In mathematics, spherical harmonics are the angular portion of a set of solutions to Laplace's equation. Represented in a system of spherical coordinates, Laplace's spherical harmonics are a specific set of spherical harmonics that forms an orthogonal system, first introduced by Pierre Simon de Laplace in 1782. Spherical harmonics are important in many theoretical and practical applications, particularly in the computation of atomic orbital electron configurations, representation of gravitational fields, geoids, and the magnetic fields of planetary bodies and stars, and characterization of the cosmic microwave background radiation. In 3D computer graphics, spherical harmonics play a special role in a wide variety of topics including indirect lighting (ambient occlusion, global illumination, precomputed radiance transfer, etc.) and recognition of 3D shapes.
- 1 History
- 2 Laplace's spherical harmonics
- 3 Conventions
- 4 Spherical harmonics in Cartesian form
- 5 Spherical harmonics expansion
- 6 Spectrum analysis
- 7 Algebraic properties
- 8 Visualization of the spherical harmonics
- 9 List of spherical harmonics
- 10 Higher dimensions
- 11 Connection with representation theory
- 12 See also
- 13 Notes
- 14 References
Spherical harmonics were first investigated in connection with the Newtonian potential of Newton's law of universal gravitation in three dimensions. In 1782, Pierre-Simon de Laplace had, in his Mécanique Céleste, determined that the gravitational potential at a point x associated to a set of point masses mi located at points xi was given by
Each term in the above summation is an individual Newtonian potential for a point mass. Just prior to that time, Adrien-Marie Legendre had investigated the expansion of the Newtonian potential in powers of r = |x| and r1 = |x1|. He discovered that if r ≤ r1 then
where γ is the angle between the vectors x and x1. The functions Pi are the Legendre polynomials, and they are a special case of spherical harmonics. Subsequently, in his 1782 memoire, Laplace investigated these coefficients using spherical coordinates to represent the angle γ between x1 and x. (See Applications of Legendre polynomials in physics for a more detailed analysis.)
In 1867, William Thomson (Lord Kelvin) and Peter Guthrie Tait introduced the solid spherical harmonics in their Treatise on Natural Philosophy, and also first introduced the name of "spherical harmonics" for these functions. The solid harmonics were homogeneous solutions of Laplace's equation
By examining Laplace's equation in spherical coordinates, Thomson and Tait recovered Laplace's spherical harmonics. The term "Laplace's coefficients" was employed by William Whewell to describe the particular system of solutions introduced along these lines, whereas others reserved this designation for the zonal spherical harmonics that had properly been introduced by Laplace and Legendre.
The 19th century development of Fourier series made possible the solution of a wide variety of physical problems in rectangular domains, such as the solution of the heat equation and wave equation. This could be achieved by expansion of functions in series of trigonometric functions. Whereas the trigonometric functions in a Fourier series represent the fundamental modes of vibration in a string, the spherical harmonics represent the fundamental modes of vibration of a sphere in much the same way. Many aspects of the theory of Fourier series could be generalized by taking expansions in spherical harmonics rather than trigonometric functions. This was a boon for problems possessing spherical symmetry, such as those of celestial mechanics originally studied by Laplace and Legendre.
The prevalence of spherical harmonics already in physics set the stage for their later importance in the 20th century birth of quantum mechanics. The spherical harmonics are eigenfunctions of the square of the orbital angular momentum operator
Laplace's spherical harmonics
Consider the problem of finding solutions of the form f(r,θ,φ) = R(r)Y(θ,φ). By separation of variables, two differential equations result by imposing Laplace's equation:
The second equation can be simplified under the assumption that Y has the form Y(θ,φ) = Θ(θ)Φ(φ). Applying separation of variables again to the second equation gives way to the pair of differential equations
for some number m. A priori, m is a complex constant, but because Φ must be a periodic function whose period evenly divides 2π, m is necessarily an integer and Φ is a linear combination of the complex exponentials e±imφ. The solution function Y(θ,φ) is regular at the poles of the sphere, where θ=0,π. Imposing this regularity in the solution Θ of the second equation at the boundary points of the domain is a Sturm–Liouville problem that forces the parameter λ to be of the form λ = ℓ(ℓ+1) for some non-negative integer with ℓ ≥ |m|; this is also explained below in terms of the orbital angular momentum. Furthermore, a change of variables t = cosθ transforms this equation into the Legendre equation, whose solution is a multiple of the associated Legendre polynomial . Finally, the equation for R has solutions of the form R(r) = Arℓ + Br−ℓ−1; requiring the solution to be regular throughout R3 forces B = 0.
Here the solution was assumed to have the special form Y(θ,φ) = Θ(θ)Φ(φ). For a given value of ℓ, there are 2ℓ+1 independent solutions of this form, one for each integer m with −ℓ ≤ m ≤ ℓ. These angular solutions are a product of trigonometric functions, here represented as a complex exponential, and associated Legendre polynomials:
Here is called a spherical harmonic function of degree ℓ and order m, is an associated Legendre polynomial, N is a normalization constant, and θ and φ represent colatitude and longitude, respectively. In particular, the colatitude θ, or polar angle, ranges from 0 at the North Pole to π at the South Pole, assuming the value of π/2 at the Equator, and the longitude φ, or azimuth, may assume all values with 0 ≤ φ < 2π. For a fixed integer ℓ, every solution Y(θ,φ) of the eigenvalue problem
is a linear combination of . In fact, for any such solution, rℓY(θ,φ) is the expression in spherical coordinates of a homogeneous polynomial that is harmonic (see below), and so counting dimensions shows that there are 2ℓ+1 linearly independent such polynomials.
The general solution to Laplace's equation in a ball centered at the origin is a linear combination of the spherical harmonic functions multiplied by the appropriate scale factor rℓ,
Orbital angular momentum
The is conventional in quantum mechanics; it is convenient to work in units in which . The spherical harmonics are eigenfunctions of the square of the orbital angular momentum
Laplace's spherical harmonics are the joint eigenfunctions of the square of the orbital angular momentum and the generator of rotations about the azimuthal axis:
Furthermore, L2 is a positive operator.
If Y is a joint eigenfunction of L2 and Lz, then by definition
for some real numbers m and λ. Here m must in fact be an integer, for Y must be periodic in the coordinate φ with period a number that evenly divides 2π. Furthermore, since
and each of Lx, Ly, Lz are self-adjoint, it follows that λ ≥ m2.
Denote this joint eigenspace by Eλ,m, and define the raising and lowering operators by
Then L+ and L− commute with L2, and the Lie algebra generated by L+, L−, Lz is the special linear Lie algebra, with commutation relations
Thus L+ : Eλ,m → Eλ,m+1 (it is a "raising operator") and L− : Eλ,m → Eλ,m−1 (it is a "lowering operator"). In particular, Lk
+ : Eλ,m → Eλ,m+k must be zero for k sufficiently large, because the inequality λ ≥ m2 must hold in each of the nontrivial joint eigenspaces. Let Y ∈ Eλ,m be a nonzero joint eigenfunction, and let k be the least integer such that
it follows that
Thus λ = ℓ(ℓ+1) for the positive integer ℓ = m+k.
Orthogonality and normalization
Several different normalizations are in common use for the Laplace spherical harmonic functions. Throughout the section, we use the standard convention that (see associated Legendre polynomials)
which is the natural normalization given by Rodrigues' formula.
In seismology, the Laplace spherical harmonics are generally defined as (this is the convention used in this article)
which are orthonormal
where δij is the Kronecker delta and dΩ = sinθ dφ dθ. This normalization is used in quantum mechanics because it ensures that probability is normalized, i.e.
The disciplines of geodesy and spectral analysis use
which possess unit power
The magnetics community, in contrast, uses Schmidt semi-normalized harmonics
which have the normalization
In quantum mechanics this normalization is sometimes used as well, and is named Racah's normalization after Giulio Racah.
It can be shown that all of the above normalized spherical harmonic functions satisfy
where the superscript * denotes complex conjugation. Alternatively, this equation follows from the relation of the spherical harmonic functions with the Wigner D-matrix.
One source of confusion with the definition of the spherical harmonic functions concerns a phase factor of (−1)m for m > 0, 1 otherwise, commonly referred to as the Condon–Shortley phase in the quantum mechanical literature. In the quantum mechanics community, it is common practice to either include this phase factor in the definition of the associated Legendre polynomials, or to append it to the definition of the spherical harmonic functions. There is no requirement to use the Condon–Shortley phase in the definition of the spherical harmonic functions, but including it can simplify some quantum mechanical operations, especially the application of raising and lowering operators. The geodesy and magnetics communities never include the Condon–Shortley phase factor in their definitions of the spherical harmonic functions nor in the ones of the associated Legendre polynomials.
A real basis of spherical harmonics can be defined in terms of their complex analogues by setting
The Condon-Shortley phase convention is used here for consistency.
These real spherical harmonics are sometimes known as tesseral spherical harmonics. These functions have the same orthonormality properties as the complex ones above. The harmonics with m > 0 are said to be of cosine type, and those with m < 0 of sine type. The reason can be seen in the following subsection that deals with the cartesian representation.
See here for a list of real spherical harmonics up to and including , which can be seen to be consistent with the output of the equations above.
The corresponding inverse equations are
Use in quantum chemistry
As is known from the analytic solutions for the hydrogen atom, the eigenfunctions of the angular part of the wave function are spherical harmonics. However, the solutions of the non-relativistic Schrödinger equation without magnetic terms can be made real. This is why the real forms are extensively used in basis functions for quantum chemistry, as the programs don't then need to use complex algebra. Here, it is important to note that the real functions span the same space as the complex ones would.
Spherical harmonics in Cartesian form
The following expresses normalized spherical harmonics in Cartesian coordinates (Condon-Shortley phase):
and for m = 0:
For this reduces to
Using the expressions for , , and listed explicitly above we obtain:
Using the equations above to form the real spherical harmonics, it is seen that for only the terms (cosines) are included, and for only the terms (sines) are included:
and for m = 0:
Spherical harmonics expansion
The Laplace spherical harmonics form a complete set of orthonormal functions and thus form an orthonormal basis of the Hilbert space of square-integrable functions. On the unit sphere, any square-integrable function can thus be expanded as a linear combination of these:
This expansion holds in the sense of mean-square convergence — convergence in L2 of the sphere — which is to say that
The expansion coefficients are the analogs of Fourier coefficients, and can be obtained by multiplying the above equation by the complex conjugate of a spherical harmonic, integrating over the solid angle Ω, and utilizing the above orthogonality relationships. This is justified rigorously by basic Hilbert space theory. For the case of orthonormalized harmonics, this gives:
A square-integrable function f can also be expanded in terms of the real harmonics Yℓm above as a sum
The convergence of the series holds again in the same sense, but the benefit of the real expansion is that for real functions f the expansion coefficients become real.
Power spectrum in signal processing
The total power of a function f is defined in the signal processing literature as the integral of the function squared, divided by the area of its domain. Using the orthonormality properties of the real unit-power spherical harmonic functions, it is straightforward to verify that the total power of a function defined on the unit sphere is related to its spectral coefficients by a generalization of Parseval's theorem:
is defined as the angular power spectrum. In a similar manner, one can define the cross-power of two functions as
is defined as the cross-power spectrum. If the functions f and g have a zero mean (i.e., the spectral coefficients f00 and g00 are zero), then Sff(ℓ) and Sfg(ℓ) represent the contributions to the function's variance and covariance for degree ℓ, respectively. It is common that the (cross-)power spectrum is well approximated by a power law of the form
When β = 0, the spectrum is "white" as each degree possesses equal power. When β < 0, the spectrum is termed "red" as there is more power at the low degrees with long wavelengths than higher degrees. Finally, when β > 0, the spectrum is termed "blue". The condition on the order of growth of Sff(ℓ) is related to the order of differentiability of f in the next section.
One can also understand the differentiability properties of the original function f in terms of the asymptotics of Sff(ℓ). In particular, if Sff(ℓ) decays faster than any rational function of ℓ as ℓ → ∞, then f is infinitely differentiable. If, furthermore, Sff(ℓ) decays exponentially, then f is actually real analytic on the sphere.
The general technique is to use the theory of Sobolev spaces. Statements relating the growth of the Sff(ℓ) to differentiability are then similar to analogous results on the growth of the coefficients of Fourier series. Specifically, if
then f is in the Sobolev space Hs(S2). In particular, the Sobolev embedding theorem implies that f is infinitely differentiable provided that
for all s.
A mathematical result of considerable interest and use is called the addition theorem for spherical harmonics. This is a generalization of the trigonometric identity
in which the role of the trigonometric functions appearing on the right-hand side is played by the spherical harmonics and that of the left-hand side is played by the Legendre polynomials.
Consider two unit vectors x and y, having spherical coordinates (θ,φ) and (θ′,φ′), respectively. The addition theorem states
where Pℓ is the Legendre polynomial of degree ℓ. This expression is valid for both real and complex harmonics. The result can be proven analytically, using the properties of the Poisson kernel in the unit ball, or geometrically by applying a rotation to the vector y so that it points along the z-axis, and then directly calculating the right-hand side.
In particular, when x = y, this gives Unsöld's theorem
which generalizes the identity cos2θ + sin2θ = 1 to two dimensions.
In the expansion (1), the left-hand side Pℓ(x·y) is a constant multiple of the degree ℓ zonal spherical harmonic. From this perspective, one has the following generalization to higher dimensions. Let Yj be an arbitrary orthonormal basis of the space Hℓ of degree ℓ spherical harmonics on the n-sphere. Then , the degree ℓ zonal harmonic corresponding to the unit vector x, decomposes as
Furthermore, the zonal harmonic is given as a constant multiple of the appropriate Gegenbauer polynomial:
where ωn−1 is the volume of the (n−1)-sphere.
The Clebsch–Gordan coefficients are the coefficients appearing in the expansion of the product of two spherical harmonics in terms of spherical harmonics itself. A variety of techniques are available for doing essentially the same calculation, including the Wigner 3-jm symbol, the Racah coefficients, and the Slater integrals. Abstractly, the Clebsch–Gordan coefficients express the tensor product of two irreducible representations of the rotation group as a sum of irreducible representations: suitably normalized, the coefficients are then the multiplicities.
The spherical harmonics have well defined parity in the sense that they are either even or odd with respect to reflection about the origin. Reflection about the origin is represented by the operator . For the spherical angles, this corresponds to the replacement . The associated Legendre polynomials gives (−1)ℓ+m and from the exponential function we have (−1)m, giving together for the spherical harmonics a parity of (−1)ℓ:
This remains true for spherical harmonics in higher dimensions: applying a point reflection to a spherical harmonic of degree ℓ changes the sign by a factor of (−1)ℓ.
Visualization of the spherical harmonics
The Laplace spherical harmonics can be visualized by considering their "nodal lines", that is, the set of points on the sphere where , or alternatively where . Nodal lines of are composed of circles: some are latitudes and others are longitudes. One can determine the number of nodal lines of each type by counting the number of zeros of in the latitudinal and longitudinal directions independently. For the latitudinal direction, the real and imaginary components of the associated Legendre polynomials each possess ℓ−|m| zeros, whereas for the longitudinal direction, the trigonometric sin and cos functions possess 2|m| zeros.
When the spherical harmonic order m is zero (upper-left in the figure), the spherical harmonic functions do not depend upon longitude, and are referred to as zonal. Such spherical harmonics are a special case of zonal spherical functions. When ℓ = |m| (bottom-right in the figure), there are no zero crossings in latitude, and the functions are referred to as sectoral. For the other cases, the functions checker the sphere, and they are referred to as tesseral.
More general spherical harmonics of degree ℓ are not necessarily those of the Laplace basis , and their nodal sets can be of a fairly general kind.
List of spherical harmonics
Analytic expressions for the first few orthonormalized Laplace spherical harmonics that use the Condon-Shortley phase convention:
The classical spherical harmonics are defined as functions on the unit sphere S2 inside three-dimensional Euclidean space. Spherical harmonics can be generalized to higher-dimensional Euclidean space Rn as follows. Let Pℓ denote the space of homogeneous polynomials of degree ℓ in n variables. That is, a polynomial P is in Pℓ provided that
obtained by restriction from Aℓ.
The following properties hold:
- The sum of the spaces Hℓ is dense in the set of continuous functions on Sn−1 with respect to the uniform topology, by the Stone-Weierstrass theorem. As a result, the sum of these spaces is also dense in the space L2(Sn−1) of square-integrable functions on the sphere. Thus every square-integrable function on the sphere decomposes uniquely into a series a spherical harmonics, where the series converges in the L2 sense.
- For all f ∈ Hℓ, one has
- where ΔSn−1 is the Laplace–Beltrami operator on Sn−1. This operator is the analog of the angular part of the Laplacian in three dimensions; to wit, the Laplacian in n dimensions decomposes as
- It follows from the Stokes theorem and the preceding property that the spaces Hℓ are orthogonal with respect to the inner product from L2(Sn−1). That is to say,
- for f ∈ Hℓ and g ∈ Hk for k ≠ ℓ.
- Conversely, the spaces Hℓ are precisely the eigenspaces of ΔSn−1. In particular, an application of the spectral theorem to the Riesz potential gives another proof that the spaces Hℓ are pairwise orthogonal and complete in L2(Sn−1).
- Every homogeneous polynomial P ∈ Pℓ can be uniquely written in the form
- where Pj ∈ Aj. In particular,
An orthogonal basis of spherical harmonics in higher dimensions can be constructed inductively by the method of separation of variables, by solving the Sturm-Liouville problem for the spherical Laplacian
where φ is the axial coordinate in a spherical coordinate system on Sn−1. The end result of such a procedure is
where the indices satisfy |ℓ1| ≤ ℓ2 ≤ ... ≤ ℓn−1 and the eigenvalue is −ℓn−1(ℓn−1 + n−2). The functions in the product are defined in terms of the Legendre function
Connection with representation theory
The space Hℓ of spherical harmonics of degree ℓ is a representation of the symmetry group of rotations around a point (SO(3)) and its double-cover SU(2). Indeed, rotations act on the two-dimensional sphere, and thus also on Hℓ by function composition
The elements of Hℓ arise as the restrictions to the sphere of elements of Aℓ: harmonic polynomials homogeneous of degree ℓ on three-dimensional Euclidean space R3. By polarization of ψ ∈ Aℓ, there are coefficients symmetric on the indices, uniquely determined by the requirement
The condition that ψ be harmonic is equivalent to the assertion that the tensor must be trace free on every pair of indices. Thus as an irreducible representation of SO(3), Hℓ is isomorphic to the space of traceless symmetric tensors of degree ℓ.
More generally, the analogous statements hold in higher dimensions: the space Hℓ of spherical harmonics on the n-sphere is the irreducible representation of SO(n+1) corresponding to the traceless symmetric ℓ-tensors. However, whereas every irreducible tensor representation of SO(2) and SO(3) is of this kind, the special orthogonal groups in higher dimensions have additional irreducible representations that do not arise in this manner.
The special orthogonal groups have additional spin representations that are not tensor representations, and are typically not spherical harmonics. An exception are the spin representation of SO(3): strictly speaking these are representations of the double cover SU(2) of SO(3). In turn, SU(2) is identified with the group of unit quaternions, and so coincides with the 3-sphere. The spaces of spherical harmonics on the 3-sphere are certain spin representations of SO(3), with respect to the action by quaternionic multiplication.
The angle-preserving symmetries of the two-sphere are described by the group of Möbius transformations PSL(2,C). With respect to this group, the sphere is equivalent to the usual Riemann sphere. The group PSL(2,C) is isomorphic to the (proper) Lorentz group, and its action on the two-sphere agrees with the action of the Lorentz group on the celestial sphere in Minkowski space. The analog of the spherical harmonics for the Lorentz group is given by the hypergeometric series; furthermore, the spherical harmonics can be re-expressed in terms of the hypergeometric series, as SO(3) = PSU(2) is a subgroup of PSL(2,C).
|Wikimedia Commons has media related to Spherical harmonics.|
- Cylindrical harmonics
- Spherical basis
- Spin spherical harmonics
- Spin-weighted spherical harmonics
- Sturm–Liouville theory
- Table of spherical harmonics
- Vector spherical harmonics
- A historical account of various approaches to spherical harmonics in three-dimensions can be found in Chapter IV of MacRobert 1967. The term "Laplace spherical harmonics" is in common use; see Courant & Hilbert 1962 and Meijer & Bauer 2004.
- The approach to spherical harmonics taken here is found in (Courant & Hilbert 1966, §V.8, §VII.5).
- Physical applications often take the solution that vanishes at infinity, making A = 0. This does not affect the angular portion of the spherical harmonics.
- Edmonds 1957, §2.5
- Messiah, Albert (1999). Quantum mechanics : two volumes bound as one (Two vol. bound as one, unabridged reprint ed.). Mineola, NY: Dover. ISBN 9780486409245.
- al.], Claude Cohen-Tannoudji, Bernard Diu, Franck Laloë; transl. from the French by Susan Reid Hemley ... [et (1996). Quantum mechanics. Wiley-Interscience: Wiley. ISBN 9780471569527.
- Heiskanen and Moritz, Physical Geodesy, 1967, eq. 1-62
- Watson & Whittaker 1927, p. 392.
- This is valid for any orthonormal basis of spherical harmonics of degree ℓ. For unit power harmonics it is necessary to remove the factor of 4π.
- Watson & Whittaker 1927, p. 395
- Unsöld 1927
- Stein & Weiss 1971, §IV.2
- Eremenko, Jakobson & Nadirashvili 2007
- Solomentsev 2001; Stein & Weiss 1971, §Iv.2
- Higuchi, Atsushi (1987). "Symmetric tensor spherical harmonics on the N-sphere and their application to the de Sitter group SO(N,1)". Journal of Mathematical Physics 28 (7).
- N. Vilenkin, Special Functions and the Theory of Group Representations, Am. Math. Soc. Transl.,vol. 22, (1968).
- J. D. Talman, Special Functions, A Group Theoretic Approach, (based on lectures by E.P. Wigner), W. A. Benjamin, New York (1968).
- W. Miller, Symmetry and Separation of Variables, Addison-Wesley, Reading (1977).
- A. Wawrzyńczyk, Group Representations and Special Functions, Polish Scientific Publishers. Warszawa (1984).
- Cited references
- Courant, Richard; Hilbert, David (1962), Methods of Mathematical Physics, Volume I, Wiley-Interscience.
- Edmonds, A.R. (1957), Angular Momentum in Quantum Mechanics, Princeton University Press, ISBN 0-691-07912-9
- Eremenko, Alexandre; Jakobson, Dmitry; Nadirashvili, Nikolai (2007), "On nodal sets and nodal domains on and ", Université de Grenoble. Annales de l'Institut Fourier 57 (7): 2345–2360, ISSN 0373-0956, MR 2394544
- MacRobert, T.M. (1967), Spherical harmonics: An elementary treatise on harmonic functions, with applications, Pergamon Press.
- Meijer, Paul Herman Ernst; Bauer, Edmond (2004), Group theory: The application to quantum mechanics, Dover, ISBN 978-0-486-43798-9.
- Solomentsev, E.D. (2001), "Spherical harmonics", in Hazewinkel, Michiel, Encyclopedia of Mathematics, Springer, ISBN 978-1-55608-010-4.
- Stein, Elias; Weiss, Guido (1971), Introduction to Fourier Analysis on Euclidean Spaces, Princeton, N.J.: Princeton University Press, ISBN 978-0-691-08078-9.
- Unsöld, Albrecht (1927), "Beiträge zur Quantenmechanik der Atome", Annalen der Physik 387 (3): 355–393, Bibcode:1927AnP...387..355U, doi:10.1002/andp.19273870304.
- Watson, G. N.; Whittaker, E. T. (1927), A Course of Modern Analysis, Cambridge University Press, p. 392.
- General references
- E.W. Hobson, The Theory of Spherical and Ellipsoidal Harmonics, (1955) Chelsea Pub. Co., ISBN 978-0-8284-0104-3.
- C. Müller, Spherical Harmonics, (1966) Springer, Lecture Notes in Mathematics, Vol. 17, ISBN 978-3-540-03600-5.
- E. U. Condon and G. H. Shortley, The Theory of Atomic Spectra, (1970) Cambridge at the University Press, ISBN 0-521-09209-4, See chapter 3.
- J.D. Jackson, Classical Electrodynamics, ISBN 0-471-30932-X
- Albert Messiah, Quantum Mechanics, volume II. (2000) Dover. ISBN 0-486-40924-4.
- Press, WH; Teukolsky, SA; Vetterling, WT; Flannery, BP (2007), "Section 6.7. Spherical Harmonics", Numerical Recipes: The Art of Scientific Computing (3rd ed.), New York: Cambridge University Press, ISBN 978-0-521-88068-8
- D. A. Varshalovich, A. N. Moskalev, V. K. Khersonskii Quantum Theory of Angular Momentum,(1988) World Scientific Publishing Co., Singapore, ISBN 9971-5-0107-4
- Weisstein, Eric W., "Spherical harmonics", MathWorld.