Trisodium phosphate
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| Names | |||
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| IUPAC name
Trisodium phosphate
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| Other names
Sodium phosphate tribasic, trisodium orthophosphate, sodium phosphate
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| Identifiers | |||
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3D model (JSmol)
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| ChEBI | |||
| ChEMBL | |||
| ChemSpider | |||
| ECHA InfoCard | 100.028.645 | ||
| EC Number |
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| E number | E339(iii) (antioxidants, ...) | ||
| KEGG | |||
PubChem CID
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| RTECS number | |||
| UNII |
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CompTox Dashboard (EPA)
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| Properties | |||
| Na3PO4 | |||
| Molar mass | 163.939 g·mol−1 | ||
| Density | 2.536 g/cm3 (17.5 °C, anhydrous) 1.62 g/cm3 (20 °C, dodecahydrate)[2][3][4] | ||
| Melting point | 1,583 °C (2,881 °F; 1,856 K) (anhydrous)[3] 73.4 °C (164.1 °F; 346.5 K) (dodecahydrate)[4] | ||
| Boiling point | 100 °C (212 °F; 373 K) (dodecahydrate) decomposes[4] | ||
| anhydrous:[3] 5.4 g/100 mL (0 °C) 12 g/100 mL (20 °C)[5] 14.5 g/100 mL (25 °C) 23.3 g/100 mL (40 °C) 94.6 g/100 mL (100 °C) dodecahydrate:[4] 28.3 g/100 mL (20 °C) | |||
| Solubility | insoluble in ethanol, CS2[4] | ||
| Basicity (pKb) | 2.23 | ||
| Structure | |||
| Trigonal | |||
| Thermochemistry | |||
Heat capacity (C)
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665 J/mol·K (dodecahydrate)[4] | ||
Std molar
entropy (S⦵298) |
224.7 J/mol·K (anhydrous)[3] 660 J/mol·K (dodecahydrate)[4] | ||
Std enthalpy of
formation (ΔfH⦵298) |
-1935.5 kJ/mol (anhydrous)[3] -5480 kJ/mol (dodecahydrate)[4] | ||
Gibbs free energy (ΔfG⦵)
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-1819 kJ/mol (anhydrous)[3] | ||
| Pharmacology | |||
| A06AD17 (WHO) A06AG01 (WHO) B05XA09 (WHO) | |||
| Hazards[6] | |||
| GHS labelling: | |||
 
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| Danger | |||
| H315, H318, H335 | |||
| P261, P280, P305+P351+P338 | |||
| NFPA 704 (fire diamond) | |||
| Flash point | Non-flammable | ||
| Safety data sheet (SDS) | ICSC 1178 | ||
| Related compounds | |||
Other cations
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Tripotassium phosphate Triammonium phosphate Trimagnesium phosphate | ||
Related compounds
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Monosodium phosphate Disodium phosphate | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Trisodium phosphate (TSP) is the inorganic compound with the chemical formula Na3PO4. It is a white, granular or crystalline solid, highly soluble in water, producing an alkaline solution. TSP is used as a cleaning agent, builder, lubricant, food additive, stain remover, and degreaser.[7]
The item of commerce is often partially hydrated and may range from anhydrous Na3PO4 to the dodecahydrate Na3PO4 · 12 H2O. Most often found in white powder form, it can also be called trisodium orthophosphate or simply sodium phosphate.
Production
Trisodium phosphate is produced by neutralization of phosphoric acid using sodium carbonate, which produces disodium hydrogen phosphate. The disodium hydrogen phosphate is reacted with sodium hydroxide to form trisodium phosphate and water.
- Na2CO3 + H3PO4 → Na2HPO4 + CO2 + H2O
- Na2HPO4 + NaOH → Na3PO4 + H2O
Uses
Cleaning
Trisodium phosphate was at one time extensively used in formulations for a variety of consumer-grade soaps and detergents, and the most common use for trisodium phosphate has been in cleaning agents. The pH of a 1% solution is 12 (i.e., very basic), and the solution is sufficiently alkaline to saponify grease and oils. In combination with surfactants, TSP is an excellent agent for cleaning everything from laundry to concrete driveways. This versatility and low manufacturing price made TSP the basis for a plethora of cleaning products sold in the mid-20th century.
TSP is still sold and used as a cleaning agent, but since the late 1960s, its use has diminished in the United States and many other parts of the world because, like many phosphate-based cleaners, it is known to cause extensive eutrophication of lakes and rivers once it enters a water system.[8]
TSP is commonly used after cleaning a surface with mineral spirits to remove hydrocarbon residues and may be used with household chlorine bleach in the same solution without hazardous reactions.[citation needed] This mixture is particularly effective for removing mildew, but is less effective at removing mold.[citation needed]
Although it is still the active ingredient in some toilet bowl-cleaning tablets, TSP is generally not recommended for cleaning bathrooms because it can stain metal fixtures and can damage grout.[9]
Chlorination
With the formula Na3PO4 · 1/4NaOCl · 11 H2O the material called chlorinated trisodium phosphate is used as a disinfectant and bleach, like sodium hypochlorite. It is prepared using NaOCl in place of some of the base to neutralize phosphoric acid.[7]
Flux
In the U.S., trisodium phosphate is an approved flux for use in hard soldering joints in medical-grade copper plumbing. The flux is applied as a concentrated water solution and dissolves copper oxides at the temperature used in copper brazing. Residues are water-soluble and can be rinsed out before plumbing is put into service.
TSP is used as an ingredient in fluxes designed to deoxygenate nonferrous metals for casting. It can be used in ceramic production to lower the flow point of glazes.
Painting enhancement
TSP is still in common use for the cleaning, degreasing, and deglossing of walls prior to painting. TSP breaks the gloss of oil-based paints and opens the pores of latex-based paint, providing a surface better suited for the adhesion of the subsequent layer.[10][unreliable source?]
Food additive
Sodium phosphates including monosodium phosphate, disodium phosphate, and trisodium phosphate are approved as food additives in the EU. They are commonly used as acidity regulators and have the collective E number E339.[11] The United States Food and Drug Administration lists sodium phosphates as generally recognized as safe.[12][13]
Exercise performance enhancement
Trisodium phosphate has gained a following as a nutritional supplement that can improve certain parameters of exercise performance.[14] The basis of this belief is the fact that phosphate is required for the energy-producing Krebs cycle central to aerobic metabolism. Phosphates are available from a number of other sources that are much milder than TSP. While TSP is not toxic per se, it is severely irritating to gastric mucosa unless used as part of a buffered solution.
Regulation
In the Western world, phosphate usage has declined owing to ecological problems with the damage to lakes and rivers through eutrophication.
Substitutes
By the end of the 20th century, many products that formerly contained TSP were manufactured with TSP substitutes, which consist mainly of sodium carbonate along with various admixtures of nonionic surfactants and a limited percentage of sodium phosphates.
Products sold as TSP substitutes, containing soda ash and zeolites, are promoted as direct substitutes. However, sodium carbonate is not as strongly basic as trisodium phosphate, making it less effective in demanding applications.[citation needed] Zeolites, which are clay based, are added to laundry detergents as water softening agents and are essentially non-polluting; however, zeolites do not dissolve and can deposit a fine, powdery residue in the wash tub.[citation needed] Cleaning products labeled as TSP may contain other ingredients, with perhaps less than 50% trisodium phosphate.[15]
References
- ^ Merck Index, 12th Edition, 8808.
- ^ Eagleson, Mary, ed. (1994). Concise Encyclopedia Chemistry. Walter de Gruyter. p. 1000. ISBN 978-3-11-011451-5. Retrieved 25 May 2014.
- ^ a b c d e f "Sodium phosphate".
- ^ a b c d e f g h "Sodium phosphate dodecahydrate".
- ^ "Archived copy" (PDF). Archived from the original (PDF) on 14 March 2016. Retrieved 25 May 2014.
{{cite web}}: CS1 maint: archived copy as title (link) - ^ Sigma-Aldrich Co., Sodium phosphate. Retrieved on 2014-05-25.
- ^ a b Klaus Schrödter, Gerhard Bettermann, Thomas Staffel, Friedrich Wahl, Thomas Klein, Thomas Hofmann "Phosphoric Acid and Phosphates" in Ullmann’s Encyclopedia of Industrial Chemistry 2008, Wiley-VCH, Weinheim. doi:10.1002/14356007.a19_465.pub3
- ^ Dishes Still Dirty? Blame Phosphate-Free Detergent, National Public Radio, 15 December 2010
- ^ "TSP ... Cleaning for the Big Dogs". Home Repair and Do It Yourself Tips and Articles from the Natural Handyman. Natural Handyman.
- ^ Alonzy, Jerry. "Painting Preparation Q&A".
- ^ Current EU approved additives and their E Numbers, Food Standards Agency, 26 November 2010
- ^ 21CFR182.1778, Code of Federal Regulations
- ^ 21CFR182.1778, Electronic Code of Federal Regulations
- ^ Folland JP, et al. (2008). "Sodium phosphate loading improves laboratory cycling time-trial performance in trained cyclists". Journal of Science and Medicine in Sport. 11 (5): 464–468. doi:10.1016/j.jsams.2007.04.004. PMID 17569583.
- ^ MSDS Archived 26 September 2010 at the Wayback Machine for Dap TSP cleaner
External links
