A solar cell (also called a photovoltaic cell) is an electrical device that converts the energy of light directly into electricity by the photovoltaic effect. It is a form of photoelectric cell (in that its electrical characteristics—e.g. current, voltage, or resistance—vary when light is incident upon it) which, when exposed to light, can generate and support an electric current without being attached to any external voltage source, but do require an external load for power consumption.
The term "photovoltaic" comes from the Greek φῶς (phōs) meaning "light", and from "volt", the unit of electro-motive force, the volt, which in turn comes from the last name of the Italian physicist Alessandro Volta, inventor of the battery (electrochemical cell). The term "photo-voltaic" has been in use in English since 1849.
Photovoltaics is the field of technology and research related to the practical application of photovoltaic cells in producing electricity from light, though it is often used specifically to refer to the generation of electricity from sunlight. Cells can be described as photovoltaic even when the light source is not necessarily sunlight (lamplight, artificial light, etc.). In such cases the cell is sometimes used as a photodetector (for example infrared detectors), detecting light or other electromagnetic radiation near the visible range, or measuring light intensity.
The operation of a photovoltaic (PV) cell requires 3 basic attributes:
- The absorption of light, generating either electron-hole pairs or excitons.
- The separation of charge carriers of opposite types.
- The separate extraction of those carriers to an external circuit.
In contrast, a solar thermal collector supplies heat by absorbing sunlight, for the purpose of either direct heating or indirect electrical power generation. "Photoelectrolytic cell" (photoelectrochemical cell), on the other hand, refers either to a type of photovoltaic cell (like that developed by Edmond Becquerel and modern dye-sensitized solar cells), or to a device that splits water directly into hydrogen and oxygen using only solar illumination.
- 1 Building block of a solar panel
- 2 History of solar cells
- 3 Applications
- 4 Theory
- 5 Efficiency
- 6 Other ways for improving the efficiency
- 7 Cost
- 8 Practical materials
- 9 Emerging research topics and pre-industrial technology in solar cells
- 10 Manufacture
- 11 Manufacturers and certification
- 12 See also
- 13 References
- 14 Bibliography
- 15 External links
Building block of a solar panel
Assemblies of photovoltaic cells are used to make solar modules which generate electrical power from sunlight. Multiple cells in an integrated group, all oriented in one plane, constitute a solar photovoltaic panel or "solar photovoltaic module," as distinguished from a "solar thermal module" or "solar hot water panel." The electrical energy generated from solar modules, colloquially referred to as solar power, is an example of solar energy. A group of connected solar modules is called an "array."
History of solar cells
The photovoltaic effect was first experimentally demonstrated by French physicist Edmond Becquerel. In 1839, at age 19, experimenting in his father's laboratory, he built the world's first photovoltaic cell. Willoughby Smith first described the "Effect of Light on Selenium during the passage of an Electric Current" in an article that was published in 20 February 1873 issue of Nature. However, it was not until 1883 that the first solid state photovoltaic cell was built, by Charles Fritts, who coated the semiconductor selenium with an extremely thin layer of gold to form the junctions. The device was only around 1% efficient. In 1888 Russian physicist Aleksandr Stoletov built the first cell based on the outer photoelectric effect discovered by Heinrich Hertz earlier in 1887.
Albert Einstein explained the underlying mechanism of light instigated carrier excitation—the photoelectric effect—in 1905, for which he received the Nobel prize in Physics in 1921. Russell Ohl patented the modern junction semiconductor solar cell in 1946, which was discovered while working on the series of advances that would lead to the transistor.
The first practical photovoltaic cell was developed in 1954 at Bell Laboratories  by Daryl Chapin, Calvin Souther Fuller and Gerald Pearson. They used a diffused silicon p–n junction that reached 6% efficiency, compared to the selenium cells that found it difficult to reach 0.5%. Les Hoffman CEO of Hoffman Electronics Corporation had his Semiconductor Division pioneer the fabrication and mass production of solar cells. From 1954 to 1960 Hoffman improved the efficiency of Solar Cells from 2% to 14%. At first, cells were developed for toys and other minor uses, as the cost of the electricity they produced was very high; in relative terms, a cell that produced 1 watt of electrical power in bright sunlight cost about $250, comparing to $2 to $3 per watt for a coal plant.
Solar cells were brought from obscurity by the suggestion to add them, probably due to the successes made by Hoffman Electronics, to the Vanguard I satellite, launched in 1958. In the original plans, the satellite would be powered only by battery, and last a short time while this ran down. By adding cells to the outside of the body, the mission time could be extended with no major changes to the spacecraft or its power systems. In 1959 the United States launched Explorer 6. It featured large solar arrays resembling wings, which became a common feature in future satellites. These arrays consisted of 9600 Hoffman solar cells. There was some skepticism at first, but in practice the cells proved to be a huge success, and solar cells were quickly designed into many new satellites, notably Bell's own Telstar.
Improvements were slow over the next two decades, and the only widespread use was in space applications where their power-to-weight ratio was higher than any competing technology. However, this success was also the reason for slow progress; space users were willing to pay anything for the best possible cells, there was no reason to invest in lower-cost solutions if this would reduce efficiency. Instead, the price of cells was determined largely by the semiconductor industry; their move to integrated circuits in the 1960s led to the availability of larger boules at lower relative prices. As their price fell, the price of the resulting cells did as well. However these effects were limited, and by 1971 cell costs were estimated to be $100 per watt.
Berman's price reductions
In the late 1960s, Elliot Berman was investigating organic solar cells. He was introduced to a team at Exxon who were looking for projects 30 years in the future. The group had concluded that electrical power would be much more expensive by 2000, and felt that this increase in price would make new alternative energy sources more attractive, and solar was the most interesting among these. In 1969, Berman joined the Linden, New Jersey Exxon lab, Solar Power Corporation (SPC).
His first major effort was to canvas the potential market to see what possible uses for a new product were, and they quickly found that if the price per watt were reduced from then-current $100/watt to about $20/watt there would be significant demand. Knowing that his ribbon concept would take years to develop, the team started looking for ways to hit the $20 price point using existing materials. The first improvement was the realization that the existing cells were based on standard semiconductor manufacturing process, even though that was not ideal. This started with the boule, cutting it into disks called wafers, polishing the wafers, and then, for cell use, coating them with an anti-reflective layer. Berman noted that the rough-sawn wafers already had a perfectly suitable anti-reflective front surface, and by printing the electrodes directly on this surface, two major steps in the cell processing were eliminated. The team also explored ways to improve the mounting of the cells into arrays, eliminating the expensive materials and hand wiring used in space applications. Their solution was to use a printed circuit board on the back, acrylic plastic on the front, and silicone glue between the two, potting the cells. The largest improvement in price point was Berman's realization that existing silicon was effectively "too good" for solar cell use; the minor imperfections that would ruin a boule (or individual wafer) for electronics would have little effect in the solar application. Solar cells could be made using cast-off material from the electronics market.
Putting all of these changes into practice, the company started buying up "reject" silicon from existing manufacturers at very low cost. By using the largest wafers available, thereby reducing the amount of wiring for a given panel area, and packaging them into panels using their new methods, by 1973 SPC was producing panels at $10 per watt and selling them at $20 per watt, a fivefold decrease in prices in two years.
SPC approached companies making navigational buoys as a natural market for their products, but found a curious situation. The primary company in the business was Automatic Power, a battery manufacturer. Realizing that solar cells might eat into their battery profits, Automatic had purchased a solar navigation aid prototype from Hoffman Electronics and shelved it. Seeing there was no interest at Automatic Power, SPC turned to Tideland Signal, another battery company formed by ex-Automatic managers. Tideland introduced a solar-powered buoy and was soon ruining Automatic's business.
The timing could not be better; the rapid increase in the number of offshore oil platforms and loading facilities produced an enormous market among the oil companies. As Tideland's fortunes improved, Automatic Power started looking for their own supply of solar panels. They found Bill Yerks of Solar Power International (SPI) in California, who was looking for a market. SPI was soon bought out by one of its largest customers, the ARCO oil giant, forming ARCO Solar. ARCO Solar's factory in Camarillo, California was the first dedicated to building solar panels, and was in continual operation from its purchase by ARCO in 1977 until 2011 when it was closed by SolarWorld.
This market combined with the 1973 oil crisis. Oil companies were now cash-flush due to their huge profits during the crisis, but were also acutely aware that their future success would depend on some other form of power. Over the next few years, major oil companies started a number of solar firms, and were for decades the largest producers of solar panels. Exxon, ARCO, Shell, Amoco (later purchased by BP) and Mobil all had major solar divisions during the 1970s and 1980s. Technology companies also had some investment, including General Electric, Motorola, IBM, Tyco and RCA.
In recent times, further improvements have brought production costs down under $1 a watt, with wholesale costs well under $2. "Balance of system" costs are now more than the panels themselves. Large commercial arrays can be built, as of 2010, at below $3.40 a watt, fully commissioned.
As the semiconductor industry moved to ever-larger boules, older equipment became available at fire-sale prices. Cells have grown in size as older equipment became available on the surplus market; ARCO Solar's original panels used cells with 2 to 4 inch (50 to 100 mm) diameter. Panels in the 1990s and early 2000s generally used 5 inch (125 mm) wafers, and since 2008 almost all new panels use 6 inch (150 mm) cells. The widespread introduction of flat screen televisions in the late 1990s and early 2000s led to the wide availability of large sheets of high-quality glass, used on the front of the panels.
During the 1990s, polysilicon cells became increasingly popular. These cells offer less efficiency than their monosilicon counterparts, but they are grown in large vats that greatly reduce the cost of production. By the mid-2000s, poly was dominant in the low-cost panel market, but more recently a variety of factors has pushed the higher performance mono back into widespread use.
Manufacturers of wafer-based cells have responded to high silicon prices in 2004–2008 prices with rapid reductions in silicon consumption. In 2008, according to Jef Poortmans, director of IMEC's organic and solar department, current cells use between eight and nine grams of silicon per watt of power generation, with wafer thicknesses in the neighborhood of 0.200 mm.
Other technologies have tried to enter the market. First Solar was briefly the largest panel manufacturer in 2009, in terms of yearly power produced, using a thin-film cell sandwiched between two layers of glass. Since then silicon panels reasserted their dominant position both in terms of lower prices and the rapid rise of Chinese manufacturing, resulting in the top producers being Chinese. By late 2011, efficient production in China, coupled with a drop in European demand due to budgetary turmoil had dropped prices for crystalline solar-based modules further, to about $1.09 per watt in October 2011, down sharply from the price per watt in 2010. Prices continued to fall in 2012, reaching $0.62/watt by 4Q2012 with further price reductions expected in 2013.
A more modern process, mono-like-multi, aims to offer the performance of mono at the cost of poly, and is in the process of being introduced in 2012. As of 2013, the plummeting cost of silicon still continues to usher in a new era of inexpensive solar cells, making non-cell and even non-module costs ever more important for the advancement of economical solar energy.
Solar cells are often electrically connected and encapsulated as a module. Photovoltaic modules often have a sheet of glass on the front (sun up) side, allowing light to pass while protecting the semiconductor wafers from abrasion and impact due to wind-driven debris, rain, hail, etc. Solar cells are also usually connected in series in modules, creating an additive voltage. Connecting cells in parallel will yield a higher current; however, very significant problems exist with parallel connections. For example, shadow effects can shut down the weaker (less illuminated) parallel string (a number of series connected cells) causing substantial power loss and even damaging the weaker string because of the excessive reverse bias applied to the shadowed cells by their illuminated partners. Strings of series cells are usually handled independently and not connected in parallel, special paralleling circuits are the exceptions. Although modules can be interconnected to create an array with the desired peak DC voltage and loading current capacity, using independent MPPTs (maximum power point trackers) provides a better solution. In the absence of paralleling circuits, shunt diodes can be used to reduce the power loss due to shadowing in arrays with series/parallel connected cells.
To make practical use of the solar-generated energy, the electricity is most often fed into the electricity grid using inverters (grid-connected photovoltaic systems); in stand-alone systems, batteries are used to store the energy that is not needed immediately. Solar panels can be used to power or recharge portable devices.
The solar cell works in three steps:
- Photons in sunlight hit the solar panel and are absorbed by semiconducting materials, such as silicon.
- Electrons (negatively charged) are excited from their current molecular/atomic orbital. Once excited the electron can either dissipate the energy, and return to its orbital or travel through the cell until it reaches an electrode. Current starts flowing through the material to cancel the potential and this electricity is captured. Due to the special composition of solar cells, the electrons are only allowed to move in a single direction.
- An array of solar cells converts solar energy into a usable amount of direct current (DC) electricity.
The efficiency of a solar cell may be broken down into reflectance efficiency, thermodynamic efficiency, charge carrier separation efficiency and conductive efficiency. The overall efficiency is the product of all of these individual efficiencies.
A solar cell usually has a voltage dependent efficiency curve, temperature coefficients, and shadow angles.
Due to the difficulty in measuring these parameters directly, other parameters are measured instead: thermodynamic efficiency, quantum efficiency, integrated quantum efficiency, VOC ratio, and fill factor. Reflectance losses are a portion of the quantum efficiency under "external quantum efficiency". Recombination losses make up a portion of the quantum efficiency, VOC ratio, and fill factor. Resistive losses are predominantly categorized under fill factor, but also make up minor portions of the quantum efficiency, VOC ratio.
The fill factor is defined as the ratio of the actual maximum obtainable power to the product of the open circuit voltage and short circuit current. This is a key parameter in evaluating the performance of solar cells. Typical commercial solar cells have a fill factor > 0.70. Grade B cells have a fill factor usually between 0.4 to 0.7. Cells with a high fill factor have a low equivalent series resistance and a high equivalent shunt resistance, so less of the current produced by the cell is dissipated in internal losses.
Single p–n junction crystalline silicon devices are now approaching the theoretical limiting power efficiency of 33.7%, noted as the Shockley–Queisser limit in 1961. In the extreme, with an infinite number of layers, the corresponding limit is 86% using concentrated sunlight.
Other ways for improving the efficiency
There are many reviews that suggest many ways to improve the solar cells efficiency, consisting to incorporate lanthanide doped materials (Er3+, Yb3+, Ho3+ or combination of them) on to a solar cell, taking advantage of their optical properties to convert the infrared radiation to visible light . This kind of process, called upconversion, is a luminescence process where two low-energy infrared photons are absorbed by rare-earth ions to generate a high-energy visible photon. As example, the energy transfer upconversion process (ETU), consists in successive transfer processes between excited ions under excitation in the near infrared. Therefore, an excited ion can reach a high energetic level from which de-excites emitting a visible photon. By this way, an upconverter material could be placed below the solar cell in order to absorb the infrared light (not absorbed by the Si) and produce visible photons to excite the solar cell, enhancing its response to infrared radiation. There are many upconversion materials, but usually they are doped with lanthanide ions because they are efficient in these upconversion processes. These ions are most commonly found in the trivalent state and their rich energy level structure over a broad spectral range explains their numerous applications. Among them, the Er3+ ions have been the most used. The Er3+ ions absorb the solar radiation around 1.54 µm. Two Er3+ ions that have absorbed this radiation can interact with each other through an upconversion process. The excited ion emits light above the Si bandgap that is absorbed by the solar cell and creates an additional electron–hole pair that can contribute to generate current. However, the obtained efficiency of the solar cell was small. In addition, the fluoroindate glasses have shown to have very low phonon energy and they have been also proposed as suitable matrix doped with Ho3+ ions in order to improve the efficiency of silicon solar cells, using upconversion processes.
The cost of a solar cell is given per unit of peak electrical power. Solar-specific feed-in tariffs vary worldwide, and even state by state within various countries. Such feed-in tariffs can be highly effective in encouraging the development of solar power projects.
High-efficiency solar cells are of interest to decrease the cost of solar energy. Many of the costs of a solar power plant are proportional to the panel area or land area of the plant. A higher efficiency cell may reduce the required areas and so reduce the total plant cost, even if the cells themselves are more costly. Efficiencies of bare cells, to be useful in evaluating solar power plant economics, must be evaluated under realistic conditions. The basic parameters that need to be evaluated are the short circuit current, open circuit voltage.
The chart above illustrates the best laboratory efficiencies obtained for various materials and technologies, generally this is done on very small, i.e., one cm² cells. Commercial efficiencies are significantly lower.
Grid parity, the point at which photovoltaic electricity is equal to or cheaper than grid power, can be reached using low cost solar cells. Proponents of solar hope to achieve grid parity first in areas with abundant sun and high costs for electricity such as in California and Japan. Some argue that grid parity has been reached in Hawaii and other islands that otherwise use diesel fuel to produce electricity. George W. Bush had set 2015 as the date for grid parity in the USA. Speaking at a conference in 2007, General Electric's Chief Engineer predicted grid parity without subsidies in sunny parts of the United States by around 2015. The Photovoltaic Association reported in 2012 that Australia has reached grid parity (ignoring feed in tariffs).
The price of solar panels fell steadily for 40 years, until 2004 when high subsidies in Germany drastically increased demand there and greatly increased the price of purified silicon (which is used in computer chips as well as solar panels). The recession of 2008 and the onset of Chinese manufacturing caused prices to resume their decline with vehemence. In the four years after January 2008 prices for solar modules in Germany dropped from €3 to €1 per peak watt. During that same times production capacity surged with an annual growth of more than 50%. China increased market share from 8% in 2008 to over 55% in the last quarter of 2010. Recently, in December 2012 the price of Chinese solar panels had dropped to $0.60/Wp (crystalline modules).
Swanson's law, an observation similar to Moore's Law that states that solar cell prices fall 20% for every doubling of industry capacity, has gained recent (as of 2012) media attention, having been featured in an article in the British weekly newspaper The Economist.
Various materials display varying efficiencies and have varying costs. Materials for efficient solar cells must have characteristics matched to the spectrum of available light. Some cells are designed to efficiently convert wavelengths of solar light that reach the Earth surface. However, some solar cells are optimized for light absorption beyond Earth's atmosphere as well. Light absorbing materials can often be used in multiple physical configurations to take advantage of different light absorption and charge separation mechanisms.
Industrial photovoltaic solar cells are made of monocrystalline silicon, polycrystalline silicon, amorphous silicon, cadmium telluride or copper indium selenide/sulfide, or GaAs-based multijunction material systems.
By far, the most prevalent bulk material for solar cells is crystalline silicon (abbreviated as a group as c-Si), also known as "solar grade silicon". Bulk silicon is separated into multiple categories according to crystallinity and crystal size in the resulting ingot, ribbon, or wafer. These cells are entirely based around the concept of a p-n junction.
- monocrystalline silicon (c-Si): often made using the Czochralski process. Single-crystal wafer cells tend to be expensive, and because they are cut from cylindrical ingots, do not completely cover a square solar cell module without a substantial waste of refined silicon. Hence most c-Si panels have uncovered gaps at the four corners of the cells.
- polycrystalline silicon, or multicrystalline silicon, (poly-Si or mc-Si): made from cast square ingots — large blocks of molten silicon carefully cooled and solidified. Poly-Si cells are less expensive to produce than single crystal silicon cells, but are less efficient. United States Department of Energy data show that there were a higher number of polycrystalline sales than monocrystalline silicon sales.
- ribbon silicon is a type of polycrystalline silicon: it is formed by drawing flat thin films from molten silicon and results in a polycrystalline structure. These cells have lower efficiencies than poly-Si, but save on production costs due to a great reduction in silicon waste, as this approach does not require sawing from ingots.
- mono-like-multi silicon: Developed in the 2000s and introduced commercially around 2009, mono-like-multi, or cast-mono, uses existing polycrystalline casting chambers with small "seeds" of mono material. The result is a bulk mono-like material with poly around the outsides. When sawn apart for processing, the inner sections are high-efficiency mono-like cells (but square instead of "clipped"), while the outer edges are sold off as conventional poly. The result is line that produces mono-like cells at poly-like prices.
Thin-film technologies reduce the amount of material required in creating the active material of solar cell. Most thin film solar cells are sandwiched between two panes of glass to make a module. Since silicon solar panels only use one pane of glass, thin film panels are approximately twice as heavy as crystalline silicon panels, although they have a smaller ecological impact (determined from life cycle analysis). The majority of film panels have significantly lower conversion efficiencies, lagging silicon by two to three percentage points. Thin-film solar technologies have enjoyed large investment due to the success of First Solar and the largely unfulfilled promise of lower cost and flexibility compared to wafer silicon cells, but they have not become mainstream solar products due to their lower efficiency and corresponding larger area consumption per watt production. Cadmium telluride (CdTe), copper indium gallium selenide (CIGS) and amorphous silicon (a-Si) are three thin-film technologies often used as outdoor photovoltaic solar power production. As of December 2013, CdTe was most cost effective (U.S. manufacturing cost per installed watt: $0.59 reported by First Solar) widely used thin film technology, and CIGS technology has the highest laboratory efficiency (20.4% as of December 2013), though CdTe cells made by First Solar have the highest industrial efficiency, and the lab efficiency of the immature GaAs thin film technology tops 28%.
Cadmium telluride solar cell
A cadmium telluride solar cell uses a cadmium telluride (CdTe) thin film, a semiconductor layer to absorb and convert sunlight into electricity. One disadvantage of this technology, the only thin film material so far to rival crystalline silicon in cost/watt, is that cadmium is a deadly poison. Another issue is that tellurium (anion: "telluride") is a metal extremely rare in the earth's crust.
The cadmium present in the cells would be toxic if released. However, release is impossible during normal operation of the cells and is unlikely during ﬁres in residential roofs. A square meter of CdTe contains approximately the same amount of Cd as a single C cell nickel-cadmium battery, in a more stable and less soluble form.
Copper indium gallium selenide
Copper indium gallium selenide (CIGS) is a direct band gap material. It has the highest efficiency (~20%) among thin film materials (see CIGS solar cell). Traditional methods of fabrication involve vacuum processes including co-evaporation and sputtering. Recent developments at IBM and Nanosolar attempt to lower the cost by using non-vacuum solution processes.
GaAs thin film cells
The Dutch Radboud University Nijmegen set the record for thin film solar cell efficiency using a single junction GaAs to 25.8% in August 2008 using only 4 µm thick GaAs layer which can be transferred from a wafer base to glass or plastic film. Recently, this record has been increased to 28.8%. The high efficiency obtained in GaAs thin film solar cells is attributed to the extreme high quality GaAs epitaxial growth, surface passivation by the AlGaAs, and the promotion of photon recycling by the thin film design.
Silicon thin films
Silicon thin-film cells are mainly deposited by chemical vapor deposition (typically plasma-enhanced, PE-CVD) from silane gas and hydrogen gas. Depending on the deposition parameters, this can yield:
- Amorphous silicon (a-Si or a-Si:H)
- Protocrystalline silicon or
- Nanocrystalline silicon (nc-Si or nc-Si:H), also called microcrystalline silicon.
It has been found that protocrystalline silicon with a low volume fraction of nanocrystalline silicon is optimal for high open circuit voltage. These types of silicon present dangling and twisted bonds, which results in deep defects (energy levels in the bandgap) as well as deformation of the valence and conduction bands (band tails). The solar cells made from these materials tend to have lower energy conversion efficiency than bulk silicon, but are also less expensive to produce. The quantum efficiency of thin film solar cells is also lower due to reduced number of collected charge carriers per incident photon.
An amorphous silicon (a-Si) solar cell is made of amorphous or microcrystalline silicon and its basic electronic structure is the p-i-n junction. a-Si is attractive as a solar cell material because it is abundant and non-toxic (unlike its CdTe counterpart) and requires a low processing temperature, enabling production of devices to occur on flexible and low-cost substrates. As the amorphous structure has a higher absorption rate of light than crystalline cells, the complete light spectrum can be absorbed with a very thin layer of photo-electrically active material. A film only 1 micrometer thick can absorb 90% of the usable solar energy. This reduced material requirement along with current technologies being capable of large-area deposition of a-Si, the scalability of this type of cell is high. However, because it is amorphous, it has high inherent disorder and dangling bonds, making it a bad conductor for charge carriers. These dangling bonds act as recombination centers that severely reduce the carrier lifetime and pin the Fermi level so that doping the material to n- or p- type is not possible. Amorphous Silicon also suffers from the Staebler-Wronski effect, which results in the efficiency of devices utilizing amorphous silicon dropping as the cell is exposed to light. The production of a-Si thin film solar cells uses glass as a substrate and deposits a very thin layer of silicon by plasma-enhanced chemical vapor deposition (PECVD). A-Si manufacturers are working towards lower costs per watt and higher conversion efficiency with continuous research and development on multijunction solar cells for solar panels. Anwell Technologies Limited recently announced its target for multi-substrate-multi-chamber PECVD, to lower the cost to US $0.50 per watt.
Amorphous silicon has a higher bandgap (1.7 eV) than crystalline silicon (c-Si) (1.1 eV), which means it absorbs the visible part of the solar spectrum more strongly than the infrared portion of the spectrum. As nc-Si has about the same bandgap as c-Si, the nc-Si and a-Si can advantageously be combined in thin layers, creating a layered cell called a tandem cell. The top cell in a-Si absorbs the visible light and leaves the infrared part of the spectrum for the bottom cell in nc-Si.
Recently, solutions to overcome the limitations of thin-film crystalline silicon have been developed. Light trapping schemes where the weakly absorbed long wavelength light is obliquely coupled into the silicon and traverses the film several times can significantly enhance the absorption of sunlight in the thin silicon films. Minimizing the top contact coverage of the cell surface is another method for reducing optical losses; this approach simply aims at reducing the area that is covered over the cell to allow for maximum light input into the cell. Anti-reflective coatings can also be applied to create destructive interference within the cell. This can be done by modulating the refractive index of the surface coating; if destructive interference is achieved, there will be no reflective wave and thus all light will be transmitted into the semiconductor cell. Surface texturing is another option, but may be less viable because it also increases the manufacturing price. By applying a texture to the surface of the solar cell, the reflected light can be refracted into striking the surface again, thus reducing the overall light reflected out. Light trapping as another method allows for a decrease in overall thickness of the device; the path length that the light will travel is several times the actual device thickness. This can be achieved by adding a textured backreflector to the device as well as texturing the surface. If both front and rear surfaces of the device meet this criterion, the light will be 'trapped' by not having an immediate pathway out of the device due to internal reflections. Thermal processing techniques can significantly enhance the crystal quality of the silicon and thereby lead to higher efficiencies of the final solar cells. Further advancement into geometric considerations of building devices can exploit the dimensionality of nanomaterials. Creating large, parallel nanowire arrays enables long absorption lengths along the length of the wire while still maintaining short minority carrier diffusion lengths along the radial direction. Adding nanoparticles between the nanowires will allow for conduction through the device. Because of the natural geometry of these arrays, a textured surface will naturally form which allows for even more light to be trapped. A further advantage of this geometry is that these types of devices require about 100 times less material than conventional wafer-based devices.
High-efficiency multijunction cells were originally developed for special applications such as satellites and space exploration, but are also now used effectively with terrestrial solar concentrators. Multijunction cells consist of multiple thin films, each essentially a solar cell in its own right, grown on top of each other, typically using metalorganic vapour phase epitaxy. A triple-junction cell, for example, may consist of the semiconductors: GaAs, Ge, and GaInP2. Each type of semiconductor will have a characteristic band gap energy which, loosely speaking, causes it to absorb light most efficiently at a certain color, or more precisely, to absorb electromagnetic radiation over a portion of the spectrum. Combinations of semiconductors are carefully chosen to efficiently absorb most of the solar spectrum, thus generating electricity from as much of the solar energy as possible.
GaAs based multijunction devices are the most efficient solar cells to date. In 15 October 2012, triple junction metamorphic cell reached a record high of 44%.
Tandem solar cells based on monolithic, series connected, gallium indium phosphide (GaInP), gallium arsenide GaAs, and germanium Ge p–n junctions, are seeing demand rapidly rise. Between December 2006 and December 2007, the cost of 4N gallium metal rose from about $350 per kg to $680 per kg. Additionally, germanium metal prices have risen substantially to $1000–1200 per kg this year. Those materials include gallium (4N, 6N and 7N Ga), arsenic (4N, 6N and 7N) and germanium, pyrolitic boron nitride (pBN) crucibles for growing crystals, and boron oxide, these products are critical to the entire substrate manufacturing industry.
Triple-junction GaAs solar cells were also being used as the power source of the Dutch four-time World Solar Challenge winners Nuna in 2003, 2005 and 2007, and also by the Dutch solar cars Solutra (2005), Twente One (2007) and 21Revolution (2009).
Emerging research topics and pre-industrial technology in solar cells
Light-absorbing dyes (DSSC)
Dye-sensitized solar cells (DSSCs) are made of low-cost materials and do not need elaborate equipment to manufacture, so they can be made in a DIY fashion, possibly allowing players to produce more of this type of solar cell than others. In bulk it should be significantly less expensive than older solid-state cell designs. DSSC's can be engineered into flexible sheets, and although its conversion efficiency is less than the best thin film cells, its price/performance ratio should be high enough to allow them to compete with fossil fuel electrical generation.
Typically a ruthenium metalorganic dye (Ru-centered) is used as a monolayer of light-absorbing material. The dye-sensitized solar cell depends on a mesoporous layer of nanoparticulate titanium dioxide to greatly amplify the surface area (200–300 m2/g TiO2, as compared to approximately 10 m2/g of flat single crystal). The photogenerated electrons from the light absorbing dye are passed on to the n-type TiO2, and the holes are absorbed by an electrolyte on the other side of the dye. The circuit is completed by a redox couple in the electrolyte, which can be liquid or solid. This type of cell allows a more flexible use of materials, and is typically manufactured by screen printing or use of ultrasonic nozzles, with the potential for lower processing costs than those used for bulk solar cells. However, the dyes in these cells also suffer from degradation under heat and UV light, and the cell casing is difficult to seal due to the solvents used in assembly. In spite of the above, this is a popular emerging technology with some commercial impact forecast within this decade. The first commercial shipment of DSSC solar modules occurred in July 2009 from G24i Innovations.
Quantum dot solar cells (QDSCs)
Quantum dot solar cells (QDSCs) are based on the Gratzel cell, or dye-sensitized solar cell, architecture but employ low band gap semiconductor nanoparticles, fabricated with such small crystallite sizes that they form quantum dots (such as CdS, CdSe, Sb2S3, PbS, etc.), instead of organic or organometallic dyes as light absorbers. Quantum dots (QDs) have attracted much interest because of their unique properties. Their size quantization allows for the band gap to be tuned by simply changing particle size. They also have high extinction coefficients, and have shown the possibility of multiple exciton generation.
In a QDSC, a mesoporous layer of titanium dioxide nanoparticles forms the backbone of the cell, much like in a DSSC. This TiO2 layer can then be made photoactive by coating with semiconductor quantum dots using chemical bath deposition, electrophoretic deposition, or successive ionic layer adsorption and reaction. The electrical circuit is then completed through the use of a liquid or solid redox couple. During the last 3–4 years, the efficiency of QDSCs has increased rapidly with efficiencies over 5% shown for both liquid-junction and solid state cells. In an effort to decrease production costs of these devices, the Prashant Kamat research group recently demonstrated a solar paint made with TiO2 and CdSe that can be applied using a one-step method to any conductive surface and have shown efficiencies over 1%.
Organic/polymer solar cells
Organic solar cells are a relatively novel technology, yet may hold the promise of a substantial price reduction. These cells can be processed from liquid solution, hence the possibility of a simple roll-to-roll printing process, potentially leading to inexpensive, large scale production. In addition, these cells could be beneficial for some applications where mechanical flexibility and disposability are important. Current cell efficiencies are, however, very low, and practical devices are essentially non-existent.
Organic solar cells and polymer solar cells are built from thin films (typically 100 nm) of organic semiconductors including polymers, such as polyphenylene vinylene and small-molecule compounds like copper phthalocyanine (a blue or green organic pigment) and carbon fullerenes and fullerene derivatives such as PCBM. Energy conversion efficiencies achieved to date using conductive polymers are very low compared to inorganic materials. However, recent improvements have led to a NREL (National Renewable Energy Laboratory) certified efficiency of 8.3% for the Konarka Power Plastic, and organic tandem cells in 2012 reached 11.1%.
The active region of an organic device consists of two materials, one which acts as an electron donor and the other as an acceptor. When a photon is converted into an electron hole pair, typically in the donor material, distinct from most other solar cell types, the charges tend to remain bound in the form of an exciton, and are separated when the exciton diffuses to the donor-acceptor interface. The short exciton diffusion lengths of most polymer systems tend to limit the efficiency of such devices. Nanostructured interfaces, sometimes in the form of bulk heterojunctions, can improve performance.
In 2011, researchers at the Massachusetts Institute of Technology and Michigan State University developed the first highly efficient transparent solar cells that had a power efficiency close to 2% with a transparency to the human eye greater than 65%, achieved by selectively absorbing the ultraviolet and near-infrared parts of the spectrum with small-molecule compounds. Researchers at UCLA more recently developed an analogous polymer solar cell, following the same approach, that is 70% transparent and has a 4% power conversion efficiency. The efficiency limits of both opaque and transparent organic solar cells were recently outlined. These lightweight, flexible cells can be produced in bulk at a low cost, and could be used to create power generating windows.
In 2013, researchers announced polymer cells with some 3% efficiency. They used block copolymers, self-assembling organic materials that arrange themselves into distinct layers. The research focused on P3HT-b-PFTBT that separates into bands some 16 nanometers wide.
Because solar cells are semiconductor devices, they share some of the same processing and manufacturing techniques as other semiconductor devices such as computer and memory chips. However, the stringent requirements for cleanliness and quality control of semiconductor fabrication are more relaxed for solar cells. Most large-scale commercial solar cell factories today make screen printed poly-crystalline or single crystalline silicon solar cells.
Poly-crystalline silicon wafers are made by wire-sawing block-cast silicon ingots into very thin (180 to 350 micrometer) slices or wafers. The wafers are usually lightly p-type doped. To make a solar cell from the wafer, a surface diffusion of n-type dopants is performed on the front side of the wafer. This forms a p–n junction a few hundred nanometers below the surface.
Anti-reflection coatings, to increase the amount of light coupled into the solar cell, are typically next applied. Silicon nitride has gradually replaced titanium dioxide as the anti-reflection coating, because of its excellent surface passivation qualities. It prevents carrier recombination at the surface of the solar cell. It is typically applied in a layer several hundred nanometers thick using plasma-enhanced chemical vapor deposition (PECVD). Some solar cells have textured front surfaces that, like anti-reflection coatings, serve to increase the amount of light coupled into the cell. Such surfaces can usually only be formed on single-crystal silicon, though in recent years methods of forming them on multicrystalline silicon have been developed.
The wafer then has a full area metal contact made on the back surface, and a grid-like metal contact made up of fine "fingers" and larger "bus bars" are screen-printed onto the front surface using a silver paste. The rear contact is also formed by screen-printing a metal paste, typically aluminium. Usually this contact covers the entire rear side of the cell, though in some cell designs it is printed in a grid pattern. The paste is then fired at several hundred degrees Celsius to form metal electrodes in ohmic contact with the silicon. Some companies use an additional electro-plating step to increase the cell efficiency. After the metal contacts are made, the solar cells are interconnected by flat wires or metal ribbons, and assembled into modules or "solar panels". Solar panels have a sheet of tempered glass on the front, and a polymer encapsulation on the back.
Manufacturers and certification
National Renewable Energy Laboratory tests and validates solar technologies. There are three reliable certifications of solar equipment: UL and IEEE (both U.S. standards) and IEC. There are a huge array of solar cell companies worldwide, see List of photovoltaics companies by country and rankings.
Solar cells are manufactured primarily in Japan, Germany, mainland China, Taiwan, Malaysia and the United States, whereas Europe, China, the U.S., and Japan have dominated (94% or more as of 2013) in installed systems for the last decade. Numerous other nations, however, have or are acquiring significant solar cell production capacity. While technologies are constantly evolving toward higher efficiencies, the most effective cells for low cost electrical production are not necessarily those with the highest efficiency, but those with a balance between low-cost production and efficiency high enough to minimize area-related balance of systems cost. Those companies with large scale manufacturing technology for coating inexpensive substrates may, in fact, ultimately be the lowest cost net electricity producers, even with cell efficiencies that are lower than those of single-crystal technologies.
Global PV cell/module production increased by 10% in 2012 despite a 9% decline in solar energy investments according to the annual 'PV Status Report" released by the European Commission's Joint Research Centre." Since 2009 cell production has quadrupled.
Due mainly to heavy government investment, China has played by far the most important role in changing the face of solar cell manufacturing in recent years. Chinese companies produced solar cells/modules with a capacity of ~23 GW in 2013 (60% of global production).
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- Photovoltaics CDROM online
- Solar cell manufacturing techniques
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