The Gas Chromatograph (GC) is used to separate out individual gases from a complex mixture into molecular components. The resulting gas flow is analyzed in the mass spectrometer with a mass range of 2-535 Daltons.
The SAM also has three subsystems: the 'Chemical separation and processing laboratory', for enrichment and derivatization of the organic molecules of the sample; the sample manipulation system (SMS) for transporting powder delivered from the MSL drill to a SAM inlet and into one of 74 sample cups. The SMS then moves the sample to the SAM oven to release gases by heating to up to 1000oC; and the pump subsystem to purge the separators and analysers.
9 November 2012: A pinch of fine sand and dust became the first solid Martian sample deposited into the SAM. The sample came from the patch of windblown material called Rocknest, which had provided a sample previously for mineralogical analysis by CheMin instrument.
3 December 2012: NASA reported SAM had detected water molecules, chlorine and sulphur. Hints of organic compounds couldn't be ruled out as contamination from Curiosity itself, however.
16 December 2014: NASA reported the Curiosity rover detected a "tenfold spike", likely localized, in the amount of methane in the Martian atmosphere. Sample measurements taken "a dozen times over 20 months" showed increases in late 2013 and early 2014, averaging "7 parts of methane per billion in the atmosphere." Before and after that, readings averaged around one-tenth that level. In addition, high levels of organic chemicals, particularly chlorobenzene, were detected in powder drilled from one of the rocks, named "Cumberland", analyzed by the Curiosity rover.