Tellurous acid

From Wikipedia, the free encyclopedia
Jump to: navigation, search
Tellurous acid
Identifiers
CAS number 10049-23-7 N
PubChem 24936
ChemSpider 23310 YesY
ChEBI CHEBI:30465 YesY
Jmol-3D images Image 1
Properties
Molecular formula H2TeO3
Molar mass 177.616 grams
Appearance colorless crystals
Density ~ 3 g/cm3
Boiling point decomp.
Solubility in water negligible
Acidity (pKa) pKa(1) = 2.48, pKa(2) = 7.70 [1]
Structure
Crystal structure unknown
Molecular shape pyramidal at Te
Related compounds
Other anions Selenous acid
Sulfurous acid
Other cations Sodium tellurite
Related compounds Telluric acid
Selenic acid
Sulfuric acid
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
 N (verify) (what is: YesY/N?)
Infobox references

Tellurous acid is an inorganic compound with the formula H2TeO3. It is the oxoacid of tellurium(IV).[2] The compound is not well characterized. An alternative way of writing its formula is (HO)2TeO. In principle, tellurous acid would form by treatment of tellurium dioxide with water, i.e. hydrolysis. The related conjugate base is well known in the form of several salts such as potassium acid tellurite, KHTeO3.

Properties[edit]

In contrast to the analogous compound Selenous acid, Tellurous acid is only metastable. Most tellurite salts contain the TeO32− ion. Oxidation of its aqueous solution with hydrogen peroxide gives the tellurate ion. It is usually prepared as an aqueous solution where it acts as a weak acid.[1]

References[edit]

  1. ^ a b Catherine E. Housecroft; Alan G. Sharpe (2008). "Chapter 16: The group 16 elements". Inorganic Chemistry, 3rd Edition. Pearson. p. 524. ISBN 978-0-13-175553-6. 
  2. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 0080379419.