Pitchblende from Niederschlema-Alberoda deposit, Germany
|Uranium dioxide or uranium(IV) oxide (UO2)|
|Crystal symmetry||Isometric, hexoctahedral
H-M symbol: (4/m32/m)
Space group: F m3m
|Unit cell||a = 5.4682 Å; Z = 4|
|Color||Steel-black to velvet-black, brownish black, pale gray to pale green; in transmitted light, pale green, pale yellow to deep brown|
|Crystal habit||Massive, botryoidal, granular. Octahedral crystals uncommon.|
|Fracture||Conchoidal to uneven|
|Mohs scale hardness||5–6|
|Luster||Submetallic, greasy, dull|
|Streak||Brownish black, gray, olive-green|
|Diaphaneity||Opaque; transparent in thin fragments|
|Specific gravity||10.63–10.95; decreases on oxidation|
|Other characteristics||Radioactivity: 70 Bq/g to 150 kBq/g|
Uraninite is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2, but due to oxidation the mineral typically contains variable U3O8. Additionally due to the decay of the uranium it contains oxides of lead and trace amounts of helium. It may also contain thorium, and rare earth elements. It is most commonly known as pitchblende (from pitch, because of its black color, and blende, a term used by German miners to denote minerals whose density suggested metal content, but whose exploitation was, at the time they were named, either impossible or not economically feasible). The mineral has been known at least since the 15th century from silver mines in the Ore Mountains, on the German/Czech border. The type locality is the town of Jáchymov, on the Czech side of the mountains, where F.E.Brückmann described the mineral in 1772. Pitchblende from the Johanngeorgenstadt deposit in Germany was used by M. Klaproth in 1789 to discover the element uranium.
All uraninite minerals contain a small amount of radium as a radioactive decay product of uranium. Uraninite also always contains small amounts of the lead isotopes 206Pb and 207Pb, the end products of the decay series of the uranium isotopes 238U and 235U respectively. Small amounts of helium are also present in uraninite as a result of alpha decay. Helium was first found on Earth in uraninite after having been discovered spectroscopically in the Sun's atmosphere. The extremely rare elements technetium and promethium can be found in uraninite in very small quantities (about 200 pg/kg and 4 fg/kg respectively), produced by the spontaneous fission of uranium-238.
Uraninite is a major ore of uranium. Some of the highest grade uranium ores in the world were found in the Shinkolobwe mine in the Democratic Republic of the Congo (the initial source for the Manhattan Project) and in the Athabasca Basin in northern Saskatchewan, Canada. Another important source of pitchblende is at Great Bear Lake in the Northwest Territories of Canada, where it is found in large quantities associated with silver. It also occurs in Australia, the Czech Republic, Germany, England, and South Africa. In the United States it can be found in the states of Arizona, Colorado, Connecticut, Maine, New Hampshire, New Mexico, North Carolina and Wyoming. The geologist Charles Steen made a fortune on the production of Uraninite in his Mi Vida mine in Moab, Utah.
Uranium ore is generally processed close to the mine into yellowcake, which is an intermediate step in the processing of uranium.
- Klein, Cornelis and Cornelius S. Hurlbut, Jr., Manual of Mineralogy, Wiley, 1985, 20th ed. pp. 307–308 ISBN 0-471-80580-7
- Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W. and Nichols, Monte C. (ed.). "Uraninite" (PDF). Handbook of Mineralogy. III (Halides, Hydroxides, Oxides). Chantilly, VA, US: Mineralogical Society of America. ISBN 0-9622097-2-4. Retrieved December 5, 2011.
- Uraninite. Mindat.org
- Uraninite. Webmineral.com
- Veselovsky, F., Ondrus, P., Gabsová, A., Hlousek, J., Vlasimsky, P., Chernyshew, I.V. (2003). "Who was who in Jáchymov mineralogy II". Journal of the Czech Geological Society (3–4 ed.) 48: 93–205.
- Schüttmann, W. (1998). "Das Erzgebirge und sein Uran". RADIZ-Information 16: 13–34.
Media related to Uraninite at Wikimedia Commons