ZND detonation model
The ZND detonation model is a one-dimensional model for the process of detonation of an explosive. It was proposed during World War II independently by Y. B. Zel'dovich, John von Neumann, and Werner Döring, hence the name.
This model admits finite-rate chemical reactions and thus the process of detonation consists of the following stages. First, an infinitely thin shock wave compresses the explosive to a high pressure called the von Neumann spike. At the von Neumann spike point the explosive still remains unreacted. The spike marks the onset of the zone of exothermic chemical reaction, which finishes at the Chapman-Jouguet state. After that, the detonation products expand backward.
In the reference frame in which the shock is stationary, the flow following the shock is subsonic. Because of this, energy release behind the shock is able to be transported acoustically to the shock for its support. For a self-propagating detonation, the shock relaxes to a speed given by the Chapman–Jouguet condition, which induces the material at the end of the reaction zone to have a locally sonic speed in the reference frame in which the shock is stationary. In effect, all of the chemical energy is harnessed to propagate the shock wave forward.
- Zel’dovich, Ya.B. (1940). К теории распространения детонации в газообразных системах [On the theory of the propagation of detonations on gaseous system]. Zh. Eksp. Teor. Fiz. (in Russian) 10: 542–568.
- von Neumann, J. (1963). "Theory of detonation waves. Progress Report to the National Defense Research Committee Div. B, OSRD-549 (April 1, 1942. PB 31090)". In Taub, A. H. John von Neumann: Collected Works, 1903-1957 6. New York: Pergamon Press. ISBN 978-0-08-009566-0.
- Döring, W. (1943). "Über Detonationsvorgang in Gasen" [On detonation processes in gases]. Annalen der Physik (in German) 43 (6–7): 421–436. Bibcode:1943AnP...435..421D. doi:10.1002/andp.19434350605. ISSN 0003-4916.