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Traditional dry cure hams may use only salt as the curative agent, such as with San Daniele or Parma hams, although this is comparatively rare.<ref name=meat>{{cite web|url=http://www.meatsandsausages.com/sausage-making/curing/methods|title=Curing Methods|publisher=Meat and Sausages.com}}</ref> This process involves cleaning the raw meat, covering it in salt (for about two months for Parma ham) whilst it is gradually pressed - draining all the blood. It is then washed and hung in a dark, temperature regulated place until dry. It is then hung to air for another period of time.
Traditional dry cure hams may use only salt as the curative agent, such as with San Daniele or Parma hams, although this is comparatively rare.<ref name=meat>{{cite web|url=http://www.meatsandsausages.com/sausage-making/curing/methods|title=Curing Methods|publisher=Meat and Sausages.com}}</ref> This process involves cleaning the raw meat, covering it in salt (for about two months for Parma ham) whilst it is gradually pressed - draining all the blood. It is then washed and hung in a dark, temperature regulated place until dry. It is then hung to air for another period of time.


The duration of the curing process varies by the type of ham, with Serrano ham curing in 9-12 months, Parma hams taking more than 12 months, and Iberian ham taking up to 2 years to reach the desired flavour characteristics.<ref>{{cite journal|journal=European Food Research and Technology|year=2001|volume=213|issue=2|pages=83-87|title=Dipeptidyl peptidase activities along the processing of Serrano dry-cured ham|first1=Miguel Angel|last1=Sentandreu|first2=Fidel|last2=Toldrá|url=http://link.springer.com/article/10.1007/s002170100355#page-1}}</ref>
Most modern dry cure hams also use [[nitrite]]s (either [[sodium nitrite|sodium]] or [[potassium nitrate|potassium]]), which are added along with the salt, although following a similar methodology. The nitrites deliver a distinctive pink or red tinge to the meat, as well as imparting flavour.

Most modern dry cure hams also use [[nitrite]]s (either [[sodium nitrite|sodium]] or [[potassium nitrate|potassium]]), which are added along with the salt, although following a similar methodology. The nitrites deliver a distinctive pink or red tinge to the meat, as well as imparting flavour. The amount and mixture of salt and nitrites used has an impact on the shrinkage of the meat, with increased salt volume reducing shrinkage.<ref>{{cite journal|journal=Journal of Food Science|title=Effect of salt, phosphates and other curing ingredients on shrinkage of lean pork meat and quality of smoked processed ham|first1=Eugen|last1=Wierbicki|first2=John J|last2=Howker|year=1976|volume=41|issue=5|pages=1116-1121|url=http://onlinelibrary.wiley.com/doi/10.1111/j.1365-2621.1976.tb14399.x/abstract?deniedAccessCustomisedMessage=&userIsAuthenticated=false}}</ref>


[[Sodium nitrite]] is used for the because it prevents bacterial growth and, in a reaction with the meat's [[myoglobin]], gives the product a desirable dark red color. Because of the toxicity of nitrite (the lethal dose of nitrite for humans is about 22&nbsp;mg per kg body weight), some areas specify a maximum allowable content of nitrite in the final product. Under certain conditions, especially during cooking, nitrites in meat can react with degradation products of [[amino acid]]s, forming [[nitrosamine]]s, which are known [[carcinogen]]s.<ref>{{cite PMID|16865769}}</ref>
[[Sodium nitrite]] is used for the because it prevents bacterial growth and, in a reaction with the meat's [[myoglobin]], gives the product a desirable dark red color. Because of the toxicity of nitrite (the lethal dose of nitrite for humans is about 22&nbsp;mg per kg body weight), some areas specify a maximum allowable content of nitrite in the final product. Under certain conditions, especially during cooking, nitrites in meat can react with degradation products of [[amino acid]]s, forming [[nitrosamine]]s, which are known [[carcinogen]]s.<ref>{{cite PMID|16865769}}</ref>

The dry curing of ham involves a number of biochemical reactions caused by [[enzyme]]s. The enzymes involved are [[proteinase]]s ([[cathepsin]]s - [[Cathepsin B|B]], [[Cathepsin D|D]], [[Cathepsin H|H]], and [[Cathepsin L1|L]], [[calpain]]s) and [[exopeptidase]]s ([[peptidase]] and [[aminopeptidase]].<ref name=toldra>{{cite journal|last1=Toldrá|first1=Fidel|last2=Flores|first2=Mónica|title=The Role of Muscle Proteases and Lipases in Flavor Development During the Processing of Dry-Cured Ham|journal=Critical Reviews in Food SCience and Nutrition|year=1998|volume=38|issue=4|pages=351-352|url=http://www.tandfonline.com/doi/abs/10.1080/10408699891274237#.UlauaVNr2BI}}</ref>

The enzymes cause an intense [[proteolysis]] in the muscle tissue, which creates large numbers of small [[peptide]]s and free [[amino acid]]s, whilst the muscle and [[adipose]] tissue lipids undergo [[lipolysis]] and create free fatty acids.<ref name=toldra/>

The salt in the curing process acts as a strong inhibitor of [[proteolysis|proteolytic activity]], and phosphates also have an effect on reducing this activity.<ref>{{cite journal|journal=Meat Science|title=Effect of curing salt and phosphate on the activity of porcine muscle proteases|year=1989|volume=24|issue=4|pages=241-249|url=http://www.sciencedirect.com/science/article/pii/0309174089900429|last1=Sárraga|first1=Carmen|last2=Gil|first2=Marta|first3=Jacint|last3=Arnau|first4=Josep M|last4=Monfort}}</ref>

The properties of the raw meat have a major impact on the impact of the enzymes, with factors including age of the animal and breeding impacting the process, as well as weight of the pig.<ref>{{cite journal|first1=Carmen|last1=Sárraga|first2=Marta|last2=Gil|first3=José Antonio|last3=García-Regueiro|journal=Journal of the Science of Food and Agriculture|title=Comparison of calpain and cathepsin (B,L and D) activities during dry-cured ham processing from heavy and large white pigs|volume=62|issue=1|pages=71-75|date=Sept 2006|doi=10.1002}}</ref> During the process itself, conditions such as temperature, time, water activity, [[redox potential]] and salt content all have an impact.<ref name=toldra/>


===Wet curing===
===Wet curing===

Revision as of 14:14, 10 October 2013

Typical slice of ham
Whole ham

Ham is a processed pork foodstuff,[1] which undergoes preservation through curing, smoking, or salting. Ham was traditionally made only from the hind leg of swine, and referred to that specific cut of pork,[2] but in modern usage 'ham' may not be a single cut of meat, and is often created through a process of re-forming.

The precise nature of meat termed 'ham' is controlled, often by statute, in a number of areas, including the United States and European Union, meaning that only products meeting a certain set of criteria can be called ham. In addition, there a numerous ham products which have specific geographical naming protection, such as Prosciutto di Parma in Europe, and Smithfield ham in the US.

Ham is also often colloquially used to mean any sliced (or re-formed) preserved meat, regardless of the animal it is made from, although this is usually qualified with the species of animal as with turkey ham.

Definition

Ham has a number of definitions, and its meaning has evolved over time. Ham was originally the cut of pork deriving from the hind legs of swine, which was then often preserved through processes such as curing, smoking, or salting. Cooked leg of pork is called gammon.

Because of the preservation process, ham is a compound foodstuff or ingredient, being made up of the original meat, as well as the remnants of the preserving agent(s), such as salt, but it is still recognised as a food in its own right.[3]

In many countries the term is now protected by statute, with a specific definition. For instance, in the United States, the Code of Federal Regulations (CFR) says that "the word “ham,” without any prefix indicating the species of animal from which derived, shall be used in labeling only in connection with the hind legs of swine".[4]

In addition to the main categories, some processing choices can affect legal labeling. For instance, in the United State, a 'smoked' ham must have been smoked by hanging over burning wood chips in a smokehouse or an atomized spray of liquid smoke such that the product appearance is equivalent; a "hickory-smoked" ham must have been smoked using only hickory. However, injecting "smoke flavor" is not legal grounds for claiming the ham was "smoked"; these are labeled "smoke flavor added". Hams can only be labelled "honey-cured" if honey was at least 50% of the sweetener used, is at least 3% of the formula, and has a discernible effect on flavor. So-called "lean" and "extra lean" hams must adhere to maximum levels of fat and cholesterol per 100 grams of product.

Ham which is re-formed from smaller pieces in to a larger block also has to be labelled in many jursidictions.

Etymology

The word "ham" is derived from the Old English ham or hom meaning the hollow or bend of the knee, from a Germanic base where it meant 'crooked'. It gained the meaning of the leg of an animal around the 15th century.[5]

Method

There are several methods for producing ham from raw meat, and this is undertaken to preserve and flavour the meat. Most ham is safe to eat following preservation, without the need for cooking.

Dry curing

Traditional dry cure hams may use only salt as the curative agent, such as with San Daniele or Parma hams, although this is comparatively rare.[6] This process involves cleaning the raw meat, covering it in salt (for about two months for Parma ham) whilst it is gradually pressed - draining all the blood. It is then washed and hung in a dark, temperature regulated place until dry. It is then hung to air for another period of time.

The duration of the curing process varies by the type of ham, with Serrano ham curing in 9-12 months, Parma hams taking more than 12 months, and Iberian ham taking up to 2 years to reach the desired flavour characteristics.[7]

Most modern dry cure hams also use nitrites (either sodium or potassium), which are added along with the salt, although following a similar methodology. The nitrites deliver a distinctive pink or red tinge to the meat, as well as imparting flavour. The amount and mixture of salt and nitrites used has an impact on the shrinkage of the meat, with increased salt volume reducing shrinkage.[8]

Sodium nitrite is used for the because it prevents bacterial growth and, in a reaction with the meat's myoglobin, gives the product a desirable dark red color. Because of the toxicity of nitrite (the lethal dose of nitrite for humans is about 22 mg per kg body weight), some areas specify a maximum allowable content of nitrite in the final product. Under certain conditions, especially during cooking, nitrites in meat can react with degradation products of amino acids, forming nitrosamines, which are known carcinogens.[9]

The dry curing of ham involves a number of biochemical reactions caused by enzymes. The enzymes involved are proteinases (cathepsins - B, D, H, and L, calpains) and exopeptidases (peptidase and aminopeptidase.[10]

The enzymes cause an intense proteolysis in the muscle tissue, which creates large numbers of small peptides and free amino acids, whilst the muscle and adipose tissue lipids undergo lipolysis and create free fatty acids.[10]

The salt in the curing process acts as a strong inhibitor of proteolytic activity, and phosphates also have an effect on reducing this activity.[11]

The properties of the raw meat have a major impact on the impact of the enzymes, with factors including age of the animal and breeding impacting the process, as well as weight of the pig.[12] During the process itself, conditions such as temperature, time, water activity, redox potential and salt content all have an impact.[10]

Wet curing

Wet curing involves the immersion of the meat in a brine, sometimes with other ingredients such as sugar also added for flavour. Meat is submerged in the brine for around 3-14 days, during which time the meat needs to be kept submerged, and the brine mixture agitated periodically to prevent separation of the ingredients.[6]

Wet curing also has the effect of increasing volume and weight of the finished product, by about 4%.

The wet curing process can also be replicated by using mechanical pumping using needles and curing solution. This can be quicker, increase the weight of the finished product by more than immersion wet curing, and ensure a more even distribution of salt through the meat. This process is quicker than traditional wet cure, normally being completed between a few days and a few weeks.[13]

Smoking

Ham can also be preserved through the smoking method, where it is placed in a smokehouse (or equivalent) to be cured by the action of smoke.

The main flavor compounds of smoked ham are guaiacol, and its 4-, 5-, and 6-methyl derivatives as well as 2,6-dimethylphenol. These compounds are produced by thermal breakdown (i.e., combustion) of lignin, a major constituent of wood used in the smokehouse.[14]

Protected designations

Hams aging in an atmospherically controlled storage room in Mazerolles, Béarn
Spanish Jamón de Guijuelo, a protected designation ham

There are a wide number of hams worldwide which have some level of protection of their unique characteristics, usually relating to their method of preservation and/or location of production or processing. Dependant on jursidiction, rules may prevent any other product being sold with the particular appelation, such as through the European protected geographical indication.

Uses

Ham is typically used in its sliced form, often as a filling for sandwiches and similar foods, such as in the ham sandwich and ham and cheese sandwich. Other variations include toasted sandwiches such as the croque-monsieur.

It is also used chopped in a wide range of dishes, such as omelettes.

Whole pork leg is also served cooked as gammon.

See also

References

  1. ^ "Red and processed meats and cancer prevention". World Cancer Research Fund.
  2. ^ "Bacon: Bacon and Ham Curing" in Chambers's Encyclopædia. London: George Newnes, 1961, Vol. 2, p. 39.
  3. ^ "Labelling and Composition of Meat Products: Guidance Notes" (PDF). Food Standards Agency Scotland. p. 31.
  4. ^ "9 CFR 317.8 - False or misleading labeling or practices generally; specific prohibitions and requirements for labels and containers". Legal Information Institute.
  5. ^ Brown, Lesley, ed. (2007). Shorter Oxford English Dictionary. Vol. II (Sixth ed.). Oxford: Oxford University press. p. 3611.
  6. ^ a b "Curing Methods". Meat and Sausages.com.
  7. ^ Sentandreu, Miguel Angel; Toldrá, Fidel (2001). "Dipeptidyl peptidase activities along the processing of Serrano dry-cured ham". European Food Research and Technology. 213 (2): 83–87.
  8. ^ Wierbicki, Eugen; Howker, John J (1976). "Effect of salt, phosphates and other curing ingredients on shrinkage of lean pork meat and quality of smoked processed ham". Journal of Food Science. 41 (5): 1116–1121.
  9. ^ Template:Cite PMID
  10. ^ a b c Toldrá, Fidel; Flores, Mónica (1998). "The Role of Muscle Proteases and Lipases in Flavor Development During the Processing of Dry-Cured Ham". Critical Reviews in Food SCience and Nutrition. 38 (4): 351–352.
  11. ^ Sárraga, Carmen; Gil, Marta; Arnau, Jacint; Monfort, Josep M (1989). "Effect of curing salt and phosphate on the activity of porcine muscle proteases". Meat Science. 24 (4): 241–249.
  12. ^ Sárraga, Carmen; Gil, Marta; García-Regueiro, José Antonio (Sept 2006). "Comparison of calpain and cathepsin (B,L and D) activities during dry-cured ham processing from heavy and large white pigs". Journal of the Science of Food and Agriculture. 62 (1): 71–75. doi:10.1002. {{cite journal}}: Check |doi= value (help); Check date values in: |date= (help)
  13. ^ Deibel, RH; Niven, CF (September 1958). "The occurence and significance of a motile microorganism of the Genus Lactobacillus in ham curing brines". Applied Microbiology. 5 (5): 323–327.
  14. ^ Wittkowski, Reiner; Ruther, Joachim; Drinda, Heike; Rafiei-Taghanaki, Foroozan "Formation of smoke flavor compounds by thermal lignin degradation" ACS Symposium Series (Flavor Precursors), 1992, volume 490, pp 232–243. ISBN 9780841222229
  15. ^ Regulator Agency of the Serrano Ham D.O., Jamón de Teruel.com
  16. ^ "Campaña informativa sobre los Productos del Ibérico del Ministerio de Agricultura de España". Web.archive.org. 22 May 2008. Archived from the original on 22 May 2008. Retrieved 8 September 2013.
  17. ^ A colour atlas of food quality control, section "Brine curing", pages 65 and 66. Jane P. Sutherland, A. H. Varnam
  18. ^ "Food Legends of the United Kingdom: York Ham". Information Britain. Retrieved 11 November 2009.
  19. ^ Lori Alden. "Cook's Thesaurus: Ham". Food Subs. Retrieved 5 October 2008.