|Sir William Crookes|
Sir William Crookes in 1906
17 June 1832|
|Died||4 April 1919
|Influenced||J. K. F. Zöllner|
|Notable awards||Royal Medal (1875)
Davy Medal (1888)
Albert Medal (1899)
Copley Medal (1904)
Elliott Cresson Medal (1912)
Sir William Crookes, OM, FRS (17 June 1832 – 4 April 1919) was a British chemist and physicist who attended the Royal College of Chemistry, London, and worked on spectroscopy. He was a pioneer of vacuum tubes, inventing the Crookes tube which was made in 1875. Crookes was the inventor of the Crookes radiometer, which today is made and sold as a novelty item.
Crookes made a career of being a meteorologist and lecturer at multiple places. Crookes worked in chemistry and physics. His experiments were notable for the originality of their design. He executed them skilfully. His interests, ranging over pure and applied science, economic and practical problems, and psychiatric research, made him a well-known personality. He received many public and academic honors. Crookes's life was one of unbroken scientific activity.
William Crookes (later Sir William Crookes) was born in London, the eldest of 16 siblings. His father, Joseph Crookes, was a tailor of north-country origin, at that time living with his second wife, Mary Scott Lewis Rutherford Johnson.
From 1850 to 1854 he filled the position of assistant in the college, and soon embarked upon original work. It wasn't in organic chemistry which the focus of his teacher, August Wilhelm von Hofmann, might have been expected to lead him towards, but into new compounds of selenium. These were the subject of his first published papers, 1851. He worked at the department at the Radcliffe Observatory in Oxford in 1854. In 1855 he was appointed lecturer in chemistry at the Chester Diocesan Training College. In 1856 he married Ellen, daughter of William Humphrey of Darlington. They had three sons and a daughter. Married and living in London, he was devoted mainly to independent work. In 1859, he founded the Chemical News, a science magazine which he edited for many years and conducted on much less formal lines than was usual for the journals of scientific societies.
In 1861, Crookes discovered a previously unknown element with a bright green emission line in its spectrum and named the element thallium, from the Greek thallos, a green shoot. Crookes wrote a standard treatise on Select Methods in Chemical Analysis in 1871. Crookes was effective in experimentation. The method of spectral analysis, introduced by Bunsen and Kirchhoff, was received by Crookes with great enthusiasm and to great effect. His first important discovery was that of the element thallium, announced in 1861, and made with the help of spectroscopy. By this work his reputation became firmly established, and he was elected a fellow of the Royal Society in 1863.
He developed the Crookes tubes, investigating cathode rays. He published numerous papers on spectroscopy and conducted research on a variety of minor subjects. In his investigations of the conduction of electricity in low pressure gases, he discovered that as the pressure was lowered, the negative electrode (cathode) appeared to emit rays (the so-called "cathode rays", now known to be a stream of free electrons, and used in cathode ray display devices). As these examples indicate, he was a pioneer in the construction and use of vacuum tubes for the study of physical phenomena. He was, as a consequence, one of the first scientists to investigate what is now called a plasma and identified it as the fourth state of matter in 1879. He also devised one of the first instruments for the studying nuclear radioactivity, the spinthariscope.
Crookes investigated the properties of cathode rays, showing that they travel in straight lines, cause fluorescence when they fall on some substances, and that their impact can produce great heat. He believed that he had discovered a fourth state of matter, which he called "radiant matter", but his theoretical views on the nature of "radiant matter" were to be superseded. He believed the rays to consist of streams of particles of ordinary molecular magnitude. It remained for Sir J. J. Thomson to expound on the subatomic nature of cathode rays (consisting of streams of negative electrons). Nevertheless, Crookes's experimental work in this field was the foundation of discoveries which eventually changed the whole of chemistry and physics.
Crookes' attention had been attracted to the vacuum balance in the course of his research into thallium. He soon discovered the phenomenon which drives the movement in a Crookes radiometer, in which a set of vanes, each blackened on one side and polished on the other, rotate when exposed to radiant energy. Crookes did not, however, provide the true explanation of this apparent "attraction and repulsion resulting from radiation".
After 1880, he lived at 7 Kensington Park Gardens where all his later work was done, in his private laboratory.
Crookes identified the first known sample of helium, in 1895. Crookes was knighted in 1897.
In 1903, Crookes turned his attention to the newly discovered phenomenon of radioactivity, achieving the separation from uranium of its active transformation product, uranium-X (later established to be protactinium). Crookes observed the gradual decay of the separated transformation product, and the simultaneous reproduction of a fresh supply in the original uranium. At about the same time as this important discovery, he observed that when "p-particles", ejected from radio-active substances, impinge upon zinc sulfide, each impact is accompanied by a minute scintillation, an observation which forms the basis of one of the most useful methods in the technique of radioactivity.
Crookes wrote a small book on diamonds in 1909. In 1910, Crookes received the Order of Merit. He died in London on 4 April 1919, two years after his wife. He is buried in London's Brompton Cemetery.
Crookes became interested in spiritualism in the late 1860s. In this he was possibly influenced by the untimely death of his younger brother Philip in 1867 at age 21 from yellow fever contracted while on an expedition to lay a telegraph cable from Cuba to Florida. In 1867, Crookes from the influence of Cromwell Fleetwood Varley attended a séance to try and get in touch with his brother.
Between 1871 and 1874, Crookes studied the mediums Kate Fox, Florence Cook, and Daniel Dunglas Home. After his investigation he believed that the mediums could produce genuine paranormal phenomena and communicate with spirits. Psychologists Leonard Zusne and Warren H. Jones have described Crookes as gullible as he endorsed fraudulent mediums as genuine.
Edward Clodd claimed Crookes had a poor eyesight that may of explained his belief in spiritualist phenomena and quoted William Ramsay as saying Crookes is "so shortsighted that, despite his unquestioned honesty, he cannot be trusted in what he tells you he has seen." Biographer William Hodson Brock noted that Crookes was "evidently short-sighted, but did not wear spectacles until the 1890s. Until then he may have used a monocle or pocket magnifying glass when necessary. What limitations this imposed upon his psychic investigations we can only imagine."
After studying the reports of Florence Cook the science historian Sherrie Lynne Lyons wrote that the alleged spirit "Katie King" was Cook herself and at other times an accomplice. Regarding Crookes, Lyons wrote "Here was a man with a flawless scientific reputation, who discovered a new element, but could not detect a real live maiden who was masquerading as a ghost." Cook was repeatedly exposed as a fraudulent medium but she had been "trained in the arts of the séance" which managed to trick Crookes. Some researchers such as Trevor H. Hall suspected that Crookes had an affair with Cook.
In a series of experiments in London at the house of Crookes in February 1875, the medium Anna Eva Fay managed to fool Crookes into believing she had genuine psychic powers. Fay later confessed to her fraud and revealed the tricks she had used. Regarding Crookes and his experiments with mediums, the magician Harry Houdini suggested that Crookes had been deceived. The physicist Victor Stenger wrote that the experiments were poorly controlled and "his desire to believe blinded him to the chicanery of his psychic subjects."
In his quest for proof of psychic phenomena, Cookes created a physicist's experiment to reveal a "hitherto undetected force" involving a vessel filled with water sitting on a balance beam. This led to correspondence with William Carpenter and Charles Wheatstone, among others, which Crookes published, in an attempt to explain away the objections of the other scientists... with some almost farcical elements arising along the way: "You must allow me to protest against (my experiments) being ignored" (Crookes to Wheatstone, March 27, 1872, reproduced in the pamphlet published by Crookes). "Dr W.B. Carpenter...(spoke of) an experiment... It was not my experiment, but an unjustifiable misrepresentation of it". (Preface of pamphlet.)
In 1906, William Hope tricked Crookes with a fake spirit photograph of his wife. Oliver Lodge revealed there had been obvious signs of double exposure, the picture of Lady Crookes had been copied from a wedding anniversary photograph, however, Crookes was a convinced spiritualist and claimed it was genuine evidence for spirit photography.
Crookes joined the Society for Psychical Research, becoming its president in the 1890s: he also joined the Theosophical Society and the Ghost Club, of which he was president from 1907 to 1912. In 1890 he was initiated into the Hermetic Order of the Golden Dawn.
- U.S. Patent 182,172, Improvement In Apparatus For Indicating The Intensity Of Radiation
- The difference between "Crookes tubes" and "Geissler tubes" is this: In a Geissler tube the exhaustion is very much less than in a Crookes tube, the light which we see in the Geissler tube being due to the luminescence of the residual gas. (Transactions, Volume 9. Hertfordshire Natural History Society and Field Club. The Club, 1898. Page 136.)
- Alexander E. Outerbridge, Jr., A Fourth State of Matter. Lecture delivered before the Franklin Institute, 17 February 1881. Journal of the Franklin Institute of the State of Pennsylvania, Volume 81. By Franklin Institute (Philadelphia, Pa.). Page 287+.
- William Crookes, On Radiant Matter. Lecture delivered before the British Association for the Advancement of Science, at Sheffield, Friday, 22 August 1879. The Popular Science Monthly, Volume 16. D. Appleton, 1880. Pg157+
- Radio-activity induced by the oscillatory discharge, or, The subsequent radio-active emanation from substances exposed to the Tesla oscillatory discharge. Harry Marshall Diemer, Ralph Stuart Cooper. Cornell University, 1903. Page 43+.
- Chemist & Druggist, Volume 60. Benn Brothers., 1902. Pg 268.
- Negatively electrified particles whose mass is only 1/1840 that of a hydrogen atom
- Brock (2004)
- Janet Oppenheim. (1988). The Other World: Spiritualism and Psychical Research in England, 1850-1914. Cambridge University Press. pp. 343-347. ISBN 978-0521265058
- John Hannavy. (2007). Encyclopedia of Nineteenth-Century Photography. Routledge. p. 350. ISBN 978-0415972352 "Crookes' beloved younger brother had died in 1867 and the scientist hoped that spiritualism could provide a reunion. Although warned of the risk of ridicule, Crookes announced his intent to investigate mediums."
- Sherrie Lynne Lyons. (2010). Species, Serpents, Spirits, and Skulls: Science at the Margins in the Victorian Age. State University of New York Press. p. 92. ISBN 978-1438427980 "Crookes appears to have been initially attracted to spiritualism when his youngest brother, whom he was quite close to, died of yellow fever. Brought up with the traditional Christian belief in the afterlife, Crookes was persuaded to attend a séance in 1867 to try to make contact with his brother."
- Martyn Jolly. (2006). Faces of the Living dead: The Belief in Spirit Photography. Miegunyah Press. p. 30. ISBN 978-0712348997 "In 1867, he was devastated by the death of his much-loved youngest brother who, at the age of twenty-one. had caught yellow fever while laying a submarine telegraph cable in Cuba. At the time, Crookes was collaborating with a fellow electro-physicist Cromwell Fleetwood Varley, who was a pioneer of intercontinental telegraphy, as well as a clairvoyant. He persuaded Crookes to try to get in touch with his dead brother by spiritualist means."
- Daniel Cohen. (1971). Masters of the Occult. Dodd, Mead & Company. p. 111. ISBN 978-0396064077
- Andrew Neher. (2011). Paranormal and Transcendental Experience: A Psychological Examination. Dover Publications. p. 214. ISBN 978-0486261676 "William Crookes, the noted English physicist, had endorsed Catherine Fox as genuine... Crookes also endorsed several other mediums who were later exposed, including Anna Eva Fay (who was exposed more than once and who eventually explained how she duped Crookes), Florence Cook (who was the subject of more than one expose), and D. D. Home."
- Leonard Zusne; Warren H. Jones. (2014). Anomalistic Psychology: A Study of Magical Thinking. Psychology Press. p. 216. ISBN 978-0-805-80508-6 "The fact is that William Crookes, although very good at physics experiments, was rather weak on drawing inferences and on theorizing. Besides, he was gullible. He endorsed several mediums in spite of their demonstrated trickery. Having witnessed a single seance with Kate Fox, he became convinced that the Fox sisters' rappings were genuine."
- Edward Clodd. (1917). The Question: A Brief History and Examination of Modern Spiritualism. Grant Richards, London. p. 100
- William Hodson Brock. (2008). William Crookes (1832-1919) and the Commercialization of Science. Ashgate Publishing. p. 140. ISBN 978-0754663225
- Sherrie Lynne Lyons. (2010). Species, Serpents, Spirits, and Skulls: Science at the Margins in the Victorian Age. State University of New York Press. p. 101. ISBN 978-1438427980
- M. Lamar Keene. (1997). The Psychic Mafia. Prometheus Books. p. 64. ISBN 978-1573921619 "The most famous of materialization mediums, Florence Cook-- though she managed to convince a scientist, Sir William Crookes, that she was genuine-- was repeatedly exposed in fraud. Florence had been trained in the arts of the séance by Frank Herne, a well-known physical medium whose materializations were grabbed on more than one occasion and found to be the medium himself."
- Trevor H. Hall. (1963). The Spiritualists: The Story of Florence Cook and William Crookes. Helix Press.
- Ruth Brandon. (1985). "Unsavoury Spirits". New Scientist 18 July. p. 52
- John Thomas Sladek. (1974). The New Apocrypha: A Guide to Strange Sciences and Occult Beliefs. Panther. p. 194. ISBN 978-0586039748 "Crookes was forty-one, and his wife was pregnant with their tenth child. Florence was eighteen and pretty, and willing to spend considerable time at Crookes home, locked into a dark room alone with him, while beautiful apparitions were shown to him. The man Florence had secretly married, Captain Corner, put an unspiritual construction on the proceedings, and gave Crookes a beating. By 1875 the situation was becoming obvious to outsiders, who published hints that the next manifestation might be an infant phenomenon. As for the apparitions, no one but Crookes is reported to have ever seen them... By 1880 Florence had been exposed as a fraud by Sir George Sitwell."
- Amy Lehman. (2009). Victorian Women and the Theatre of Trance: Mediums, Spiritualists. McFarland. p. 158. ISBN 978-0786434794 Crookes took 44 photographs of “Katie King,” in some of which he, or Florence Cook appear alongside her. He described in detail the physical differences between the spirit and her medium. The fact that some of these photographs, which still exist, show a Katie King who looks almost identical to Florence Cook calls Crookes’ judgment, not to mention his veracity, into question. Skeptics at the time who were convinced that Florence was a fake thought that either Crookes was being completely hood-winked or that he had agreed to perpetrate the fraud with Florence. And the only explanation in either case had to be that Crookes was smitten with Florence—at the very least besotted with her and probably having an affair."
- Massimo Polidoro. (2000). Anna Eva Fay: The Mentalist Who Baffled Sir William Crookes. Skeptical Inquirer 24: 36-38.
- Harry Houdini. (2011). A Magician Among the Spirits. Cambridge University Press. p. 205. ISBN 978-1108027489 "There is not the slightest doubt in my mind that this brainy man was hoodwinked, and that his confidence was betrayed by the so-called mediums that he tested. His powers of observation were blinded and his reasoning faculties so blunted by his prejudice in favor of anything psychic or occult that he could not, or would not, resist the influence."
- Victor J. Stenger. (1990). Physics and Psychics: The Search for a World Beyond the Senses. Prometheus Books. pp. 156-157. ISBN 978-0-87975-575-1
- Royal Society paper by Crookes of Sept 27, 1871, cited in a pamphlet he published discussing reactions to it.
- William Hodson Brock. (2008). William Crookes (1832–1919) and the Commercialization of Science. Ashgate. p. 474. ISBN 978-0754663225
- William Hodson Brock (2008). William Crookes (1832-1919) and the commercialization of science. Science, technology, and culture, 1700–1945. Ashgate Publishing. p. 440. ISBN 0-7546-6322-1.
- Alex Owen (2007). The Place of Enchantment: British Occultism and the Culture of the Modern. Chicago: University of Chicago Press. p. 70.
- Ruth Brandon. (1983). Scientists and the Supernormal. New Scientist. 16 June. pp. 783–786.
- Ruth Brandon. (1985). Unsavoury Spirits. New Scientist 18 July. p. 52.
- Eric Deeson. (1974). Commonsense and Sir William Crookes. New Scientist. 26 December. pp. 922–925.
- William Hodson Brock (2004). "Crookes, Sir William (1832–1919)". Oxford Dictionary of National Biography (online ed.). Oxford University Press. doi:10.1093/ref:odnb/32639. (Subscription or UK public library membership required.)
- William Hodson Brock (2008). William Crookes (1832-1919) and the Commercialization of Science. Science, technology, and culture, 1700–1945. Ashgate Publishing. ISBN 0-7546-6322-1.
- Edmund Edward Fournier d'Albe (2011, originally published in 1923). The Life of Sir William Crookes. Cambridge University Press. ISBN 978-1-108-06159-9
- Trevor H. Hall (1963). The Spiritualists: The Story of Florence Cook and William Crookes. Helix Press.
- Massimo Polidoro (2000). Anna Eva Fay: The Mentalist Who Baffled Sir William Crookes. Skeptical Inquirer 24: 36-38.
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- Works by William Crookes at Project Gutenberg
- Hinshelwood, Cyril Norman, "William Crookes, A Victorian man of science". 1927. (Much material on this page was taken from Hinshlewood's article)
- Weeks, Mary Elvira (1932). "The discovery of the elements: XVI. The rare earth elements". Journal of Chemical Education 9 (10): 1751–1773. Bibcode:1932JChEd...9.1751W. doi:10.1021/ed009p1751.