Ununpentium

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"Uup" and "UUp" redirect here. For the political party, see Ulster Unionist Party.
"Element 115" redirects here. For fictional and conspiracy references to element 115, see Materials science in science fiction.
Ununpentium   115Uup
General properties
Name, symbol ununpentium, Uup
Pronunciation Listeni/nnˈpɛntiəm/
oon-oon-PEN-tee-əm
Alternative names element 115, eka-bismuth
Ununpentium in the periodic table
Hydrogen (diatomic nonmetal)
Helium (noble gas)
Lithium (alkali metal)
Beryllium (alkaline earth metal)
Boron (metalloid)
Carbon (polyatomic nonmetal)
Nitrogen (diatomic nonmetal)
Oxygen (diatomic nonmetal)
Fluorine (diatomic nonmetal)
Neon (noble gas)
Sodium (alkali metal)
Magnesium (alkaline earth metal)
Aluminium (post-transition metal)
Silicon (metalloid)
Phosphorus (polyatomic nonmetal)
Sulfur (polyatomic nonmetal)
Chlorine (diatomic nonmetal)
Argon (noble gas)
Potassium (alkali metal)
Calcium (alkaline earth metal)
Scandium (transition metal)
Titanium (transition metal)
Vanadium (transition metal)
Chromium (transition metal)
Manganese (transition metal)
Iron (transition metal)
Cobalt (transition metal)
Nickel (transition metal)
Copper (transition metal)
Zinc (transition metal)
Gallium (post-transition metal)
Germanium (metalloid)
Arsenic (metalloid)
Selenium (polyatomic nonmetal)
Bromine (diatomic nonmetal)
Krypton (noble gas)
Rubidium (alkali metal)
Strontium (alkaline earth metal)
Yttrium (transition metal)
Zirconium (transition metal)
Niobium (transition metal)
Molybdenum (transition metal)
Technetium (transition metal)
Ruthenium (transition metal)
Rhodium (transition metal)
Palladium (transition metal)
Silver (transition metal)
Cadmium (transition metal)
Indium (post-transition metal)
Tin (post-transition metal)
Antimony (metalloid)
Tellurium (metalloid)
Iodine (diatomic nonmetal)
Xenon (noble gas)
Caesium (alkali metal)
Barium (alkaline earth metal)
Lanthanum (lanthanide)
Cerium (lanthanide)
Praseodymium (lanthanide)
Neodymium (lanthanide)
Promethium (lanthanide)
Samarium (lanthanide)
Europium (lanthanide)
Gadolinium (lanthanide)
Terbium (lanthanide)
Dysprosium (lanthanide)
Holmium (lanthanide)
Erbium (lanthanide)
Thulium (lanthanide)
Ytterbium (lanthanide)
Lutetium (lanthanide)
Hafnium (transition metal)
Tantalum (transition metal)
Tungsten (transition metal)
Rhenium (transition metal)
Osmium (transition metal)
Iridium (transition metal)
Platinum (transition metal)
Gold (transition metal)
Mercury (transition metal)
Thallium (post-transition metal)
Lead (post-transition metal)
Bismuth (post-transition metal)
Polonium (post-transition metal)
Astatine (metalloid)
Radon (noble gas)
Francium (alkali metal)
Radium (alkaline earth metal)
Actinium (actinide)
Thorium (actinide)
Protactinium (actinide)
Uranium (actinide)
Neptunium (actinide)
Plutonium (actinide)
Americium (actinide)
Curium (actinide)
Berkelium (actinide)
Californium (actinide)
Einsteinium (actinide)
Fermium (actinide)
Mendelevium (actinide)
Nobelium (actinide)
Lawrencium (actinide)
Rutherfordium (transition metal)
Dubnium (transition metal)
Seaborgium (transition metal)
Bohrium (transition metal)
Hassium (transition metal)
Meitnerium (unknown chemical properties)
Darmstadtium (unknown chemical properties)
Roentgenium (unknown chemical properties)
Copernicium (transition metal)
Ununtrium (unknown chemical properties)
Flerovium (unknown chemical properties)
Ununpentium (unknown chemical properties)
Livermorium (unknown chemical properties)
Ununseptium (unknown chemical properties)
Ununoctium (unknown chemical properties)
Bi

Uup

(Uhe)
fleroviumununpentiumlivermorium
Atomic number 115
Standard atomic weight [289]
Element category unknown, but probably a post-transition metal
Group, period, block group 15 (pnictogens), period 7, p-block
Electron configuration [Rn] 5f14 6d10 7s2 7p3 (predicted)[1]
per shell: 2, 8, 18, 32, 32, 18, 5 (predicted)
Physical properties
Phase solid (predicted)[1]
Melting point 670 K ​(400 °C, ​750 °F) (predicted)[1][2]
Boiling point ~1400 K ​(~1100 °C, ​~2000 °F) (predicted)[1]
Density (near r.t.) 13.5 g·cm−3 (predicted)[2] (at 0 °C, 101.325 kPa)
Heat of fusion 5.90–5.98 kJ·mol−1 (extrapolated)[3]
Heat of vaporization 138 kJ·mol−1 (predicted)[2]
Atomic properties
Oxidation states 1, 3(prediction)[1][2]
Ionization energies 1st: 538.4 kJ·mol−1 (predicted)[1]
2nd: 1756.0 kJ·mol−1 (predicted)[2]
3rd: 2653.3 kJ·mol−1 (predicted)[2]
(more)
Atomic radius empirical: 187 pm (predicted)[1][2]
Covalent radius 156–158 pm (extrapolated)[3]
Miscellanea
CAS Number 54085-64-2
History
Naming IUPAC systematic element name
Discovery Joint Institute for Nuclear Research and Lawrence Livermore National Laboratory (2003)
Most stable isotopes
Main article: Isotopes of ununpentium
iso NA half-life DM DE (MeV) DP
290Uup syn 16 ms[4] α 9.95 286Uut
289Uup syn 220 ms[4] α 10.31 285Uut
288Uup syn 87 ms α 10.46 284Uut
287Uup syn 32 ms α 10.59 283Uut
· references

Ununpentium is the temporary name of a synthetic superheavy element in the periodic table that has the temporary symbol Uup and has the atomic number 115.

It is placed as a heavier homologue to bismuth and the heaviest member of group 15 (VA). It was first observed in 2003 and about 50 atoms of ununpentium have been synthesized to date, with about 25 direct decays of the parent element having been detected. Four consecutive isotopes are currently known, 287–290Uup, with 289Uup having the longest measured half-life of ~200 ms.[4] On August 27, 2013, researchers at GSI from Lund University in Sweden reported confirming the existence of the element.[5][6] On September 10, 2013, researchers from the same research group working in Darmstadt, Germany reported synthesis as well. [7]

History[edit]

Discovery profile[edit]

Simulation of an accelerated calcium-48 ion about to collide with an americium-243 target atom.

On February 2, 2004, synthesis of ununpentium was reported in Physical Review C by a team composed of Russian scientists at the Joint Institute for Nuclear Research in Dubna, and American scientists at the Lawrence Livermore National Laboratory.[8][9] The team reported that they bombarded americium-243 with calcium-48 ions to produce four atoms of ununpentium. These atoms, they report, decayed by emission of alpha-particles to ununtrium in approximately 100 milliseconds.

48
20
Ca
+ 243
95
Am
291
115
Uup
*
288
115
Uup
+ 3 n → 284
113
Uut
+ α

The Dubna–Livermore collaboration has strengthened their claim for the discovery of ununpentium by conducting chemical experiments on the decay daughter 268Db. In experiments in June 2004 and December 2005, the dubnium isotope was successfully identified by milking the Db fraction and measuring any SF activities.[10][11] Both the half-life and decay mode were confirmed for the proposed 268Db which lends support to the assignment of Z=115 to the parent nuclei.

Sergei Dmitriev from the Flerov Laboratory of Nuclear Reactions (FLNR) in Dubna, Russia, has formally put forward their claim of discovery of ununpentium to the IUPAC/IUPAP Joint Working Party (JWP).[12] In 2011, the IUPAC evaluated the Dubna–Livermore results and concluded that they did not meet the criteria for discovery.[13]

Naming[edit]

Ununpentium is historically known as eka-bismuth. Ununpentium is a temporary IUPAC systematic element name derived from the digits 115, where "un-" represents Latin unum. "Pent-" represents the Greek word for 5. For more, see systematic element name.

Current and future experiments[edit]

The team at Dubna have also identified the nuclides 287Uup and 289Uup in the 4n and 2n channels, respectively. Ununpentium has also been synthesized as a decay product of ununseptium.

The FLNR also have future plans to study light isotopes of element 115 using the reaction 241Am + 48Ca.[14]

A team of researchers at Lund University announced they had corroborated the 2004 findings in August 2013 by shooting calcium ions into a thin film of americium.[15][16] Researchers at the GSI Helmholtz in Darmstadt, Germany reported the successful synthesis of ununpentium using the same reaction just two weeks later, on September 10, 2013.[7]

Nucleosynthesis[edit]

Target-projectile combinations[edit]

The table below contains various combinations of targets and projectiles which could be used to form compound nuclei with Z=115. Each entry is a combination for which calculations have provided estimates for cross section yields from various neutron evaporation channels. The channel with the highest expected yield is given.

Target Projectile CN Attempt result
208Pb 75As 283Uup Reaction yet to be attempted
232Th 55Mn 287Uup Reaction yet to be attempted
238U 51V 289Uup Failure to date
237Np 50Ti 287Uup Reaction yet to be attempted
244Pu 45Sc 289Uup Reaction yet to be attempted
243Am 48Ca 291Uup[17][18] Successful reaction
241Am 48Ca 289Uup Planned Reaction
248Cm 41K 289Uup Reaction yet to be attempted
249Bk 40Ar 289Uup Reaction yet to be attempted
249Cf 37Cl 286Uup Reaction yet to be attempted

Hot fusion[edit]

Hot fusion reactions are processes that create compound nuclei at high excitation energy (~40–50 MeV, therefore "hot"), leading to a reduced probability of survival from fission. The excited nucleus then decays to the ground state via the emission of 3–5 neutrons. Fusion reactions utilizing 48Ca nuclei usually produce compound nuclei with intermediate excitation energies (~30–35 MeV) and are sometimes referred to as "warm" fusion reactions. This leads, in part, to relatively high yields from these reactions.

238U(51V,xn)289−xUup

There are strong indications that this reaction was performed in late 2004 as part of a uranium(IV) fluoride target test at the GSI. No reports have been published, suggesting that no product atoms were detected, as anticipated by the team.[19]

243Am(48Ca,xn)291−xUup (x=2,3,4)

This reaction was first performed by the team in Dubna in July–August 2003. In two separate runs, they were able to detect 3 atoms of 288Uup and a single atom of 287Uup. The reaction was studied further in June 2004 in an attempt to isolate the descendant 268Db from the 288Uup decay chain. After chemical separation of a +4/+5 fraction, 15 SF decays were measured with a lifetime consistent with 268Db. In order to prove that the decays were from dubnium-268, the team repeated the reaction in August 2005 and separated the +4 and +5 fractions and further separated the +5 fractions into tantalum-like and niobium-like ones. Five SF activities were observed, all occurring in the +5 fractions and none in the tantalum-like fractions, proving that the product was indeed isotopes of dubnium.

In a series of experiments between October 2010 – February 2011, scientists at the FLNR studied this reaction at a range of excitation energies. They were able to detect 21 atoms of 288Uup and one atom of 289Uup, from the 2n exit channel. This latter result was used to support the synthesis of ununseptium. The 3n excitation function was completed with a maximum at ~8 pb. The data was consistent with that found in the first experiments in 2003.

Isotopes and nuclear properties[edit]

Chronology of isotope discovery
Isotope Year discovered Discovery reaction
287Uup 2003 243Am(48Ca,4n)
288Uup 2003 243Am(48Ca,3n)
289Uup 2009 249Bk(48Ca,4n)[4]
290Uup 2009 249Bk(48Ca,3n)[4]

Chemical properties[edit]

Extrapolated chemical properties[edit]

Oxidation states[edit]

Ununpentium is projected to be the third member of the 7p series of chemical elements and the heaviest member of group 15 (VA) in the Periodic Table, below bismuth. In this group, each member is known to portray the group oxidation state of +V but with differing stability. For nitrogen, the +V state is very difficult to achieve due to the lack of low-lying d-orbitals and the inability of the small nitrogen atom to accommodate five ligands. The +V state is well represented for phosphorus, arsenic, and antimony. However, for bismuth it is rare due to the reluctance of the 6s2 electrons to participate in bonding. This effect is known as the "inert pair effect" and is commonly linked to relativistic stabilisation of the 6s-orbitals. It is expected that ununpentium will continue this trend and portray only +III and +I oxidation states. Nitrogen(I) and bismuth(I) are known but rare and ununpentium(I) is likely to show some unique properties.[20] Because of spin-orbit coupling, flerovium may display closed-shell or noble gas-like properties; if this is the case, ununpentium will likely be monovalent as a result, since the cation Uup+ will have the same electron configuration as flerovium.

Chemistry[edit]

Ununpentium should display eka-bismuth chemical properties and should therefore form a sesquioxide, Uup2O3, and analogous chalcogenides, Uup2S3, Uup2Se3 and Uup2Te3. It should also form trihydrides and trihalides, i.e. UupH3, UupF3, UupCl3, UupBr3 and UupI3. If the +V state is accessible, it is likely that it is only possible in the fluoride, UupF5.[21][not in citation given]

Stability[edit]

Main article: Island of stability

All the reported above isotopes of element 115, obtained by nuclear collisions of lighter nuclei, are severely neutron-deficient, because the proportion of neutrons to protons needed for maximum stability increases with atomic number. The most stable isotope will probably be 299Uup, with 184 neutrons, a known "magic" closed-shell number conferring exceptional stability, making it (with one further proton outside the "magic number" of 114 protons) both the chemical and the nuclear homolog of 209Bi; but the technology required to add the required neutrons presently does not exist. This is because no known combination of target and projectile can result in the required neutrons. It has been suggested[by whom?] that such a neutron-rich isotope could be formed by quasifission (fusion followed by fission) of a massive nucleus, multi-nucleon transfer reactions in collisions of actinide nuclei, or by the alpha decay of a massive nucleus (although this would depend on the stability of the parent nuclei towards spontaneous fission).

References[edit]

  1. ^ a b c d e f g Haire, Richard G. (2006). "Transactinides and the future elements". In Morss; Edelstein, Norman M.; Fuger, Jean. The Chemistry of the Actinide and Transactinide Elements (3rd ed.). Dordrecht, The Netherlands: Springer Science+Business Media. ISBN 1-4020-3555-1. 
  2. ^ a b c d e f g Fricke, Burkhard (1975). "Superheavy elements: a prediction of their chemical and physical properties". Recent Impact of Physics on Inorganic Chemistry 21: 89–144. doi:10.1007/BFb0116498. Retrieved 4 October 2013. 
  3. ^ a b Bonchev, Danail; Kamenska, Verginia (1981). "Predicting the Properties of the 113–120 Transactinide Elements". J. Phys. Chem. 85: 1177–1186. doi:10.1021/j150609a021. 
  4. ^ a b c d e Oganessian, Y. T.; Abdullin, F. S.; Bailey, P. D. et al. (2010). "Synthesis of a New Element with Atomic Number Z=117". Physical Review Letters 104 (14): 142502. Bibcode:2010PhRvL.104n2502O. doi:10.1103/PhysRevLett.104.142502. PMID 20481935.  edit
  5. ^ "Existence of new element confirmed". Lund University. 27 August 2013. Retrieved 27 August 2013. 
  6. ^ Staff (27 August 2013). "Scientists say existence of new element confirmed". Associated Press. Retrieved 27 August 2013. 
  7. ^ a b "Phys. Rev. Lett. 111, 112502 (2013): Spectroscopy of Element 115 Decay Chains". Prl.aps.org. Retrieved 2013-09-28. 
  8. ^ Oganessian, Yu. Ts.; Utyonkoy, V. K.; Lobanov, Yu. V. et al. (2004). "Experiments on the synthesis of element 115 in the reaction 243Am(48Ca,xn)291−x115". Physical Review C 69 (2): 021601. Bibcode:2004PhRvC..69b1601O. doi:10.1103/PhysRevC.69.021601. 
  9. ^ Oganessian et al. (2003). "Experiments on the synthesis of element 115 in the reaction 243Am(48Ca,xn)291−x115". JINR preprints. 
  10. ^ Dmitriev, S. N. (2005). "Results of the Experiment for Chemical Identification of Db as a Decay Product of Element 115". In Penionzhkevich, Yu. E.; Cherepanov, E. A. International Symposium on Exotic Nuclei: Peterhof, Russia, July 5-12, 2004. Hackensack: World Scientific. pp. 285–294. Bibcode:2005exnu.conf..285D. doi:10.1142/9789812701749_0040. ISBN 9789812701749. OCLC 77501503. 
  11. ^ Oganessian, Yu. Ts.; Utyonkov, V.; Dmitriev, S.; Lobanov, Yu.; Itkis, M.; Polyakov, A.; Tsyganov, Yu.; Mezentsev, A. et al. (2005). "Synthesis of elements 115 and 113 in the reaction 243Am+48Ca". Physical Review C 72 (3): 034611. Bibcode:2005PhRvC..72c4611O. doi:10.1103/PhysRevC.72.034611. 
  12. ^ "Project: Priority claims for the discovery of elements with atomic number greater than 111". IUPAC. Retrieved 2009-07-07. 
  13. ^ Barber, Robert C.; Karol, Paul J.; Nakahara, Hiromichi; Vardaci, Emanuele; Vogt, Erich W. (2011). "Discovery of the elements with atomic numbers greater than or equal to 113 (IUPAC Technical Report)". Pure and Applied Chemistry 83 (7): 1. doi:10.1351/PAC-REP-10-05-01. 
  14. ^ "Study of heavy and superheavy nuclei (see experiment 1.5)". Flerov Laboratory of Nuclear Reactions. 
  15. ^ "EXISTENCE OF NEW ELEMENT CONFIRMED". Lund University. 27 August 2013. Retrieved 27 August 2013. 
  16. ^ "Spectroscopy of element 115 decay chains (Accepted for publication on Physical Review Letters on 9 August 2013)". Retrieved 2 September 2013. 
  17. ^ Zagrebaev, V (2004). "Fusion-fission dynamics of super-heavy element formation and decay". Nuclear Physics A 734: 164. Bibcode:2004NuPhA.734..164Z. doi:10.1016/j.nuclphysa.2004.01.025. 
  18. ^ Feng, Z; Jin, G; Li, J; Scheid, W (2009). "Production of heavy and superheavy nuclei in massive fusion reactions". Nuclear Physics A 816: 33. arXiv:0803.1117. Bibcode:2009NuPhA.816...33F. doi:10.1016/j.nuclphysa.2008.11.003. 
  19. ^ "List of experiments 2000–2006". Univerzita Komenského v Bratislave. Archived from the original on 2007-07-23. 
  20. ^ Keller, O. L., Jr.; C. W. Nestor, Jr. (1974). "Predicted properties of the superheavy elements. III. Element 115, Eka-bismuth". Journal of Physical Chemistry 78 (19): 1945. doi:10.1021/j100612a015. 
  21. ^ WebElements – Bismuth Compounds

External links[edit]