Template:Infobox phosphorus

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siliconphosphorussulfur
N

P

As
Appearance
colorless, waxy white, yellow, scarlet, red, violet, black

waxy white (yellow cut), red (granules center left, chunk center right), and violet phosphorus
General properties
Name, symbol, number phosphorus, P, 15
Pronunciation /ˈfɒsfərəs/ fos-fər-əs
Element category nonmetal
Group, period, block 153, p
Standard atomic weight 30.973762(2)
Electron configuration [Ne] 3s2 3p3
Electrons per shell 2, 8, 5 (Image)
Physical properties
Phase solid
Density (near r.t.) (white) 1.823, (red) ≈ 2.2 – 2.34, (violet) 2.36, (black) 2.69 g·cm−3
Melting point (white) 44.2 °C, (black) 610 °C
Sublimation point (red) ≈ 416 – 590  °C, (violet) 620 °C
Boiling point (white) 280.5 °C
Heat of fusion (white) 0.66 kJ·mol−1
Heat of vaporization (white) 12.4 kJ·mol−1
Molar heat capacity (white)
23.824 J·mol−1·K−1
Vapor pressure (white)
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 279 307 342 388 453 549
Vapor pressure (red, bp. 431 °C)
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 455 489 529 576 635 704
Atomic properties
Oxidation states 5, 4, 3, 2[1], 1 [2], −1, −2, −3
(mildly acidic oxide)
Electronegativity 2.19 (Pauling scale)
Ionization energies
(more)
1st: 1011.8 kJ·mol−1
2nd: 1907 kJ·mol−1
3rd: 2914.1 kJ·mol−1
Covalent radius 107±3 pm
Van der Waals radius 180 pm
Miscellanea
Magnetic ordering (white,red,violet,black) diamagnetic[3]
Thermal conductivity (white) 0.236, (black) 12.1 W·m−1·K−1
Bulk modulus (white) 5, (red) 11 GPa
CAS registry number 7723-14-0
Most stable isotopes
Main article: Isotopes of phosphorus
iso NA half-life DM DE (MeV) DP
31P 100% 31P is stable with 16 neutrons
32P syn 14.28 d β 1.709 32S
33P syn 25.3 d β 0.249 33S
· r

References

  1. ^ webelements
  2. ^ Ellis, Bobby D.; MacDonald, Charles L. B. (2006). "Phosphorus(I) Iodide:  A Versatile Metathesis Reagent for the Synthesis of Low Oxidation State Phosphorus Compounds". Inorganic Chemistry 45 (17): 6864–74. doi:10.1021/ic060186o. PMID 16903744. 
  3. ^ Magnetic susceptibility of the elements and inorganic compounds, in Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5. 
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