Strontium oxide

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Strontium oxide[1]
Identifiers
CAS number 1314-11-0 YesY
Properties
Molecular formula SrO
Molar mass 103.62 g/mol
Appearance colorless cubic crystals
Density 4.70 g/cm3
Melting point

2531°C

Boiling point

> 3000 °C (decomp)

Solubility in water reacts, forms Sr(OH)2
Solubility miscible with potassium hydroxide
slightly soluble in alcohol
insoluble in acetone and ether
Refractive index (nD) 1.810 [2]
Structure
Crystal structure Halite (cubic), cF8
Space group Fm3m, No. 225
Coordination
geometry
Octahedral (Sr2+); octahedral (O2–)
Thermochemistry
Std enthalpy of
formation
ΔfHo298
-592.0 kJ·mol−1
Standard molar
entropy
So298
57.2 J·mol−1·K−1
Specific heat capacity, C 44.3 J·mol−1·K−1
Hazards
EU Index Not listed
Flash point Non-flammable
Related compounds
Other anions Strontium sulfide
Other cations Beryllium oxide
Magnesium oxide
Calcium oxide
Barium oxide
Related compounds Strontium hydroxide
 YesY (verify) (what is: YesY/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Strontium oxide or strontia, SrO, is formed when strontium reacts with oxygen. Burning strontium in air results in a mixture of strontium oxide and strontium nitride. It also forms from the decomposition of strontium carbonate SrCO3. It is a strongly basic oxide.

Contents

[edit] Uses

About 8% by weight of television picture tube glass is strontium oxide, which has been the major use of strontium since 1970.[3] Color televisions and other devices containing color cathode ray tubes sold in the United States are required by law to use strontium in the faceplate to block X-ray emission (these X-ray emitting TV's are no longer in production). Lead oxide can be used in the neck and funnel, but causes discoloration when used in the faceplate.[4]

[edit] Reactions

Elemental strontium is formed when strontium oxide is heated with aluminium in a vacuum.[1]

[edit] References

  1. ^ a b Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, FL: CRC Press. pp. 4–87. ISBN 0849305942. 
  2. ^ Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN 0070494398
  3. ^ Ober, Joyce A.; Polyak, Désirée E.. "Mineral Yearbook 2007:Strontium". United States Geological Survey. http://minerals.usgs.gov/minerals/pubs/commodity/strontium/myb1-2007-stron.pdf. Retrieved 2009-09-14. 
  4. ^ Méar, F; Yot, P; Cambon, M; Ribes, M (2006). "The characterization of waste cathode-ray tube glass.". Waste management 26 (12): 1468–76. doi:10.1016/j.wasman.2005.11.017. ISSN 0956-053X. PMID 16427267. 

[edit] External links

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