Water softening is the removal of calcium, magnesium, and certain other metal cations in hard water. The resulting soft water is more compatible with soap and extends the lifetime of plumbing. Water softening is usually achieved using lime softening or ion-exchange resins.
- 1 Problems with hard water
- 2 Water softening methods
- 3 Unsubstatiated claims for non-chemical devices (magnetic or catalytic)
- 4 Health effects
- 5 See also
- 6 References
- 7 External links
Problems with hard water
The presence of certain metal ions like calcium and magnesium principally as bicarbonates, chlorides, and sulfates in water causes a variety of problems. These ions interfere with the action of soaps. They also lead to buildup of limescale, which can foul plumbing, and promote galvanic corrosion. In industrial scale water softening plants, the effluent flow from the re-generation process can precipitate scale that can interfere with sewage systems.
The slippery feeling experienced when using soap with soft water occurs because soaps tend to bind to fats in the surface layers of skin, making soap molecules difficult to remove by simple dilution. In contrast, in hard-water areas the rinse water contains calcium or magnesium ions which form insoluble salts, effectively removing the residual soap from the skin but potentially leaving a coating of insoluble stearates on tub and shower surfaces, commonly called soap scum.
Which of these effects is considered more or less desirable varies from person to person, and those who dislike the sliminess and difficulty of washing off soap caused by soft water may harden the water by adding chemicals such as baking soda, calcium chloride or magnesium sulphate.
Water softening methods
The most common means for removing water hardness rely on ion-exchange polymers or reverse osmosis. Other approaches include precipitation methods and sequestration by the addition of chelating agents. Devices which supposedly use magnetism or electrolysis as a water softening technique claim to inhibit scale buildup without actually removing hardness ions from the water. Such devices have been marketed to consumers since the early 20th century, but are fraudulent.
Ion-exchange resin devices
Conventional water-softening appliances intended for household use depend on an ion-exchange resin in which "hardness ions" - mainly Ca2+ and Mg2+ - are exchanged for sodium ions. As described by NSF/ANSI Standard 44, ion exchange devices reduce the hardness by replacing magnesium and calcium (Mg2+ and Ca2+) with sodium or potassium ions (Na+ and K+)."
Types of ion exchange materials
Ion exchange resins are organic polymers containing anionic functional groups to which the dications (Ca++) bind more strongly than monocations (Na+). Inorganic materials called zeolites also exhibit ion-exchange properties. These minerals are widely used in laundry detergents. Resins are also available to remove carbonate, bi-carbonate and sulphate ions which are absorbed and hydroxide ions released from the resin.
Regeneration of ion exchange resins
When all the available Na+ ions have been replaced with calcium or magnesium ions, the resin must be re-charged by eluting the Ca2+ and Mg2+ ions using a solution of sodium chloride or sodium hydroxide depending on the type of resin used. For anionic resins, regeneration typically uses a solution of sodium hydroxide (lye) or potassium hydroxide. The waste waters eluted from the ion exchange column containing the unwanted calcium and magnesium salts are typically discharged to the sewage system.
Lime softening is when lime is added to hard water to make it softer.
Chelators are used in chemical analysis, as water softeners, and are ingredients in many commercial products such as shampoos and food preservatives. Citric acid is used to soften water in soaps and laundry detergents. A commonly used synthetic chelator is ethylenediaminetetraacetic acid (EDTA).
Distillation and rain water
Since Ca2+ and Mg2+ exist as nonvolatile salts, they can be removed by distilling the water. Distillation is too expensive in most cases. Rainwater is soft because it is naturally distilled during the water cycle of evaporation, condensation and precipitation.
Reverse osmosis (RO) takes advantage of hydrostatic pressure gradients across a special membrane. The membrane has pores large enough to admit water molecules for passage; hardness ions such as Ca2+ and Mg2+ remain behind and are flushed away by excess water into a drain. The resulting soft water supply is free of hardness ions without any other ions being added. Membranes have a limited capacity, requiring regular replacement.
Unsubstatiated claims for non-chemical devices (magnetic or catalytic)
Some manufacturers claim their devices instead of exchanging ions, the minerals in the water are crystallized so that they do not bind to surfaces. The main benefit to the user is the elimination of the need to deal with adding salt to the system. To date there are no independent confirmations of these claims.
Effects of sodium
According to the Mayo Clinic, "An 8-ounce (237-milliliter) glass of softened water generally contains less than 12.5 milligrams of sodium, which is well within the Food and Drug Administration's definition of 'very low sodium.' " Of course, the exact amount of sodium present in soft water will depend upon how much hardness is being removed by the softener (harder water equals more sodium ions being exchanged for the hardness ions) as well as the levels of naturally occurring sodium that is present in many groundwater sources.
The CDC recommends limiting daily total sodium intake to 2,300 mg per day, though the average American consumes 3,500 mg per day. Because the amount of sodium present in drinking water—even after softening—does not represent a significant percentage of a person's daily sodium intake, the EPA considers sodium in drinking water to be unlikely to cause adverse health effects.
For those who are on sodium-restricted diets, the use of a reverse osmosis system for drinking water and cooking water will remove sodium along with any other impurities which may be present. Potassium chloride can also be used as a regenerant instead of sodium chloride, although it is more costly. For people with impaired kidney function, however, elevated potassium levels can lead to complications such as cardiac arrhythmia.
- The Editors of Encyclopædia Britannica. "Hard water". Encyclopædia Britannica. Retrieved 4 March 2015.
- Stephen Lower (July 2007). "Hard water and water softening". Retrieved 2007-10-08.
- Mathew. "Types of Water Softener". Retrieved 4 March 2015.
- Elmhurst College - Cleansing action of soap.
- "Soft Water V. Hard Water In Plumbing, Pools And Hot Tubs Spas". Retrieved 2013-06-23.
- "Magnetic water treatment and pseudoscience". Lower, S. Faculty member (rtd.) Dept of Chemistry, Simon Fraser University Burnaby / Vancouver, Canada. Retrieved 2013-07-02.
- Filtration Facts, September 2005, U.S. Environmental Protection Administration, pp. 6-7. Accessed 6 January 2013.
- New Hampshire Dept of Environmental Services-Ion Exchange Treatment of Drinking Water
- Bartram, edited by Jamie; Ballance, Richard (1996). Water quality monitoring : a practical guide to the design and implementation of freshwater quality studies and monitoring programmes (1st ed. ed.). London: E & FN Spon. ISBN 0419223207.
- "Catalytic water treatment". Retrieved 4 March 2015.
- "Magnets and Magnetic Water Softeners Do Not Work". APS TechNotes. Retrieved 4 March 2015.
- "Magnetic water treatment and pseudoscience". chem1.com. Retrieved 4 March 2015.
- "Common Water Quality Problems And Their Treatment" (PDF). Retrieved 2013-06-23.