Sulfur dye

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Sulfur dyes are most commonly used dyes manufactured for cotton in terms of volume. They are cheap, generally have good wash-fastness, and are easy to apply. Sulfur dyes are predominantly black, brown, and blue.[1] Red sulfur dyes are unknown, although a pink or lighter scarlet color is available.

Representative sulfur dyes and chemical structures[edit]

The most important member of the class is Sulfur Black 1. It is produced by the thermal reaction of 2,4-dinitrophenol and sodium sulfide in hot water. This treatment affords an insoluble dye. Like many sulfur dyes, Sulfur Black 1 is imperfectly understood, and the material is probably heterogeneous. It is speculated to be a polymer consisting of thianthrene and phenothiazine subunits. The so-called sulfur bake dyes are produced from 1,4-diaminobenzene and diaminotoluene derivatives. These dyes are proposed to consist of polymers with benzothiazole subunits. Members of the sulfur bake dyes class are Sulfur Orange 1, Sulfur Brown 21, and Sulfur Green 12.[1]

Application method[edit]

Sulfur dyes are water insoluble. In the presence of a reducing agent and at alkali pH's at elevated temperature of around 80 °C, the dye particles disintegrate, which then becomes water soluble and hence can be absorbed by the fabric. Sodium sulfide or sodium hydrosulfide are suitable reducing agents. Common salt facilitates the absorption. After the fabric is removed from the dye solution, it is allowed to stand in air whereupon the dye is regenerated by oxidation. The regenerated parent dye is insoluble in water. Oxidation can also be effected in air or by hydrogen peroxide or sodium bromate in a mildly acidic solution.

The low water solubility is the basis of the good wash-fastness of these dyed fabrics. These dyes have good all round fastness except to chlorine bleaches. Because the dye is water-insoluble, it will not bleed when washed in water and will not stain other clothes. The dye, however, may have poor fastness to rubbing. The dyes are bleached by hypochlorite bleach.

Environmental issues[edit]

Due to the highly polluting nature of the dye-bath effluent, sulfur dyes are being slowly phased out. Sulfur dyes are primarily used for dark colors such as blacks, browns, and dark blues. Recent advances in dyeing technologies have allowed the substitution of toxic sulfide reducing agents. Glucose in basic solution is now used and both low sulfide and zero sulfide products are available.

Future developments in the field of reducing dye levels by means of electro-chemical processes are promising.


  1. ^ a b Gert Nagl, "Sulfur Dyes" in Ullmann's Encyclopedia of Industrial Chemistry 2005, Wiley-VCH, Weinheim. doi:10.1002/14356007.a25_613