Thujopsene

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Thujopsene
Thujopsene.svg
Identifiers
CAS number 470-40-6
PubChem 442402
ChemSpider 390845
Jmol-3D images Image 1
Properties
Molecular formula C15H24
Molar mass 204.35 g mol−1
Density 0.936 g/mL (20 °C)[1]
Boiling point 258-260 °C[1]
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
Infobox references

Thujopsene is a natural chemical compound, classified as a sesquiterpene, with the molecular formula C15H24.

Thujopsene is found in the essential oil of a variety of conifers,[2] in particular Juniperus cedrus and Thujopsis dolabrata in which it comprises around 2.2% of the weight of the heartwood.[3]

Biosynthesis[edit]

Thujopsene is biosynthesized from farnesyl pyrophosphate (FPP):[4]

ThujopseneBiosynthesis.png

References[edit]

  1. ^ a b "(−)-Thujopsene". Sigma-Aldrich. 
  2. ^ Erdtman, H.; Norin, T. (1960). "Structure of thujopsene and hinokiic acid from coniferous wood". Chemistry and Industry (22): 622–623. 
  3. ^ Runeburg, Jarl; Gramstad, Thor; Larsson, Lennart; Dodson, R. M. (1960). "The Chemistry of the Natural Order Cupressales XXX. Constituents of Juniperus cedrus L.". Acta Chemica Scandinavica 14: 1991–1994. doi:10.3891/acta.chem.scand.14-1991. 
  4. ^ J. Mann et al. Natural Products: their chemistry and biological significance. ISBN 978-0582060098.