sec-Butyl acetate
| sec-Butyl acetate | |
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Other names
acetic acid, sec-butyl ester; |
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| Identifiers | |
| CAS number | 105-46-4 |
| PubChem | 7758 |
| ChemSpider | 7472  |
| Jmol-3D images | Image 1 |
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| Properties | |
| Molecular formula | C6H12O2 |
| Molar mass | 116.16 g/mol |
| Appearance | clear, liquid |
| Density | 0.87 g/cm3, liquid |
| Melting point |
−99 °C, 174 K, -146 °F |
| Boiling point |
112 °C, 385 K, 234 °F |
| Solubility in water | 0.80 g/100 mL |
| Hazards | |
| MSDS | External MSDS |
| Main hazards | Flammable |
 (verify) (what is:  / ?)Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) |
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| Infobox references | |
sec-Butyl acetate, or s-butyl acetate, is a solvent commonly used as a solvent in lacquers and enamels, where it is used in the production of acyclic polymers, vinyl resins, and nitrocellulose [1]. It is a clear flammable liquid with a sweet smell[2].
sec-Butyl acetate has three isomers that are also acetate esters: n-butyl acetate, isobutyl acetate, and tert-butyl acetate.
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[edit] History
The first method of production of sec-butyl acetate was the esterification of sec-butanol and acetic anhydride[3] It was experimentally determined and published in 1946 by Rolf Altschul[4].
[edit] Toxicology
The LD50 for rats is 13 g/kg [5]. Exposure in humans to significant quantities of sec-butyl acetate can cause irritation to the eyes, mouth, throat, nose, and skin[6]. Ingestion and inhalation of sec-butyl acetate can cause central nervous system depression producing symptoms of dizziness and disorientation[6].
[edit] References
- ^ "Acetic acid", Ullman's encyclopedia of industrial chemistry (2003, 6th ed., Vol. 1, pp. 170–171). Weinheim, Germany: Wiley-VCH.
- ^ Howard, H. H. (1993). sec-Butyl acetate. In Handbook of environmental fate and exposure data for organic chemists (Vol. 5, pp. 60-65). Chelsea, MI: Lewis.
- ^ Altschul, R. (1946). "The Reversible Esterification of Carboxylic Acids with Isobutene and Trimethylethylene. Quantitative Studies and Synthetic Applications", Journal of the American Chemical Society, 68(12), 2605-2609.
- ^ O'Neil, M. J. (Ed.) (2001). sec-Butyl Acetate. In The Merck index: An encyclopedia of chemicals, drugs, and biologicals (13th ed., pg. 1539). Whitehouse Stations, NJ: Merck.
- ^ Canadian Center for Occupational Health and Safety. (1996). 2-Butyl acetate. Retrieved February 20, 2009, from CHEMINFO database.
- ^ a b International Programme on Chemical Safety. (2003). sec-Butyl acetate. Retrieved February 20, 2009, from INCHEM database.
