Silver trifluoromethanesulfonate

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Silver trifluoromethanesulfonate
Silver triflate.png
Identifiers
CAS number 2923-28-6 N
PubChem 76223
Jmol-3D images Image 1
Properties
Molecular formula CF3SO3Ag
Molar mass 256.937 g/mol
Odor odorless
Melting point 286 °C (547 °F; 559 K)
Solubility in water soluble
Hazards
MSDS Oxford MSDS
EU classification Harmful (Xn)
NFPA 704
Flammability code 0: Will not burn. E.g., water Health code 1: Exposure would cause irritation but only minor residual injury. E.g., turpentine Reactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g., liquid nitrogen Special hazards (white): no codeNFPA 704 four-colored diamond
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
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Infobox references

Silver trifluoromethanesulfonate, or silver triflate is the triflate salt of silver. Since the triflate anion is weakly coordinating, it is useful as a halide abstraction reagent. This is similar to other silver salts, e.g. the tetrafluoroborate and the hexafluorophosphate. It is useful in activating sulfur protecting groups at the anomeric centres of carbohydrates, in presence of iodine/NIS.