Sodium hexametaphosphate
| Sodium hexametaphosphate[1] | |
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Other names
Calgon S Glassy sodium |
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| Identifiers | |
| CAS number | 10124-56-8  |
| PubChem | 24968 |
| ChemSpider | 23340  |
| EC number | 233-343-1 |
| MeSH | sodium+polymetaphosphate |
| Jmol-3D images | Image 1 |
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| Properties | |
| Molecular formula | Na6P6O18 |
| Molar mass | 611.7704 g mol-1 |
| Appearance | White crystals |
| Odor | odorless |
| Density | 2.484 g/cm3 |
| Melting point |
628 °C, 901 K, 1162 °F |
| Boiling point |
1500 °C, 1773 K, 2732 °F |
| Solubility in water | soluble |
| Solubility | insoluble in organic solvents |
| Refractive index (nD) | 1.482 |
| Hazards | |
| MSDS | hazard.com |
| S-phrases | S24/25 |
| Main hazards | Irritant |
| LD50 | 3.053 g kg-1 |
| Related compounds | |
| Other anions | Trisodium phosphate Tetrasodium pyrophosphate Pentasodium triphosphate |
| Related compounds | Sodium trimetaphosphate |
 (verify) (what is:  / ?)Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) |
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| Infobox references | |
Sodium hexametaphosphate (SHMP) is a hexamer of composition (NaPO3)6.[2] Sodium hexametaphosphate of commerce is typically a mixture of polymeric metaphosphates, of which the hexamer is one, and is usually the compound referred to by this name. It is more correctly termed sodium polymetaphosphate. It is prepared by melting monosodium orthophosphate, followed by rapid cooling. SHMP hydrolyzes in aqueous solution, particularly under acidic conditions, to sodium trimetaphosphate and sodium orthophosphate.
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Uses [edit]
SHMP is used as a sequestrant and has applications within a wide variety of industries, including as a food additive in which it is used under the E number E452i. Sodium carbonate is sometimes added to SHMP to raise the pH to 8.0-8.6, which produces a number of SHMP products used for water softening and detergents. Also used as a dispersing agent to break down clay and other soil types.
One of the lesser-known uses for sodium hexametaphosphate is as a deflocculant in the making of terra sigillata, a ceramic technique using a fine particled slip. The sodium hexametaphosphate or another deflocculant allows the clay particles of an ordinary slip to remain suspended for an extended period of time; after 24hrs or more, the slip separates into layers with the larger particles at the bottom, and the finest particles can be siphoned off and applied to a green ware ceramic surface. It is also used as a deflocculant or dispersant for the ASTM D422 - 63(2007) Standard Test Method for Particle-Size Analysis of Soils.
It can be prepared from Na2HPO4 and NaH2PO4.[citation needed]
It is currently used as an active ingredient in Crest Pro-Health as a claimed anti-staining and tartar prevention ingredient.[3]
Tautomers [edit]
Sigma-Aldrich shows an open ring configuration with PO2 on one end and PO4 on the other end.[4]
References [edit]
- ^ Merck Index, 12th Edition, Sodium polymetaphosphate, 8814
- ^ Van Wazer, John R. Phosphorus and its compounds. New York : Interscience Publishers (1958)
- ^ http://www.crestprohealth.com/pro-health-faq/
- ^ http://www.sigmaaldrich.com/catalog/product/aldrich/cds001195?lang=en
External links [edit]
- Occupational Health and Safety Agency for Healthcare in British Columbia
- Use of phosphates (including sodium hexametaphosphate) in industry
- Material Safety Data Sheet
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