Ununennium

From Wikipedia, the free encyclopedia
Jump to: navigation, search
ununoctiumununenniumunbinilium
Fr

Uue

Uhe
Appearance
General properties
Name, symbol, number ununennium, Uue, 119
Pronunciation /ˌjuːnəˈnɛniəm/
ew-nə-ne-nee-əm

Listeni/nnˈɛniəm/
oon-oon-e-nee-əm

Element category alkali metals
Group, period, block 18, s
Standard atomic weight unknown
Electron configuration [Uuo] 8s1 (predicted)
Electrons per shell 2, 8, 18, 32, 32, 18, 8, 1 (predicted) (Image)
Physical properties
Atomic properties
Oxidation states 1, 3[1]
(predicted)
· r


Ununennium, also known as eka-francium or element 119, is the temporary name of a hypothetical chemical element in the periodic table that has the temporary symbol Uue and has the atomic number 119. To date, attempted syntheses of this element have been unsuccessful. Since it is below the alkali metals it might have properties similar to those of francium or caesium. Like other alkali metals, it should be extremely reactive with water and air. A predicted oxidation state is +1. Ununennium would be the first element in the eighth period of the periodic table and possibly[citation needed] the seventh alkali metal, though relativistic effects might make it less reactive than francium and caesium.

Contents

[edit] Unsuccessful attempts at synthesis

The synthesis of ununennium was attempted in 1985 by bombarding a target of einsteinium-254 with calcium-48 ions at the superHILAC accelerator at Berkeley, California. No atoms were identified, leading to a limiting yield of 300 nb.[2]

\,^{254}_{99}\mathrm{Es} + \,^{48}_{20}\mathrm{Ca} \to \,^{302}_{119}\mathrm{Uue} ^{*} \to \ 
 \ no\ atoms

It is highly unlikely that this reaction will be useful given the extremely difficult task of making sufficient amounts of 254Es to make a large enough target to increase the sensitivity of the experiment to the required level, due to the rarity of the element, and extreme rarity of the isotope.

[edit] Predicted decay characteristics

The alpha-decay half-lives of 1700 nuclei with 100 ≤ Z ≤ 130 have been calculated in a quantum tunneling model with alpha-decay Q-values from different mass estimates.[3][4][5] The alpha-decay half-lives predicted for 291-307119 are of the order of micro-seconds. The highest value of the alpha-decay half-life predicted in the quantum tunneling model with the mass estimates from a macroscopic-microscopic model is ~485 microseconds for the isotope 294119. For 302119 it is ~163 microseconds.

[edit] Target-projectile combinations leading to Z=119 compound nuclei

The below table contains various combinations of targets and projectiles which could be used to form compound nuclei with an atomic number of 119.

Target Projectile CN Attempt result
254Es 48Ca 302Uue Failure to date

[edit] Theoretical calculations on evaporation cross sections

The below table contains various targets-projectile combinations for which calculations have provided estimates for cross section yields from various neutron evaporation channels. The channel with the highest expected yield is given.

DNS = Di-nuclear system; σ = cross section

Target Projectile CN Channel (product) σ max Model Ref
254Es 48Ca 302Uue 3n (299Uue) 0.5 pb DNS [6]

[edit] See also

[edit] References

  1. ^ Haire, Richard G. (2006). "Transactinides and the future elements". In Morss; Edelstein, Norman M.; Fuger, Jean. The Chemistry of the Actinide and Transactinide Elements (3rd ed.). Dordrecht, The Netherlands: Springer Science+Business Media. p. 1724. ISBN 1-4020-3555-1. 
  2. ^ R. W. Lougheed, J. H. Landrum, E. K. Hulet, J. F. Wild, R. J. Dougan, A. D. Dougan, H. Gäggeler, M. Schädel, K. J. Moody, K. E. Gregorich, and G. T. Seaborg (1985). "Search for superheavy elements using 48Ca + 254Esg reaction". Physical Reviews C 32 (5): 1760–1763. Bibcode 1985PhRvC..32.1760L. doi:10.1103/PhysRevC.32.1760. http://link.aps.org/abstract/PRC/v32/p1760. 
  3. ^ C. Samanta, P. Roy Chowdhury and D.N. Basu (2007). "Predictions of alpha decay half lives of heavy and superheavy elements". Nucl. Phys. A 789: 142–154. arXiv:nucl-th/0703086. Bibcode 2007NuPhA.789..142S. doi:10.1016/j.nuclphysa.2007.04.001. 
  4. ^ P. Roy Chowdhury, C. Samanta, and D. N. Basu (2008). "Search for long lived heaviest nuclei beyond the valley of stability". Phys. Rev. C 77 (4): 044603. Bibcode 2008PhRvC..77d4603C. doi:10.1103/PhysRevC.77.044603. 
  5. ^ P. Roy Chowdhury, C. Samanta, and D. N. Basu (2008). "Nuclear half-lives for α -radioactivity of elements with 100 ≤ Z ≤ 130". At. Data & Nucl. Data Tables 94 (6): 781–806. Bibcode 2008ADNDT..94..781C. doi:10.1016/j.adt.2008.01.003. 
  6. ^ Feng, Z; Jin, G; Li, J; Scheid, W (2009). "Production of heavy and superheavy nuclei in massive fusion reactions". Nuclear Physics A 816: 33. arXiv:0803.1117. Bibcode 2009NuPhA.816...33F. doi:10.1016/j.nuclphysa.2008.11.003. 
Personal tools
Namespaces
Variants
Actions
Navigation
Interaction
Toolbox
Print/export
Languages