Capacitor-powered electric screwdriver, 2007". Ohgizmo.com. 2005-07-24. Retrieved 2012-08-14. 
  44. ^ Welcome to City Labs, CityLabs.net website.
  45. ^ 超级电容公交车专题 (Super capacitor buses topics), 52Bus.com website, August 2006 (in Chinese, archived page).

Further reading[edit]

External links[edit]