Robert Strutt, 4th Baron Rayleigh
Robert John Strutt, 4th Baron Rayleigh FRS (28 August 1875 – 13 December 1947) was a British peer and physicist. He discovered "active nitrogen" and was the first to distinguish the glow of the night sky.
He was born at Terling Place, the family home near Witham, Essex, the eldest son of John William Strutt, 3rd Baron Rayleigh and his wife Evelyn Georgiana Mary (née Balfour). He was thus a nephew of Arthur Balfour and of Eleanor Mildred Sidgwick. He was educated at Eton College and Trinity College, Cambridge, where he initially read mathematics, but changed after two terms to Natural Sciences. He became a research student in physics at the Cavendish Laboratory under J. J. Thomson, whose biography he subsequently wrote. His work at this time was on discharge of electricity through gases, including early work on x-rays and electrons. He wrote one of the first books on radioactivity, The Becquerel rays and the properties of radium (E. Arnold, 1904). He was awarded the Coutts Trotter studentship in 1898 and was a Fellow of Trinity College 1900–1906.
Strutt was elected a Fellow of the Royal Society in May, 1905 when his candidature citation read: "Fellow of Trinity College, Cambridge. As one who has made discoveries in Physics and as the author of the following papers: – 'On the Least Potential Difference required to Produce Discharge through Various Gases' (Phil Trans, vol cxciii, 1893); 'The Dispersion of the Cathode Rays by Magnetic Gases' (Phil Mag,, Nov, 1899); 'The Discharge of Electricity through Argon and helium' (ibid, March, 1900); 'The Behaviour of Becquerel and Rontgen Rays in a Magnetic Field' (Proc Roy Soc, vol lxvi); 'The Conductivity of Gases under Becquerel Rays' (Phil Trans, vol cxcvi, 1901); 'The Tendency of the Atomic Weights to Approximate to Whole Numbers' (Phil Mag,, March, 1901); 'The Discharge of Positive Electrification by Hot Metals' (ibid, July, 1902); 'Electrical Conductivity of Metals and their Vapours' (ibid, Nov, 1902); 'Some Recent Investigations on Electrical Conduction' (Proc Roy Inst, April, 1903); 'Preparation and Properties of an Intensely Radio-active Gas from Metallic Mercury' (Phil Mag, July, 1903); 'Radio-activity of Ordinary Materials' (ibid, June, 1903); 'Absorption of Light by Mercury and its Vapour' (ibid, July, 1903); 'The Intensely Penetrating Rays of radium' (Proc Roy Soc, lxxii); 'Fluorescence of Crystals under Rontgen Rays' (Phil Mag, Aug, 1903); 'An Experiment to Exhibit the Loss of Negative Electricity by Radium' (ibid, Nov, 1903).. He delivered their Bakerian Lecture in 1911 and 1919. He was president of the British Association for the year 1937–1938.
Strutt's best known work in the period 1904–1910 was the estimation of the age of minerals and rocks by measurement of their radium and helium content. In 1908 he was appointed Professor of Physics at Imperial College, London where he followed up his father's work on light scattering, which is now known as Rayleigh scattering, resulting in some papers published in the Proceedings of the Royal Society. He published a biography of his father, the third Baron Rayleigh, with the title of "Life of John William Strutt, third Baron Rayleigh". Photographs of Robert John Strutt when he was young can be found in this book. Both the father and son's work on light scattering was discussed by Young in 1982. A sketch of Robert John Strutt when he was old can also be found in Young (1982). (Please see reference.)
In 1910 Robert Strutt discovered that an electrical discharge in nitrogen gas produced "active nitrogen", an allotrope considered to be monatomic. The "whirling cloud of brilliant yellow light" produced by his apparatus reacted with quicksilver to produce explosive mercury nitride.
In 1916, working with his colleague Alfred Fowler, Strutt was the first to prove the existence of ozone in the atmosphere by examining the ultra-violet spectrum of the setting sun. Strutt proved that the ozone was mainly located in the upper atmosphere, in what is now called the ozone layer
Strutt inherited his title on the death of his father in 1919, becoming the 4th Baron Rayleigh. He resigned his chair at Imperial College but continued to experiment at home in the private laboratory that his father had established in an old stable block. His earlier work on gaseous discharge and fluorescence, led to further work on the luminosity of the night sky. He was the first to differentiate between two types of light from the night sky, the aurora or "northern lights", and the airglow that prevents the sky ever being completely dark anywhere on earth. In 1929 he was the first to measure the intensity of the light from the night sky. This work led to his posthumous nickname "the Airglow Rayleigh". The importance of his unpublished data was such that the US Airforce Cambridge Research Laboratories acquired it in 1963, almost by accident, at the same time of many of his father's experimental notebooks. They are now housed in the McDermott Library of the U.S. Air Force Academy, Colorado Springs, Colorado.
He died in Terling, Essex. He had married twice: firstly on 5 July 1905 Lady Mary Hilda Clements, daughter of Robert Clements 4th Earl of Leitrim (she died 1919) and secondly, in 1920, Kathleen Alice, daughter of John Coppin-Straker of Northumberland. He had five children by his first wife, including his heir John Arthur Strutt and the Hon Charles Strutt; he had a further child by his second wife.
- Egerton, A. C. (1949). "Lord Rayleigh. 1875-1947". Obituary Notices of Fellows of the Royal Society 6 (18): 502. doi:10.1098/rsbm.1949.0011. JSTOR 768938.
- A. C. Egerton, ‘Strutt, Robert John, fourth Baron Rayleigh (1875–1947)’, rev. Isobel Falconer "The Oxford Dictionary of National Biography". 2004. doi:10.1093/ref:odnb/36360.
- Lord Rayleign (1942) The Life of Sir J. J. Thomson Cambridge University Press
- Lord Rayleigh's Presidential Address at the British Association Meeting held at Cambridge in 1938
- Twersky, V. (1964). "Rayleigh Scattering". Applied Optics 3 (10): 1150. doi:10.1364/AO.3.001150.
- Strutt, R. J. (1911). "Bakerian Lecture. A Chemically Active Modification of Nitrogen, Produced by the Electric Discharge". Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences 85 (577): 219. Bibcode:1911RSPSA..85..219S. doi:10.1098/rspa.1911.0033.
- Robert John Strutt (1924)The Life of John William Strutt, 3rd Baron Rayleigh Edward Arnold
- Howard, J. N. (1964). "The Rayleigh Notebooks". Applied Optics 3 (10): 1129. doi:10.1364/AO.3.001129.
- "John Arthur Strutt, 5th Baron Rayleigh of Terling Place". www.thepeerage. Retrieved 22 October 2010.
- Howard, J. N. (1964). "John William Strutt, third Baron Rayleigh". Applied Optics 3 (10): 1091. doi:10.1364/AO.3.001091.
- Strutt, C. R. (1964). "The Optics Papers of Robert John Strutt, fourth Baron Rayleigh". Applied Optics 3 (10): 1116. doi:10.1364/AO.3.001116.
- Leigh Rayment's Peerage Pages [self-published source][better source needed]
- Andrew T. Young, "Rayleigh scattering", Physics Today, pp. 42–48 (January 1982).
- Lord Rayleigh's Active Nitrogen
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