|Jmol-3D images||Image 1|
|Molar mass||60.10 g mol−1|
|Density||790 mg mL−1 (at 20 °C)|
-57 °C, 216 K, -71 °F
64 °C, 337.1 K, 147 °F
|Vapor pressure||13.7 kPa (at 20 °C)|
|Refractive index (nD)||1.4075|
|Std enthalpy of
|48.3 kJ mol−1|
|Std enthalpy of
|−1982.3–−1975.1 kJ mol−1|
|200.25 J K−1 mol−1|
|Specific heat capacity, C||164.05 J K−1 mol−1|
|GHS signal word||DANGER|
|GHS hazard statements||H225, H301, H314, H331, H350, H411|
|GHS precautionary statements||P210, P261, P273, P280, P301+310|
|EU classification||F T N|
|R-phrases||R45, R11, R23/25, R34, R51/53|
|Flash point||−10 °C|
| (what is: / ?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Unsymmetrical dimethylhydrazine (UDMH) (1,1-Dimethylhydrazine) is a chemical compound with the formula H2NN(CH3)2. It is a colourless liquid, with a sharp, fishy, ammoniacal smell typical for organic amines. Samples turn yellowish on exposure to air and absorb oxygen and carbon dioxide. It mixes completely with water, ethanol, and kerosene. In concentration between 2.5% and 95% in air, its vapors are flammable. It is not sensitive to shock. Symmetrical dimethylhydrazine (CH3NHNH(CH3)) is also known but is not as useful.
- (CH3)2NH + NH2Cl → (CH3)2NNH2 + HCl
Alternatively, acetylhydrazine can be N-methylated using formaldehyde to give the N,N-dimethyl-N'-acetylhydrazine, which can subsequently be hydrolyzed:
- (CH3C(O)NHNH2 + 2 CH2O + 2 H2 → (CH3C(O)NHN(CH3)2 + 2 H2O
- (CH3C(O)NHN(CH3)2 + H2O → (CH3CO2H + H2NN(CH3)2
UDMH is often used in hypergolic rocket fuels as a bipropellant in combination with the oxidizer nitrogen tetroxide and less frequently with IRFNA (red fuming nitric acid) or liquid oxygen. UDMH is a derivative of hydrazine and is sometimes referred to as a hydrazine. As a fuel, it is described in specification MIL-PRF-25604.
UDMH is stable and can be kept loaded in rocket fuel systems for long periods, which makes it appealing for use in many liquid rocket engines, despite its high density and cost. In some applications, such as the OMS in the Space Shuttle or maneuvering engines, monomethylhydrazine is used instead due to its slightly higher specific impulse. In some kerosene-fueled rockets, UDMH functions as a starter fuel to start combustion and warm the rocket engine prior to switching to kerosene. UDMH has higher stability than hydrazine, especially at elevated temperatures, and can be used as its replacement or together in a mixture. UDMH is used in many European, Russian, Indian, and Chinese rocket designs. The Russian Proton, Kosmos-3M, and the Chinese Long March 2F are the most notable users of UDMH. The Titan, GSLV, and Delta rocket families use a mixture of 50% hydrazine and 50% UDMH, called Aerozine 50, in different stages.
Apart from its use as rocket fuel, UDMH is a nitrogen source in metalorganic vapour phase epitaxy thin-film deposition. UDMH is a contaminant, metabolite, and breakdown product of daminozide.
UDMH is toxic, a carcinogen and can explode in the presence of oxidisers. It can be absorbed through skin. During the 1980s there was concern about the levels of UDMH in various foods being a cancer risk, especially for apple juice.
See also 
- "dimazine - Compound Summary". PubChem Compound. USA: National Center for Biotechnology Information. 26 March 2005. Identification. Retrieved 21 February 2012.
- Jean-Pierre Schirmann, Paul Bourdauducq "Hydrazine" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2002. doi:10.1002/14356007.a13_177.
- MIL-PRF-25604 (1997-10-01). "Performance Specification, Propellant, uns-Dimethylhydrazine". Retrieved 2011-05-21.
- Clark, John D. (1972). Ignition! An Informal History of Liquid Rocket Propellants. Rutgers University Press. p. 45. ISBN 0-8135-0725-1.
- UDMH released into the environment can react in air to form dimethylnitrosamine, a persistent carcinogen and groundwater pollutant."Are pesticides posing intolerable risks?". Cornell University.