|Jmol-3D images||Image 1|
|Molar mass||55.92 g/mol|
|Appearance||Colorless gas or liquid|
|Density||0.625 g/cm3 at -100 °C|
|Melting point||−161.5 °C (−258.7 °F; 111.6 K)|
|Boiling point||−20.2 °C (−4.4 °F; 253.0 K)|
|Solubility in water||slight, Highly reactive|
|S-phrases||S7 S23 S26 S36/37/39 S43 S45|
|Main hazards||Spontaneously flammable in air; causes burns|
|Autoignition temperature||−40 °C (−40 °F; 233 K)|
|Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)|
|(what is: / ?)|
Trimethylborane (TMB) is a toxic, pyrophoric gas with the formula B(CH3)3 (which can also be written as Me3B, with Me representing methyl). Its melting point is -161.5 °C and its boiling point is -20.2 °C. Vapour pressure is given by log P = 6.1385+1.75 log T - 1393.3/T - 0.007735 T. T is temperature in Kelvin. CAS number is 593-90-8. Molecular weight is 55.914. The heat of vapourisation is 25.6 kJ/mol.
As a liquid it is colourless. The strongest line in the infrared spectrum is at 1330 cm−1 followed by lines at 3010 cm−1 and 1185 cm−1.
Trimethylborane was first made by Stock and Zeidler. Their method of preparation combined boron trichloride gas with dimethylzinc. Although the substance can be prepared using Grignard reagents the output is contaminated by unwanted products from the solvent. Trimethylborane can be made on a small scale with a 98% yield by reacting trimethylaluminium in hexane with boron tribromide in dibutyl ether as a solvent. Yet other methods are reacting tributyl borate with trimethylaluminium chloride, or potassium tetrafluoroborate with trimethylaluminium. Yet another method is to add boron trifluoride in ether to methyl magnesium iodide.
Trimethylborane spontaneously ignites in air if the concentration is high enough. It burns with a green flame producing soot.
Trimethylborane is a strong Lewis acid. It reacts with water and chlorine at room temperature. It also reacts with grease but not with Teflon or glass. Trimethylborane can form an adduct with ammonia: (NH3):B(CH3)3.
It reacts as a gas with trimethylphosphine to form a solid Lewis salt with a heat of formation of -41 kcal per mol. This adduct has a heat of sublimation of -24.6 kcal/mol. No reaction occurs with trimethylarsine or trimethylstibine.
Methyl lithium reacting with the Trimethylborane produces a tetramethylborate salt: LiB(CH3)4. The tetramethylborate ion has a negative charge and is isoelectronic with neopentane, tetramethylsilane, and the tetramethylammonium cation.
- http://www.voltaix.com/images/doc/Msb000_TMB.pdf MSDS from Voltaix
- William S. Rees, Jr. and al (1990). Alvin P. Ginsberg, ed. Trimethylborane. Inorganic Syntheses 27. p. 339.
- Graner, G., Hirota, E., Iijima, T., Kuchitsu, K., Ramsay, D. A., Vogt, J., Vogt, N. "C3H9B Trimethylborane". SpringerMaterials 25C. doi:10.1007/10688787_381.
- Roland Koumlstera, Paul Bingera Wilhelm, V. Dahlhof (1973). "A Convenient Preparation of Trimethylborane and Triethylborane". Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry 3 (4): 359–367. doi:10.1080/00945717308057281.
- Donald Charles Mente (May 1975). "The Reactions of Trimethyl group Va Lewis Bases with simple Boron Lewis Acids".
- Herbert Ellern (1968). "Military and Civilian Pyrotechnics". Chemical Publishing Company. p. 24. CiteSeerX: 10
.1 .1 .137 .1104.
- Gaylon S. Ross et al (2 October 1961). "Preparation of High Purity Trimethylborane". Journal of Research of the National Bureau of Standards Physics and Chemistry 66 (1).
- Georg Wittig in 1958