Tetracene

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Tetracene
Skeletal formula
Ball-and-stick model
Tetracene crystals
Names
IUPAC name
Tetracene
Other names
Naphthacene
Benz[b]anthracene
2,3-Benzanthracene
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.001.945 Edit this at Wikidata
  • InChI=1S/C18H12/c1-2-6-14-10-18-12-16-8-4-3-7-15(16)11-17(18)9-13(14)5-1/h1-12H checkY
    Key: IFLREYGFSNHWGE-UHFFFAOYSA-N checkY
  • c34cc2cc1ccccc1cc2cc3cccc4
Properties
C18H12
Molar mass 228.29 g/mol
Appearance Yellow to orange solid
Melting point 357 °C (675 °F; 630 K)
Insoluble
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Tetracene, also called naphthacene, is a polycyclic aromatic hydrocarbon. It has the appearance of a pale orange powder. Tetracene is the four-ringed member of the series of acenes, the previous one being anthracene (tricene) and the next one being pentacene.

Tetracene is a molecular organic semiconductor, used in organic field-effect transistors (OFETs) and organic light-emitting diodes (OLEDs). In May 2007, researchers from two Japanese universities, Tohoku University in Sendai and Osaka University, reported an ambipolar light-emitting transistor made of a single tetracene crystal.[1] Ambipolar means that the electric charge is transported by both positively charged holes and negatively charged electrons. Tetracene can be also used as a gain medium in dye lasers as a sensitiser in chemoluminescence.

Jan Hendrik Schön during his time at Bell Labs (1997–2002) claimed to have developed an electrically pumped laser based on tetracene. However, his results could not be reproduced, and this is considered to be a scientific fraud.[2]

References

  1. ^ T. Takahashi, T. Takenobu, J. Takeya, Y. Iwasa (2007). "Ambipolar Light-Emitting Transistors of a Tetracene Single Crystal". Advanced Functional Materials. 17 (10): 1623–1628. doi:10.1002/adfm.200700046.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  2. ^ Agin, Dan (2007). Junk Science: An Overdue Indictment of Government, Industry, and Faith Groups That Twist Science for Their Own Gain. Macmillan. ISBN 978-0-312-37480-8.