Rhodium(III) oxide

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Rhodium(III) oxide
Rhodium(III) oxide
Identifiers
12036-35-0 YesY
EC number 234-846-9
Jmol-3D images Image
PubChem 159409
Properties
Rh2O3
Molar mass 253.8092 g/mol
Appearance dark grey odorless powder
Density 8.20 g/cm3
Melting point 1,100 °C (2,010 °F; 1,370 K) (decomposes)
insoluble
Solubility insoluble in aqua regia
Structure
Crystal structure hexagonal (corundum)
Hazards
EU classification not listed
Except where noted otherwise, data is given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
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Infobox references

Rhodium(III) oxide (or Rhodium sesquioxide) is the chemical compound with the formula Rh2O3.

Structure[edit]

Rh2O3 has been found in two major forms. The hexagonal form has the corundum structure. It transforms into an orthorhombic structure when heated above 750 °C.[1]

Production[edit]

Rhodium oxide can be produced via several routes:

  • Rhodium oxide thin films can be produced by exposing Rh layer to oxygen plasma.[3]

Physical properties[edit]

Rhodium oxide films behave as a fast two-color electrochromic system: Reversible yellow ↔ dark green or yellow ↔ brown-purple color changes are obtained in KOH solutions by applying voltage ~1 V.[5]

Rhodium oxide films are transparent and conductive, like indium tin oxide (ITO) - the common transparent electrode, but Rh2O3 has 0.2 eV lower work function than ITO. Consequently, deposition of rhodium oxide on ITO improves the carrier injection from ITO thereby improving the electrical properties of organic light-emitting diodes.[3]

Applications[edit]

The major application of rhodium oxides is in catalysts, e.g. for the conversion of CO[6] or NO gases.[7]

Safety[edit]

Conditions/substances to avoid are: extreme heat, organic solvents, hydrochloric acid, hydrosulfuric acid and ammonia.

See also[edit]

References[edit]

  1. ^ J. M. D. Coey "The crystal structure of Rh2O3" Acta Cryst. (1970). B26, 1876
  2. ^ A. Wold et al. "The Reaction of Rare Earth Oxides with a High Temperature Form of Rhodium(III) Oxide" Inorg. Chem. 2 (1963) 972
  3. ^ a b S. Y. Kim et al. "Rhodium-oxide-coated indium tin oxide for enhancement of hole injection in organic light emitting diodes" Appl. Phys. Lett. 87 (2005) 072105
  4. ^ R. S. Mulukutla "Synthesis and characterization of rhodium oxide nanoparticles in mesoporous MCM-41" Phys. Chem. Chem. Phys. 1 (1999) 2027
  5. ^ S. Gottesfeld "The Anodic Rhodium Oxide Film: A Two-Color Electrochromic System" J. Electrochem. Soc. 127 (1980) 272
  6. ^ P. R. Watson and G. A. Somorjai "The hydrogenation of carbon monoxide over rhodium oxide surfaces" Journal of Catalysis 72 (1981) 347
  7. ^ R. S. Mulukutla "Characterization of rhodium oxide nanoparticles in MCM-41 and their catalytic performances for NO–CO reactions in excess O2" Applied Catalysis A: 228 (2002) 305