Wikipedia:WikiProject Chemicals/Chembox validation/VerifiedDataSandbox and Thallium(III) hydroxide: Difference between pages

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-{{ambox | text = This page contains a copy of the infobox ({{tl|chembox}}) taken from revid [{{fullurl:Thallium(III)_hydroxide|oldid=454858443}} 454858443] of page [[Thallium(III)_hydroxide]] with values updated to verified values.}}
 {{Chembox
+| IUPACName = Thallium(III) hydroxide<ref name=pubchem>{{cite web | url=https://pubchem.ncbi.nlm.nih.gov/compound/Thallium_III_-hydroxide | title=Thallium(III) hydroxide }}</ref>
-| Section1 = {{Chembox Identifiers
+| OtherNames = Thallium trihydroxide<ref name=pubchem></ref>
-|  PubChem = 20466441
+| Watchedfields = changed
-|  PubChem_Ref = {{Pubchemcite|correct|Pubchem}}
+| verifiedrevid = 470605751
-|  ChemSpiderID = 15055199
+|Section1={{Chembox Identifiers
-|  ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
-|  SMILES = O[Tl](O)O
+| CASNo =
+| PubChem = 20466441
-|  StdInChI = 1S/3H2O.Tl/h3*1H2;/q;;;+3/p-3
+| ChemSpiderID = 15055199
-|  StdInChI_Ref = {{stdinchicite|correct|chemspider}}
+| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
-|  StdInChIKey = GEPJDKDOADVEKE-UHFFFAOYSA-K
+| SMILES = O[Tl](O)O
-|  StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
+| StdInChI = 1S/3H2O.Tl/h3*1H2;/q;;;+3/p-3
+| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
+| StdInChIKey = GEPJDKDOADVEKE-UHFFFAOYSA-K
+| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
 }}
-| Section2 = {{Chembox Properties
+|Section2={{Chembox Properties
-|  Formula = {{Chem|TlH|3|O|3}}
+| Formula = {{Chem2|Tl(OH)3}}
-|  MolarMass = 255.4053 g mol<sup>-1</sup>
+| MolarMass = 255.4053 g/mol
+| Appearance = White solid
-|  ExactMass = 255.982631232 g mol<sup>-1</sup>
 }}
 }}
+'''Thallium(III) hydroxide''', {{Chem2|Tl(OH)3}}, also known as '''thallic hydroxide''', is a [[hydroxide]] of [[thallium]]. It is a white solid.
+Thallium(III) hydroxide is a very weak base; it dissociates to give the thallium(III) [[ion]], {{Chem2|Tl(3+)}}, only in strongly acidic conditions.
+==Preparation==
+Thallium(III) hydroxide can be produced by the reaction of [[thallium(III) chloride]] with [[sodium hydroxide]]<ref>Glushkova, M. A. Reaction for the formation of the hydroxide of trivalent thallium. ''Zhurnal Neorganicheskoi Khimii'', 1959. 4: 1657-1660. {{issn|0044-457X}}</ref> or the electrochemical oxidation of {{Chem2|Tl+}} in [[alkalic|alkaline]] conditions.<ref>{{cite journal|journal=Journal of the American Chemical Society|volume=73|issue=4|language=en|issn=0002-7863|date=April 1951|pages=1755–1756|doi=10.1021/ja01148a093|url=https://pubs.acs.org/doi/abs/10.1021/ja01148a093|title=The Anodic Oxidation of Thallous Ion on the Rotating Platinum Microelectrode|accessdate=2020-06-01|author=Paul Delahay, G. L. Stiehl}}</ref>
+==References==
+{{Reflist}}
+{{Thallium compounds}}
+{{Hydroxides}}
+[[Category:Hydroxides]]
+[[Category:Thallium(III) compounds]]
+{{Inorganic-compound-stub}}
+Synthesis
+Thallium(I) hydroxide is obtained from the decomposition of thallium(I) ethoxide in water.[3]
+CH3CH2OTl + H2O → TlOH + CH3CH2OH
+This can also be done by direct reaction of thallium with ethanol and oxygen gas.
+Tl + 2 CH3CH2OH + O2 → 2 CH3CH2OTl + 2 TlOH
+Another method is the reaction between thallium(I) sulfate and barium hydroxide.
+Tl2SO4 + Ba(OH)2 → 2 TlOH + BaSO4
+Properties
+Thallous hydroxide is a strong base; it dissociates to the thallous ion, Tl+, except in strongly basic conditions. Tl+ resembles an alkali metal ion, such as Li+ or K+.