In the race's other classifications, Stef Clement, of the Belkin Pro Cycling team, was the winner of the red jersey for the mountains classification; he also won a stage wearing the jersey, winning on the penultimate stage.Cannondale rider Michel Koch won both sprints classifications; along with the normal intermediate sprints, Koch was the winner of the special sprints standings, named in honour of Miguel Poblet, with the most points at the specific sprint places on the itinerary. For the second year in a row, Garmin–Sharp won the teams classification.
As the Volta a Catalunya was a UCI World Tour event, all 18 UCI ProTeams were invited automatically and obligated to send a squad. Four other squads were given wildcard places, thus completing the 22-team peloton.
In the 2014 Volta a Catalunya, four different jerseys were awarded. For the general classification, calculated by adding each cyclist's finishing times on each stage, and allowing time bonuses in intermediate sprints and at the finish in mass-start stages, the leader received a white and green jersey. This classification was considered the most important of the 2014 Volta a Catalunya, and the winner of the classification was considered the winner of the race.
Additionally, there was a sprints classification, which awarded a white jersey. In the sprints classification, cyclists received points for finishing in the top 3 at intermediate sprint points during each stage; these intermediate sprints also offered bonus seconds towards the general classification. A special sprints classification was also contested, with points on offer at a specific point during the stage; the classification was named in honour of former cyclist Miguel Poblet, who died in 2013. There was also a mountains classification, the leadership of which was marked by a red jersey. In the mountains classification, points were won by reaching the top of a climb before other cyclists, with more points available for the higher-categorised climbs.
There was also a classification for teams, in which the times of the best three cyclists per team on each stage were added together; the leading team at the end of the race was the team with the lowest total time.