Triboluminescence is an optical phenomenon in which light is generated through the breaking of chemical bonds in a material when it is pulled apart, ripped, scratched, crushed, or rubbed (see tribology). The phenomenon is not fully understood, but appears to be caused by the separation and reunification of electrical charges. The term comes from the Greek τρίβειν ("to rub"; see tribology) and the Latin lumen (light). Triboluminescence can be observed when breaking sugar crystals (especially Wint-O-Green Life Savers) and peeling adhesive tapes.
Triboluminescence is often used as a synonym for fractoluminescence (a term sometimes used when referring only to light emitted from fractured crystals). Triboluminescence differs from piezoluminescence in that a piezoluminescent material emits light when it is deformed, as opposed to broken. These are examples of mechanoluminescence, which is luminescence resulting from any mechanical action on a solid.
Uncompahgre Ute Indians
The Uncompahgre Ute Indians from Central Colorado are one of the first documented groups of people in the world credited with the application of mechanoluminescence involving the use of quartz crystals to generate light. The Ute constructed special ceremonial rattles made from buffalo rawhide which they filled with clear quartz crystals collected from the mountains of Colorado and Utah. When the rattles were shaken at night during ceremonies, the friction and mechanical stress of the quartz crystals impacting together produced flashes of light visible through the translucent buffalo hide.
The first recorded observation is attributed to English scholar Francis Bacon when he recorded in his 1620 Novum Organum that "It is well known that all sugar, whether candied or plain, if it be hard, will sparkle when broken or scraped in the dark." The scientist Robert Boyle also reported on some of his work on triboluminescence in 1663. In the late 1790s, sugar production began to produce more refined sugar crystals. These crystals were formed into a large solid cone for transport and sale. This solid cone of sugar had to be broken into usable chunks using a device known as sugar nips. People began to notice that as sugar was "nipped" in low light, tiny bursts of light were visible.
A historically important instance of triboluminescence occurred in Paris in 1675. Astronomer Jean-Felix Picard observed that his barometer was glowing in the dark as he carried it. His barometer consisted of a glass tube that was partially filled with mercury. Whenever the mercury slid down the glass tube, the empty space above the mercury would glow. While investigating this phenomenon, researchers discovered that static electricity could cause low-pressure air to glow. This discovery revealed the possibility of electric lighting.
Mechanism of action
Materials scientists have not yet arrived at a full understanding of the effect, but the current theory of triboluminescence — based upon crystallographic, spectroscopic, and other experimental evidence — is that upon fracture of asymmetrical materials, charge is separated. When the charges recombine, the electric discharge ionizes the surrounding air, causing a flash of light. Research further suggests that crystals which display triboluminescence must lack symmetry (in order to permit charge separation) and be poor conductors. However, there are substances which break this rule, and which do not possess asymmetry, yet display triboluminescence anyway, such as hexakis(antipyrine)terbium iodide. It is thought that these materials contain impurities, which confer properties of asymmetry to the substance.
A diamond may begin to glow while being rubbed. This occasionally happens to diamonds while a facet is being ground or the diamond is being sawn during the cutting process. Diamonds may fluoresce blue or red. Some other minerals, such as quartz, are triboluminescent, emitting light when rubbed together.
Ordinary Pressure-sensitive tape ("Scotch tape") displays a glowing line where the end of the tape is being pulled away from the roll. In 1953, Soviet scientists first observed that unpeeling a roll of tape in a vacuum produced X-rays. The mechanism of X-ray generation was studied further in 2008.
Also, when sugar crystals are crushed, tiny electrical fields are created, separating positive and negative charges that then create sparks while trying to reunite. Wint-O-Green Life Savers work especially well for creating such sparks, because wintergreen oil (methyl salicylate) is fluorescent and converts ultraviolet light into blue light.
Fractoluminescence is often used as a synonym for triboluminescence. It is the emission of light from the fracture (rather than rubbing) of a crystal, but fracturing often occurs with rubbing. Depending upon the atomic and molecular composition of the crystal, when the crystal fractures a charge separation can occur making one side of the fractured crystal positively charged and the other side negatively charged. Like in triboluminescence, if the charge separation results in a large enough electric potential, a discharge across the gap and through the bath gas between the interfaces can occur. The potential at which this occurs depends upon the dielectric properties of the bath gas.
This phenomenon can be demonstrated by removing ice from a freezer in a darkened room, under conditions in which the ice makes cracking sounds from sudden thermal expansion. If the ambient light is dim enough, flashes of white light from the cracking ice can be observed.
- Martín Gil Jesús and Martín Gil Francisco J. "Triboluminescence of new uranyl salts", Journal of Chemical Education, 1978, 55(5):340.
- BBC Big Bang on triboluminescence
- Timothy Dawson Changing colors: now you see them, now you don't Coloration Technology 2010 doi:10.1111/j.1478-4408.2010.00247.x
- Bacon, Francis. Novum Organum
- See Wikipedia's article: Barometric light.
- "Hexakis(antipyrine-O)terbium(III) triiodide at 160 K: confirmation of a centrosymmetric structure for a brilliantly triboluminescent complex". Acta Crystallographica Section E 58 (4). April 2002. Retrieved 21 September 2013.
- "Rockhounding Arkansas: Experiments with Quartz". Rockhoundingar.com. Retrieved 2012-10-09.
- Nature (journal). Sticky tape generates X-rays
- Karasev, V. V., Krotova, N. A. & Deryagin, B. W. (1953) "Study of electronic emission during the stripping of a layer of high polymer from glass in a vacuum" [in Russian], Doklady Akademii Nauk SSSR (Proceedings of the USSR Academy of Sciences) 88: 777-780.
- Camara C. G., Escobar J. V., Hird J. R., & Putterman S. J. (2008) "Correlation between nanosecond X-ray flashes and stick-slip friction in peeling tape," Nature 455: 1089-1092.
- Katherine Bourzac (2008-10-23). "X-Rays Made with Scotch Tape". Technology Review. Retrieved 2012-10-09.
- "Science News Online - This Week - News Feature - 5/17/97". Sciencenews.org. 1997-05-17. Retrieved 2012-10-09.
- "IUPAC Gold Book - triboluminescence". Goldbook.iupac.org. 2012-08-19. Retrieved 2012-10-09.
- Page on "wintergreen candy and other triboluminescent materials" from Towson University department of chemistry by Dr. Sweeting.
- 1997 article from science news explaining Dr. Sweeting's work.
- 2006 article "Sound science behind glowing sugar" on PhysicsWeb.
- Correlation between nanosecond X-ray flashes and stick–slip friction in peeling tape. Nature 455, 1089-1092 (23 October 2008) | doi:10.1038/nature07378