Rotation operator (quantum mechanics)
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Quantum mechanical rotations
With every physical rotation R, we postulate a quantum mechanical rotation operator D(R) which rotates quantum mechanical states.
In terms of the generators of rotation,
Please see "rotations in quantum mechanics" for details.
The translation operator
The rotation operator , with the first argument indicating the rotation axis and the second the rotation angle, can operate through the translation operator for infinitesimal rotations as explained below. This is why, it is first shown how the translation operator is acting on a particle at position x (the particle is then in the state according to Quantum Mechanics).
Translation of the particle at position x to position x+a:
Because a translation of 0 does not change the position of the particle, we have (with 1 meaning the identity operator, which does nothing):
Taylor development gives:
From that follows:
This is a differential equation with the solution .
Additionally, suppose a Hamiltonian is independent of the position. Because the translation operator can be written in terms of , and , we know that . This result means that linear momentum for the system is conserved.
In relation to the orbital angular momentum
Classically we have for the angular momentum . This is the same in quantum mechanics considering and as operators. Classically, an infinitesimal rotation of the vector r=(x,y,z) about the z-axis to r'=(x',y',z) leaving z unchanged can be expressed by the following infinitesimal translations (using Taylor approximation):
From that follows for states:
Using from above with and Taylor development we get:
with lz = x py - y px the z-component of the angular momentum according to the classical cross product.
To get a rotation for the angle , we construct the following differential equation using the condition :
Similar to the translation operator, if we are given a Hamiltonian which rotationally symmetric about the z axis, implies . This result means that angular momentum is conserved.
For the spin angular momentum about the y-axis we just replace with and we get the spin rotation operator .
Effect on the spin operator and quantum states
where is the basis transformation matrix. If the vectors respectively are the z-axis in one basis respectively another, they are perpendicular to the y-axis with a certain angle between them. The spin operator in the first basis can then be transformed into the spin operator of the other basis through the following transformation:
From standard quantum mechanics we have the known results and where and are the top spins in their corresponding bases. So we have:
Comparison with yields .
This means that if the state is rotated about the y-axis by an angle , it becomes the state , a result that can be generalized to arbitrary axes. It is important, for instance, in Sakurai's Bell inequality.
- L.D. Landau and E.M. Lifshitz: Quantum Mechanics: Non-Relativistic Theory, Pergamon Press, 1985
- P.A.M. Dirac: The Principles of Quantum Mechanics, Oxford University Press, 1958
- R.P. Feynman, R.B. Leighton and M. Sands: The Feynman Lectures on Physics, Addison-Wesley, 1965
- Karin, Todd. Rotations in Quantum Mechanics. Unpublished Work.